Equilibrio Líquido Vapor Ec. Van Laar

A= Acetato de etilo Pc(A)= 38.3B= Alcohol etílico Pc(B)= 61.4

CONSTANTES DE ANTOINE Puntos de ebullición:A1 6.3307 B1 7.43437 Teb(A)=A2 5440.049 B2 6162.36 Teb(B)=A3 373.4 B3 359.3826

CONSTANTES DE VAN LAARA(ab) 0.144A(ba) 0.17

yA xA gA gE kA kB1.05363453 1.114564 1.00275032 1.24632405 0.9453333662 1.110931691.02668651 1.08539613 1.0015109 1.22948601 0.9459094994 1.098340340.99980125 1.05594178 1.00064116 1.21341683 0.9468336869 1.08637549

0.9729419 1.02619537 1.00013904 1.19809001 0.9481059157 1.075017740.94607127 0.99615115 1.00000297 1.18348052 0.9497266175 1.064248820.91915173 0.96580324 1.00023185 1.1695648 0.9516966685 1.054051590.89214516 0.9351456 1.00082505 1.15632062 0.9540173891 1.044409950.86501284 0.90417204 1.00178241 1.14372706 0.9566905458 1.035308840.83771532 0.87287622 1.00310421 1.13176443 0.9597183528 1.026734140.81021235 0.84125161 1.00479122 1.12041422 0.9631034759 1.018672660.78246273 0.80929153 1.00684467 1.10965904 0.9668490369 1.01111210.75442428 0.77698912 1.00926623 1.09948258 0.9709586193 1.004041020.72605364 0.74433733 1.01205808 1.08986953 0.9754362746 0.997448790.69730618 0.71132894 1.01522282 1.08080559 0.9802865305 0.991325580.66813591 0.67795651 1.01876357 1.0722774 0.9855143995 0.985662330.63849529 0.64421243 1.02268392 1.06427248 0.9911253893 0.980450680.60833515 0.61008884 1.02698792 1.05677926 0.9971255139 0.975683050.57760448 0.5755777 1.03168017 1.04978697 1.0035213063 0.971352490.54625036 0.54067073 1.03676573 1.0432857 1.0103198322 0.967452760.51421773 0.50535944 1.0422502 1.03726627 1.0175287053 0.963978290.48144925 0.46963507 1.0481397 1.03172031 1.0251561037 0.960924130.44788513 0.43348863 1.05444091 1.02664016 1.0332107881 0.958285980.41346291 0.39691088 1.06116105 1.02201888 1.0417021209 0.956060140.37811729 0.35989231 1.06830793 1.01785024 1.0506400876 0.95424354

0.3417799 0.32242313 1.07588993 1.0141287 1.0600353193 0.95283370.30437909 0.28449326 1.08391606 1.01084939 1.0698991174 0.951828760.26583965 0.24609235 1.09239594 1.00800808 1.0802434791 0.951227420.22608261 0.20720971 1.10133988 1.00560121 1.0910811265 0.951028990.18502489 0.16783437 1.11075883 1.00362586 1.1024255358 0.951233370.14257909 0.12795499 1.12066446 1.00207974 1.1142909702 0.951841040.09865311 0.08755992 1.13106917 1.00096118 1.1266925141 0.952853060.05314984 0.04663714 1.14198613 1.00026916 1.1396461101 0.954271110.00596681 0.00517427 1.15342929 1.00000327 1.1531685981 0.95609744

-0.04300422 -0.03684146 1.16541343 1.00016372 1.1672777576 0.95833493-0.09387764 -0.07942322 1.1779542 1.00075136 1.1819923527 0.96098706-0.14677447 -0.12258459 1.19106815 1.00176766 1.1973321796 0.96405793-0.20182282 -0.16633957 1.20477279 1.00321472 1.2133181178 0.96755229-0.25915837 -0.21070262 1.2190866 1.00509532 1.2299721848 0.97147552-0.31892497 -0.25568867 1.23402911 1.00741284 1.2473175939 0.97583368-0.38127522 -0.30131311 1.24962095 1.01017136 1.2653788164 0.98063351-0.44637107 -0.34759185 1.26588386 1.01337562 1.2841816477 0.98588245-0.51438455 -0.39454133 1.28284083 1.01703106 1.3037532775 0.99158865-0.58549848 -0.44217853 1.30051609 1.02114382 1.3241223655 0.99776103-0.65990726 -0.49052098 1.31893519 1.02572075 1.3453191213 1.00440926-0.73781778 -0.53958685 1.33812512 1.03076949 1.36737539 1.01154384-0.81945028 -0.58939487 1.35811432 1.0362984 1.3903247437 1.01917607

