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Programa que obtiene datos de equilibrio líquido vapor a partir de la ec. de Van Laar
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A= Acetato de etilo Pc(A)= 38.3B= Alcohol etílico Pc(B)= 61.4
CONSTANTES DE ANTOINE Puntos de ebullición:A1 6.3307 B1 7.43437 Teb(A)=A2 5440.049 B2 6162.36 Teb(B)=A3 373.4 B3 359.3826
CONSTANTES DE VAN LAARA(ab) 0.144A(ba) 0.17
yA xA gA gE kA kB1.05363453 1.114564 1.00275032 1.24632405 0.9453333662 1.110931691.02668651 1.08539613 1.0015109 1.22948601 0.9459094994 1.098340340.99980125 1.05594178 1.00064116 1.21341683 0.9468336869 1.08637549
0.9729419 1.02619537 1.00013904 1.19809001 0.9481059157 1.075017740.94607127 0.99615115 1.00000297 1.18348052 0.9497266175 1.064248820.91915173 0.96580324 1.00023185 1.1695648 0.9516966685 1.054051590.89214516 0.9351456 1.00082505 1.15632062 0.9540173891 1.044409950.86501284 0.90417204 1.00178241 1.14372706 0.9566905458 1.035308840.83771532 0.87287622 1.00310421 1.13176443 0.9597183528 1.026734140.81021235 0.84125161 1.00479122 1.12041422 0.9631034759 1.018672660.78246273 0.80929153 1.00684467 1.10965904 0.9668490369 1.01111210.75442428 0.77698912 1.00926623 1.09948258 0.9709586193 1.004041020.72605364 0.74433733 1.01205808 1.08986953 0.9754362746 0.997448790.69730618 0.71132894 1.01522282 1.08080559 0.9802865305 0.991325580.66813591 0.67795651 1.01876357 1.0722774 0.9855143995 0.985662330.63849529 0.64421243 1.02268392 1.06427248 0.9911253893 0.980450680.60833515 0.61008884 1.02698792 1.05677926 0.9971255139 0.975683050.57760448 0.5755777 1.03168017 1.04978697 1.0035213063 0.971352490.54625036 0.54067073 1.03676573 1.0432857 1.0103198322 0.967452760.51421773 0.50535944 1.0422502 1.03726627 1.0175287053 0.963978290.48144925 0.46963507 1.0481397 1.03172031 1.0251561037 0.960924130.44788513 0.43348863 1.05444091 1.02664016 1.0332107881 0.958285980.41346291 0.39691088 1.06116105 1.02201888 1.0417021209 0.956060140.37811729 0.35989231 1.06830793 1.01785024 1.0506400876 0.95424354
0.3417799 0.32242313 1.07588993 1.0141287 1.0600353193 0.95283370.30437909 0.28449326 1.08391606 1.01084939 1.0698991174 0.951828760.26583965 0.24609235 1.09239594 1.00800808 1.0802434791 0.951227420.22608261 0.20720971 1.10133988 1.00560121 1.0910811265 0.951028990.18502489 0.16783437 1.11075883 1.00362586 1.1024255358 0.951233370.14257909 0.12795499 1.12066446 1.00207974 1.1142909702 0.951841040.09865311 0.08755992 1.13106917 1.00096118 1.1266925141 0.952853060.05314984 0.04663714 1.14198613 1.00026916 1.1396461101 0.954271110.00596681 0.00517427 1.15342929 1.00000327 1.1531685981 0.95609744
-0.04300422 -0.03684146 1.16541343 1.00016372 1.1672777576 0.95833493-0.09387764 -0.07942322 1.1779542 1.00075136 1.1819923527 0.96098706-0.14677447 -0.12258459 1.19106815 1.00176766 1.1973321796 0.96405793-0.20182282 -0.16633957 1.20477279 1.00321472 1.2133181178 0.96755229-0.25915837 -0.21070262 1.2190866 1.00509532 1.2299721848 0.97147552-0.31892497 -0.25568867 1.23402911 1.00741284 1.2473175939 0.97583368-0.38127522 -0.30131311 1.24962095 1.01017136 1.2653788164 0.98063351-0.44637107 -0.34759185 1.26588386 1.01337562 1.2841816477 0.98588245-0.51438455 -0.39454133 1.28284083 1.01703106 1.3037532775 0.99158865-0.58549848 -0.44217853 1.30051609 1.02114382 1.3241223655 0.99776103-0.65990726 -0.49052098 1.31893519 1.02572075 1.3453191213 1.00440926-0.73781778 -0.53958685 1.33812512 1.03076949 1.36737539 1.01154384-0.81945028 -0.58939487 1.35811432 1.0362984 1.3903247437 1.01917607