-0.9050394 -0.63996447 1.3789328 1.04231666 1.4142025792 1.02731813-0.99483527 -0.69131571 1.40061221 1.04883428 1.4390462219 1.03598311-1.08910461 -0.74346938 1.42318595 1.05586211 1.4648950371 1.04518504

-1.1881321 -0.796447 1.44668925 1.06341189 1.4917905492 1.05493892-1.29222169 -0.85027083 1.47115929 1.07149629 1.5197765682 1.0652608-1.40169809 -0.90496397 1.4966353 1.08012894 1.5488993259 1.07616781-1.51690841 -0.96055034 1.52315868 1.08932447 1.5792076208 1.0876782

bar Ptotal= 1.013 barbar

Puntos de ebullición:170.87172.85

°F BarT Pvap(A) Pvap(B) xB yB

169.4 0.95499615 0.9029544155 -0.114564 -0.05363453169.5 0.95676075 0.9049462582 -0.08539613 -0.02668651169.6 0.95852796 0.9069417391 -0.05594178 0.00019875169.7 0.96029777 0.9089408634 -0.02619537 0.0270581169.8 0.96207021 0.9109436362 0.00384885 0.05392873169.9 0.96384526 0.9129500626 0.03419676 0.08084827

170 0.96562293 0.9149601479 0.0648544 0.10785484170.1 0.96740322 0.916973897 0.09582796 0.13498716170.2 0.96918614 0.9189913153 0.12712378 0.16228468170.3 0.97097168 0.9210124077 0.15874839 0.18978765170.4 0.97275986 0.9230371796 0.19070847 0.21753727170.5 0.97455067 0.925065636 0.22301088 0.24557572170.6 0.97634412 0.9270977821 0.25566267 0.27394636170.7 0.9781402 0.929133623 0.28867106 0.30269382170.8 0.97993893 0.9311731641 0.32204349 0.33186409170.9 0.9817403 0.9332164104 0.35578757 0.36150471

171 0.98354433 0.935263367 0.38991116 0.39166485171.1 0.985351 0.9373140393 0.4244223 0.42239552171.2 0.98716032 0.9393684324 0.45932927 0.45374964171.3 0.9889723 0.9414265515 0.49464056 0.48578227171.4 0.99078695 0.9434884018 0.53036493 0.51855075171.5 0.99260425 0.9455539886 0.56651137 0.55211487171.6 0.99442421 0.9476233169 0.60308912 0.58653709171.7 0.99624685 0.9496963921 0.64010769 0.62188271171.8 0.99807215 0.9517732193 0.67757687 0.6582201171.9 0.99990013 0.9538538039 0.71550674 0.69562091

172 1.00173078 0.9559381509 0.75390765 0.73416035172.1 1.00356412 0.9580262658 0.79279029 0.77391739172.2 1.00540013 0.9601181536 0.83216563 0.81497511172.3 1.00723883 0.9622138197 0.87204501 0.85742091172.4 1.00908021 0.9643132692 0.91244008 0.90134689172.5 1.01092428 0.9664165076 0.95336286 0.94685016172.6 1.01277105 0.9685235399 0.99482573 0.99403319

0 0.2 0.4 0.6 0.8 1 1.2168

168.5

169

169.5

170

170.5

171

171.5

172

172.5

173

Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico

xA

yA

Composición

Temperatura (°F)

172.7 1.01462051 0.9706343715 1.03684146 1.04300422172.8 1.01647267 0.9727490077 1.07942322 1.09387764172.9 1.01832754 0.9748674537 1.12258459 1.14677447