-0.9050394 -0.63996447 1.3789328 1.04231666 1.4142025792 1.02731813-0.99483527 -0.69131571 1.40061221 1.04883428 1.4390462219 1.03598311-1.08910461 -0.74346938 1.42318595 1.05586211 1.4648950371 1.04518504
-1.1881321 -0.796447 1.44668925 1.06341189 1.4917905492 1.05493892-1.29222169 -0.85027083 1.47115929 1.07149629 1.5197765682 1.0652608-1.40169809 -0.90496397 1.4966353 1.08012894 1.5488993259 1.07616781-1.51690841 -0.96055034 1.52315868 1.08932447 1.5792076208 1.0876782
bar Ptotal= 1.013 barbar
Puntos de ebullición:170.87172.85
°F BarT Pvap(A) Pvap(B) xB yB
169.4 0.95499615 0.9029544155 -0.114564 -0.05363453169.5 0.95676075 0.9049462582 -0.08539613 -0.02668651169.6 0.95852796 0.9069417391 -0.05594178 0.00019875169.7 0.96029777 0.9089408634 -0.02619537 0.0270581169.8 0.96207021 0.9109436362 0.00384885 0.05392873169.9 0.96384526 0.9129500626 0.03419676 0.08084827
170 0.96562293 0.9149601479 0.0648544 0.10785484170.1 0.96740322 0.916973897 0.09582796 0.13498716170.2 0.96918614 0.9189913153 0.12712378 0.16228468170.3 0.97097168 0.9210124077 0.15874839 0.18978765170.4 0.97275986 0.9230371796 0.19070847 0.21753727170.5 0.97455067 0.925065636 0.22301088 0.24557572170.6 0.97634412 0.9270977821 0.25566267 0.27394636170.7 0.9781402 0.929133623 0.28867106 0.30269382170.8 0.97993893 0.9311731641 0.32204349 0.33186409170.9 0.9817403 0.9332164104 0.35578757 0.36150471
171 0.98354433 0.935263367 0.38991116 0.39166485171.1 0.985351 0.9373140393 0.4244223 0.42239552171.2 0.98716032 0.9393684324 0.45932927 0.45374964171.3 0.9889723 0.9414265515 0.49464056 0.48578227171.4 0.99078695 0.9434884018 0.53036493 0.51855075171.5 0.99260425 0.9455539886 0.56651137 0.55211487171.6 0.99442421 0.9476233169 0.60308912 0.58653709171.7 0.99624685 0.9496963921 0.64010769 0.62188271171.8 0.99807215 0.9517732193 0.67757687 0.6582201171.9 0.99990013 0.9538538039 0.71550674 0.69562091
172 1.00173078 0.9559381509 0.75390765 0.73416035172.1 1.00356412 0.9580262658 0.79279029 0.77391739172.2 1.00540013 0.9601181536 0.83216563 0.81497511172.3 1.00723883 0.9622138197 0.87204501 0.85742091172.4 1.00908021 0.9643132692 0.91244008 0.90134689172.5 1.01092428 0.9664165076 0.95336286 0.94685016172.6 1.01277105 0.9685235399 0.99482573 0.99403319
0 0.2 0.4 0.6 0.8 1 1.2168
168.5
169
169.5
170
170.5
171
171.5
172
172.5
173
Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico
xA
yA
Composición
Temperatura (°F)
172.7 1.01462051 0.9706343715 1.03684146 1.04300422172.8 1.01647267 0.9727490077 1.07942322 1.09387764172.9 1.01832754 0.9748674537 1.12258459 1.14677447