173 1.0201851 0.9769897147 1.16633957 1.20182282173.1 1.02204537 0.9791157962 1.21070262 1.25915837173.2 1.02390836 0.9812457034 1.25568867 1.31892497173.3 1.02577405 0.9833794415 1.30131311 1.38127522173.4 1.02764246 0.9855170158 1.34759185 1.44637107173.5 1.02951359 0.9876584318 1.39454133 1.51438455173.6 1.03138744 0.9898036946 1.44217853 1.58549848173.7 1.03326401 0.9919528096 1.49052098 1.65990726173.8 1.03514331 0.9941057821 1.53958685 1.73781778173.9 1.03702534 0.9962626174 1.58939487 1.81945028

174 1.0389101 0.9984233208 1.63996447 1.9050394174.1 1.0407976 1.0005878978 1.69131571 1.99483527174.2 1.04268783 1.0027563536 1.74346938 2.08910461174.3 1.04458081 1.0049286935 1.796447 2.1881321174.4 1.04647652 1.0071049229 1.85027083 2.29222169174.5 1.04837499 1.0092850472 1.90496397 2.40169809174.6 1.0502762 1.0114690716 1.96055034 2.51690841

0 0.2 0.4 0.6 0.8 1 1.2168

168.5

169

169.5

170

170.5

171

171.5

172

172.5

173

Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico

xA

yA

Composición

Temperatura (°F)

0 0.2 0.4 0.6 0.8 1 1.2168

168.5

169

169.5

170

170.5

171

171.5

172

172.5

173

Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico

xA

yA

Composición

Temperatura (°F)

0 0.2 0.4 0.6 0.8 1 1.2168

168.5

169

169.5

170

170.5

171

171.5

172

172.5

173

Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico

xA

yA

Composición

Temperatura (°F)

0 0.2 0.4 0.6 0.8 1 1.2168

168.5

169

169.5

170

170.5

171

171.5

172

172.5

173

Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico

xA

yA

Composición

Temperatura (°F)

0 0.2 0.4 0.6 0.8 1 1.2168

168.5

169

169.5

170

170.5

171

171.5

172

172.5

173

Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico

xA

yA

Composición

Temperatura (°F)

A= Hexano Pc(A)= 30.33353B= Octano Pc(B)= 24.96312

CONSTANTES DE ANTOINE Puntos de ebullición:A1 6.0392 B1 6.4141 Teb(A)=A2 5085.758 B2 5947.491 Teb(B)=A3 382.794 B3 360.26

CONSTANTES DE VAN LAARA(ab) 0.144A(ba) 0.17

yA xA gA gE kA kB-0.37527514 -0.24284627 1.22971963 1.0067099 1.5453197491 0.20116823-0.37853866 -0.24444381 1.23025381 1.00679556 1.548571277 0.20161223-0.38180928 -0.24603842 1.23078755 1.00688157 1.5518278642 0.20205713

-0.385087 -0.24763012 1.23132085 1.00696792 1.5550895144 0.20250291-0.38837183 -0.2492189 1.23185371 1.00705462 1.5583562313 0.20294957-0.39166378 -0.25080478 1.23238613 1.00714166 1.5616280184 0.20339713-0.39496285 -0.25238777 1.23291811 1.00722904 1.5649048794 0.20384558-0.39826906 -0.25396786 1.23344964 1.00731675 1.5681868179 0.20429493

-0.4015824 -0.25554508 1.23398074 1.0074048 1.5714738377 0.20474516-0.40490289 -0.25711941 1.23451139 1.00749317 1.5747659423 0.20519629-0.40823054 -0.25869088 1.23504159 1.00758188 1.5780631354 0.20564832-0.41156535 -0.26025948 1.23557135 1.0076709 1.5813654208 0.20610124-0.41490732 -0.26182523 1.23610067 1.00776025 1.584672802 0.20655506-0.41825647 -0.26338813 1.23662953 1.00784991 1.5879852828 0.20700978-0.42161281 -0.26494818 1.23715795 1.00793989 1.5913028669 0.20746539-0.42497633 -0.2665054 1.23768592 1.00803018 1.5946255579 0.20792191-0.42834704 -0.26805979 1.23821345 1.00812078 1.5979533596 0.20837933-0.43172496 -0.26961136 1.23874052 1.00821168 1.6012862756 0.20883765-0.43511009 -0.2711601 1.23926715 1.0083029 1.6046243097 0.20929688-0.43850244 -0.27270604 1.23979332 1.00839441 1.6079674655 0.20975701-0.44190201 -0.27424917 1.24031904 1.00848622 1.6113157468 0.21021804-0.44530882 -0.27578951 1.24084431 1.00857833 1.6146691574 0.21067998-0.44872286 -0.27732706 1.24136913 1.00867073 1.6180277009 0.21114283-0.45214414 -0.27886182 1.2418935 1.00876342 1.6213913811 0.21160659-0.45557268 -0.2803938 1.24241741 1.0088564 1.6247602017 0.21207126-0.45900848 -0.28192301 1.24294087 1.00894966 1.6281341664 0.21253684-0.46245155 -0.28344945 1.24346387 1.00904321 1.6315132791 0.21300333-0.46590189 -0.28497314 1.24398642 1.00913704 1.6348975434 0.21347073-0.46935951 -0.28649407 1.24450851 1.00923115 1.6382869632 0.21393905-0.47282441 -0.28801226 1.24503014 1.00932553 1.6416815422 0.21440828-0.47629662 -0.28952771 1.24555132 1.00942018 1.6450812841 0.21487843-0.47977612 -0.29104042 1.24607204 1.00951511 1.6484861927 0.2153495-0.48326293 -0.29255041 1.2465923 1.0096103 1.6518962719 0.21582148

-0.48675706 -0.29405767 1.24711211 1.00970576 1.6553115254 0.21629439-0.49025851 -0.29556223 1.24763145 1.00980148 1.6587319569 0.21676821-0.49376729 -0.29706407 1.24815034 1.00989747 1.6621575704 0.21724296-0.49728341 -0.29856321 1.24866876 1.00999371 1.6655883695 0.21771862-0.50080687 -0.30005965 1.24918672 1.0100902 1.6690243581 0.21819522-0.50433768 -0.3015534 1.24970423 1.01018695 1.67246554 0.21867273-0.50787585 -0.30304447 1.25022127 1.01028395 1.6759119189 0.21915118-0.51142138 -0.30453287 1.25073785 1.0103812 1.6793634989 0.21963055-0.51497429 -0.30601859 1.25125397 1.0104787 1.6828202835 0.22011084-0.51853457 -0.30750164 1.25176962 1.01057644 1.6862822768 0.22059207-0.52210224 -0.30898204 1.25228481 1.01067442 1.6897494824 0.22107423

-0.5256773 -0.31045978 1.25279954 1.01077265 1.6932219043 0.22155731-0.52925977 -0.31193488 1.2533138 1.0108711 1.6966995463 0.22204133-0.53284964 -0.31340733 1.2538276 1.0109698 1.7001824122 0.22252629-0.53644692 -0.31487715 1.25434093 1.01106873 1.7036705059 0.22301217-0.54005163 -0.31634435 1.2548538 1.01116788 1.7071638313 0.223499-0.54366376 -0.31780891 1.2553662 1.01126727 1.7106623921 0.22398676-0.54728333 -0.31927087 1.25587814 1.01136688 1.7141661923 0.22447545-0.55091033 -0.32073021 1.25638961 1.01146672 1.7176752358 0.22496509-0.55454479 -0.32218694 1.25690061 1.01156678 1.7211895264 0.22545567

bar Ptotal= 1.013 barbar

Puntos de ebullición:155.73 °F258.23 °F

°F BarT Pvap(A) Pvap(B) xB yB

169.4 1.27298033 0.2024251619 1.24284627 1.37527514169.5 1.27510494 0.2028546808 1.24444381 1.37853866169.6 1.27723231 0.2032849484 1.24603842 1.38180928169.7 1.27936247 0.2037159658 1.24763012 1.385087169.8 1.2814954 0.204147734 1.2492189 1.38837183169.9 1.28363112 0.2045802538 1.25080478 1.39166378

170 1.28576962 0.2050135263 1.25238777 1.39496285170.1 1.2879109 0.2054475526 1.25396786 1.39826906170.2 1.29005498 0.2058823335 1.25554508 1.4015824170.3 1.29220185 0.2063178701 1.25711941 1.40490289170.4 1.29435152 0.2067541635 1.25869088 1.40823054170.5 1.29650398 0.2071912145 1.26025948 1.41156535170.6 1.29865924 0.2076290242 1.26182523 1.41490732170.7 1.3008173 0.2080675936 1.26338813 1.41825647170.8 1.30297817 0.2085069237 1.26494818 1.42161281170.9 1.30514184 0.2089470154 1.2665054 1.42497633