173 1.0201851 0.9769897147 1.16633957 1.20182282173.1 1.02204537 0.9791157962 1.21070262 1.25915837173.2 1.02390836 0.9812457034 1.25568867 1.31892497173.3 1.02577405 0.9833794415 1.30131311 1.38127522173.4 1.02764246 0.9855170158 1.34759185 1.44637107173.5 1.02951359 0.9876584318 1.39454133 1.51438455173.6 1.03138744 0.9898036946 1.44217853 1.58549848173.7 1.03326401 0.9919528096 1.49052098 1.65990726173.8 1.03514331 0.9941057821 1.53958685 1.73781778173.9 1.03702534 0.9962626174 1.58939487 1.81945028
174 1.0389101 0.9984233208 1.63996447 1.9050394174.1 1.0407976 1.0005878978 1.69131571 1.99483527174.2 1.04268783 1.0027563536 1.74346938 2.08910461174.3 1.04458081 1.0049286935 1.796447 2.1881321174.4 1.04647652 1.0071049229 1.85027083 2.29222169174.5 1.04837499 1.0092850472 1.90496397 2.40169809174.6 1.0502762 1.0114690716 1.96055034 2.51690841
0 0.2 0.4 0.6 0.8 1 1.2168
168.5
169
169.5
170
170.5
171
171.5
172
172.5
173
Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico
xA
yA
Composición
Temperatura (°F)
0 0.2 0.4 0.6 0.8 1 1.2168
168.5
169
169.5
170
170.5
171
171.5
172
172.5
173
Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico
xA
yA
Composición
Temperatura (°F)
0 0.2 0.4 0.6 0.8 1 1.2168
168.5
169
169.5
170
170.5
171
171.5
172
172.5
173
Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico
xA
yA
Composición
Temperatura (°F)
0 0.2 0.4 0.6 0.8 1 1.2168
168.5
169
169.5
170
170.5
171
171.5
172
172.5
173
Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico
xA
yA
Composición
Temperatura (°F)
0 0.2 0.4 0.6 0.8 1 1.2168
168.5
169
169.5
170
170.5
171
171.5
172
172.5
173
Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico
xA
yA
Composición
Temperatura (°F)
A= Hexano Pc(A)= 30.33353B= Octano Pc(B)= 24.96312
CONSTANTES DE ANTOINE Puntos de ebullición:A1 6.0392 B1 6.4141 Teb(A)=A2 5085.758 B2 5947.491 Teb(B)=A3 382.794 B3 360.26
CONSTANTES DE VAN LAARA(ab) 0.144A(ba) 0.17
yA xA gA gE kA kB-0.37527514 -0.24284627 1.22971963 1.0067099 1.5453197491 0.20116823-0.37853866 -0.24444381 1.23025381 1.00679556 1.548571277 0.20161223-0.38180928 -0.24603842 1.23078755 1.00688157 1.5518278642 0.20205713
-0.385087 -0.24763012 1.23132085 1.00696792 1.5550895144 0.20250291-0.38837183 -0.2492189 1.23185371 1.00705462 1.5583562313 0.20294957-0.39166378 -0.25080478 1.23238613 1.00714166 1.5616280184 0.20339713-0.39496285 -0.25238777 1.23291811 1.00722904 1.5649048794 0.20384558-0.39826906 -0.25396786 1.23344964 1.00731675 1.5681868179 0.20429493
-0.4015824 -0.25554508 1.23398074 1.0074048 1.5714738377 0.20474516-0.40490289 -0.25711941 1.23451139 1.00749317 1.5747659423 0.20519629-0.40823054 -0.25869088 1.23504159 1.00758188 1.5780631354 0.20564832-0.41156535 -0.26025948 1.23557135 1.0076709 1.5813654208 0.20610124-0.41490732 -0.26182523 1.23610067 1.00776025 1.584672802 0.20655506-0.41825647 -0.26338813 1.23662953 1.00784991 1.5879852828 0.20700978-0.42161281 -0.26494818 1.23715795 1.00793989 1.5913028669 0.20746539-0.42497633 -0.2665054 1.23768592 1.00803018 1.5946255579 0.20792191-0.42834704 -0.26805979 1.23821345 1.00812078 1.5979533596 0.20837933-0.43172496 -0.26961136 1.23874052 1.00821168 1.6012862756 0.20883765-0.43511009 -0.2711601 1.23926715 1.0083029 1.6046243097 0.20929688-0.43850244 -0.27270604 1.23979332 1.00839441 1.6079674655 0.20975701-0.44190201 -0.27424917 1.24031904 1.00848622 1.6113157468 0.21021804-0.44530882 -0.27578951 1.24084431 1.00857833 1.6146691574 0.21067998-0.44872286 -0.27732706 1.24136913 1.00867073 1.6180277009 0.21114283-0.45214414 -0.27886182 1.2418935 1.00876342 1.6213913811 0.21160659-0.45557268 -0.2803938 1.24241741 1.0088564 1.6247602017 0.21207126-0.45900848 -0.28192301 1.24294087 1.00894966 1.6281341664 0.21253684-0.46245155 -0.28344945 1.24346387 1.00904321 1.6315132791 0.21300333-0.46590189 -0.28497314 1.24398642 1.00913704 1.6348975434 0.21347073-0.46935951 -0.28649407 1.24450851 1.00923115 1.6382869632 0.21393905-0.47282441 -0.28801226 1.24503014 1.00932553 1.6416815422 0.21440828-0.47629662 -0.28952771 1.24555132 1.00942018 1.6450812841 0.21487843-0.47977612 -0.29104042 1.24607204 1.00951511 1.6484861927 0.2153495-0.48326293 -0.29255041 1.2465923 1.0096103 1.6518962719 0.21582148
-0.48675706 -0.29405767 1.24711211 1.00970576 1.6553115254 0.21629439-0.49025851 -0.29556223 1.24763145 1.00980148 1.6587319569 0.21676821-0.49376729 -0.29706407 1.24815034 1.00989747 1.6621575704 0.21724296-0.49728341 -0.29856321 1.24866876 1.00999371 1.6655883695 0.21771862-0.50080687 -0.30005965 1.24918672 1.0100902 1.6690243581 0.21819522-0.50433768 -0.3015534 1.24970423 1.01018695 1.67246554 0.21867273-0.50787585 -0.30304447 1.25022127 1.01028395 1.6759119189 0.21915118-0.51142138 -0.30453287 1.25073785 1.0103812 1.6793634989 0.21963055-0.51497429 -0.30601859 1.25125397 1.0104787 1.6828202835 0.22011084-0.51853457 -0.30750164 1.25176962 1.01057644 1.6862822768 0.22059207-0.52210224 -0.30898204 1.25228481 1.01067442 1.6897494824 0.22107423
-0.5256773 -0.31045978 1.25279954 1.01077265 1.6932219043 0.22155731-0.52925977 -0.31193488 1.2533138 1.0108711 1.6966995463 0.22204133-0.53284964 -0.31340733 1.2538276 1.0109698 1.7001824122 0.22252629-0.53644692 -0.31487715 1.25434093 1.01106873 1.7036705059 0.22301217-0.54005163 -0.31634435 1.2548538 1.01116788 1.7071638313 0.223499-0.54366376 -0.31780891 1.2553662 1.01126727 1.7106623921 0.22398676-0.54728333 -0.31927087 1.25587814 1.01136688 1.7141661923 0.22447545-0.55091033 -0.32073021 1.25638961 1.01146672 1.7176752358 0.22496509-0.55454479 -0.32218694 1.25690061 1.01156678 1.7211895264 0.22545567
bar Ptotal= 1.013 barbar
Puntos de ebullición:155.73 °F258.23 °F
°F BarT Pvap(A) Pvap(B) xB yB
169.4 1.27298033 0.2024251619 1.24284627 1.37527514169.5 1.27510494 0.2028546808 1.24444381 1.37853866169.6 1.27723231 0.2032849484 1.24603842 1.38180928169.7 1.27936247 0.2037159658 1.24763012 1.385087169.8 1.2814954 0.204147734 1.2492189 1.38837183169.9 1.28363112 0.2045802538 1.25080478 1.39166378
170 1.28576962 0.2050135263 1.25238777 1.39496285170.1 1.2879109 0.2054475526 1.25396786 1.39826906170.2 1.29005498 0.2058823335 1.25554508 1.4015824170.3 1.29220185 0.2063178701 1.25711941 1.40490289170.4 1.29435152 0.2067541635 1.25869088 1.40823054170.5 1.29650398 0.2071912145 1.26025948 1.41156535170.6 1.29865924 0.2076290242 1.26182523 1.41490732170.7 1.3008173 0.2080675936 1.26338813 1.41825647170.8 1.30297817 0.2085069237 1.26494818 1.42161281170.9 1.30514184 0.2089470154 1.2665054 1.42497633