171 1.30730833 0.2093878699 1.26805979 1.42834704171.1 1.30947762 0.2098294881 1.26961136 1.43172496171.2 1.31164974 0.2102718709 1.2711601 1.43511009171.3 1.31382466 0.2107150195 1.27270604 1.43850244171.4 1.31600241 0.2111589347 1.27424917 1.44190201171.5 1.31818298 0.2116036177 1.27578951 1.44530882171.6 1.32036637 0.2120490694 1.27732706 1.44872286171.7 1.3225526 0.2124952908 1.27886182 1.45214414171.8 1.32474165 0.2129422829 1.2803938 1.45557268171.9 1.32693353 0.2133900468 1.28192301 1.45900848

172 1.32912825 0.2138385835 1.28344945 1.46245155172.1 1.3313258 0.2142878939 1.28497314 1.46590189172.2 1.33352619 0.2147379791 1.28649407 1.46935951172.3 1.33572943 0.21518884 1.28801226 1.47282441172.4 1.33793551 0.2156404778 1.28952771 1.47629662172.5 1.34014444 0.2160928934 1.29104042 1.47977612172.6 1.34235621 0.2165460878 1.29255041 1.48326293

-0.5 -0.45 -0.4 -0.35 -0.3 -0.25 -0.2168

168.5

169

169.5

170

170.5

171

171.5

172

172.5

173

Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico

xA

yA

Composición

Temperatura (°F)

172.7 1.34457084 0.2170000621 1.29405767 1.48675706172.8 1.34678832 0.2174548172 1.29556223 1.49025851172.9 1.34900867 0.2179103542 1.29706407 1.49376729

173 1.35123186 0.2183666741 1.29856321 1.49728341173.1 1.35345793 0.218823778 1.30005965 1.50080687173.2 1.35568685 0.2192816667 1.3015534 1.50433768173.3 1.35791865 0.2197403415 1.30304447 1.50787585173.4 1.36015331 0.2201998032 1.30453287 1.51142138173.5 1.36239084 0.2206600529 1.30601859 1.51497429173.6 1.36463125 0.2211210916 1.30750164 1.51853457173.7 1.36687454 0.2215829204 1.30898204 1.52210224173.8 1.36912071 0.2220455402 1.31045978 1.5256773173.9 1.37136976 0.2225089522 1.31193488 1.52925977

174 1.37362169 0.2229731572 1.31340733 1.53284964174.1 1.37587651 0.2234381565 1.31487715 1.53644692174.2 1.37813422 0.2239039509 1.31634435 1.54005163174.3 1.38039482 0.2243705415 1.31780891 1.54366376174.4 1.38265832 0.2248379294 1.31927087 1.54728333174.5 1.38492471 0.2253061155 1.32073021 1.55091033174.6 1.38719401 0.2257751009 1.32218694 1.55454479

-0.5 -0.45 -0.4 -0.35 -0.3 -0.25 -0.2168

168.5

169

169.5

170

170.5

171

171.5

172

172.5

173

Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico

xA

yA

Composición

Temperatura (°F)

-0.5 -0.45 -0.4 -0.35 -0.3 -0.25 -0.2168

168.5

169

169.5

170

170.5

171

171.5

172

172.5

173

Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico

xA

yA

Composición

Temperatura (°F)

-0.5 -0.45 -0.4 -0.35 -0.3 -0.25 -0.2168

168.5

169

169.5

170

170.5

171

171.5

172

172.5

173

Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico

xA

yA

Composición

Temperatura (°F)

-0.5 -0.45 -0.4 -0.35 -0.3 -0.25 -0.2168

168.5

169

169.5

170

170.5

171

171.5

172

172.5

173

Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico

xA

yA

Composición

Temperatura (°F)

-0.5 -0.45 -0.4 -0.35 -0.3 -0.25 -0.2168

168.5

169

169.5

170

170.5

171

171.5

172

172.5

173

Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico

xA

yA

Composición

Temperatura (°F)