171 1.30730833 0.2093878699 1.26805979 1.42834704171.1 1.30947762 0.2098294881 1.26961136 1.43172496171.2 1.31164974 0.2102718709 1.2711601 1.43511009171.3 1.31382466 0.2107150195 1.27270604 1.43850244171.4 1.31600241 0.2111589347 1.27424917 1.44190201171.5 1.31818298 0.2116036177 1.27578951 1.44530882171.6 1.32036637 0.2120490694 1.27732706 1.44872286171.7 1.3225526 0.2124952908 1.27886182 1.45214414171.8 1.32474165 0.2129422829 1.2803938 1.45557268171.9 1.32693353 0.2133900468 1.28192301 1.45900848
172 1.32912825 0.2138385835 1.28344945 1.46245155172.1 1.3313258 0.2142878939 1.28497314 1.46590189172.2 1.33352619 0.2147379791 1.28649407 1.46935951172.3 1.33572943 0.21518884 1.28801226 1.47282441172.4 1.33793551 0.2156404778 1.28952771 1.47629662172.5 1.34014444 0.2160928934 1.29104042 1.47977612172.6 1.34235621 0.2165460878 1.29255041 1.48326293
-0.5 -0.45 -0.4 -0.35 -0.3 -0.25 -0.2168
168.5
169
169.5
170
170.5
171
171.5
172
172.5
173
Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico
xA
yA
Composición
Temperatura (°F)
172.7 1.34457084 0.2170000621 1.29405767 1.48675706172.8 1.34678832 0.2174548172 1.29556223 1.49025851172.9 1.34900867 0.2179103542 1.29706407 1.49376729
173 1.35123186 0.2183666741 1.29856321 1.49728341173.1 1.35345793 0.218823778 1.30005965 1.50080687173.2 1.35568685 0.2192816667 1.3015534 1.50433768173.3 1.35791865 0.2197403415 1.30304447 1.50787585173.4 1.36015331 0.2201998032 1.30453287 1.51142138173.5 1.36239084 0.2206600529 1.30601859 1.51497429173.6 1.36463125 0.2211210916 1.30750164 1.51853457173.7 1.36687454 0.2215829204 1.30898204 1.52210224173.8 1.36912071 0.2220455402 1.31045978 1.5256773173.9 1.37136976 0.2225089522 1.31193488 1.52925977
174 1.37362169 0.2229731572 1.31340733 1.53284964174.1 1.37587651 0.2234381565 1.31487715 1.53644692174.2 1.37813422 0.2239039509 1.31634435 1.54005163174.3 1.38039482 0.2243705415 1.31780891 1.54366376174.4 1.38265832 0.2248379294 1.31927087 1.54728333174.5 1.38492471 0.2253061155 1.32073021 1.55091033174.6 1.38719401 0.2257751009 1.32218694 1.55454479
-0.5 -0.45 -0.4 -0.35 -0.3 -0.25 -0.2168
168.5
169
169.5
170
170.5
171
171.5
172
172.5
173
Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico
xA
yA
Composición
Temperatura (°F)
-0.5 -0.45 -0.4 -0.35 -0.3 -0.25 -0.2168
168.5
169
169.5
170
170.5
171
171.5
172
172.5
173
Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico
xA
yA
Composición
Temperatura (°F)
-0.5 -0.45 -0.4 -0.35 -0.3 -0.25 -0.2168
168.5
169
169.5
170
170.5
171
171.5
172
172.5
173
Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico
xA
yA
Composición
Temperatura (°F)
-0.5 -0.45 -0.4 -0.35 -0.3 -0.25 -0.2168
168.5
169
169.5
170
170.5
171
171.5
172
172.5
173
Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico
xA
yA
Composición
Temperatura (°F)
-0.5 -0.45 -0.4 -0.35 -0.3 -0.25 -0.2168
168.5
169
169.5
170
170.5
171
171.5
172
172.5
173
Equilibrio L-V de una mezcla de acetato de etilo y alcohol etílico
xA
yA
Composición
Temperatura (°F)
