2OO2年重大记事 - CAS · Web view39. Organic reactions mediated by low-valent vanadium reagents and their applications in organic synthesis Fan XS, Zhang YM* 有机化学 20 02,

2OO2年重大记事

金属有机化学国家重点实验室

第一届学术委员会名单

学术委员会主任

钱长涛研究员

中科院上海有机化学研究所

副主任

康北笙教授

中山大学化学化工学院

席振峰教授

北京大学化学系

委员

陆熙炎院士


戴立信院士


沈之荃院士

浙江大学化学系

游效曾院士

南京大学配位化学国家重点实验室

支志明院士

香港大学化学系

黄宪教授

浙江大学化学系

宋礼成教授

南开大学化学系

侯雪龙研究员


麻生明研究员


秦金贵教授

武汉大学化学系

沈琪教授

苏州大学

金国新教授

复旦大学化学系

外籍委员Prof. Sharpless

美国scripps研究所

Prof. Bönnemann德国马普煤炭研究所

Prof. Otsuka

日本大阪大学

金属有机化学国家重点实验室

学科带头人现状与需求

现有人员

目前学科方向

陆熙炎院士

金属有机，有机合成

戴立信院士

不对称催化，有机合成

麻生明研究员


侯雪龙研究员


唐勇研究员

金属有机，材料化学

丁奎玲研究员


姜标研究员


施敏研究员


邓敏智研究员

军工，金属有机

张兆国研究员


陈家碧研究员

金属络合物化学

发展学科方向

需求计划人数

配位化学

1

金属络合物的反应化学

1

金属催化的材料化学

1

金属络合物的结构化学

1

2OO2年重大记事

一. 完成2002－2003年基金申请

共资助了32个项目，其中有机所14个，外单位18个，资助总额79.8万。

二．实验室设备更新

完成了两批设备更新计划论证，第一批经费已经批准，准备购置园二色散仪一台，原位红外仪一台，分析和制备液相色谱仪一台，和有机所共同购置SGI图形工作站和高分辨质谱一台，现这些购置计划正在实施中，将于2003年6月验收。第二批设备购置计划经费还没有落实，将努力争取。

三．创新群体

2001年申请的以我室学术带头人为主的题为“导向有机合成的金属有机化学”创新研究群体已于2002年正式启动，三年共360万元。此项目还得到上海市科委的匹配支持。

四. 实验室承担的科研项目运行正常

今年由吉林大学裘式纶教授和我室麻生明研究员作为首席科学家的973项目“创造新物质的分子工程学研究”完成了中期评估，得到科技部组织的专家组的好评，并完成了后三年计划和经费预算的上报，现后三年经费资助额度已得到批准，比原计划略有增加。另外麻生明主持的基金委重点项目“用金属有机化学研究绿色化学中的基本问题”和基金委优秀实验室重点项目“金属催化的对映选择性合成”两个项目在年初都通过了基金委的中期评估，专家组一致认为，该两个项目实施两年来，出色地完成了原订的研究计划，取得了一系列创新性的丰硕研究成果。同时施敏和丁奎岭主持的中科院知识创新方向性重大项目、唐勇主持的国家“863”计划等由实验室学术带头人共同承担的项目运行正常，发表了不少高质量的论文。今年实验室发表的论文中I区论文有10篇。

五．实验室学委会工作

实验室经常与学术委员保持联系，听取他们对实验室发展的建议，请他们为实验室出谋划策。实验室在今年第12届全国金属有机会议在福州召开之际于10月24－25日召开了2002年度学委会会议，会上荣幸地邀请到了基金委和中科院的领导参加，请他们为实验室的发展提了不少建设性意见。同时本届学术会上很高兴的邀请到南京大学化学系游效曾院士作了题为“光电功能配合物的组装”的学术报告，同时游先生已应邀同意成为我们实验室学术委员会委员中的一员，他的加盟必将推动我们实验室今后在配位化学方面的发展。

六．庆贺黄耀曾院士九十华诞

今年是我室德高望重的黄耀曾院士九十华诞，我们实验室在第12届全国金属有机化学会议上组织了祝贺黄耀曾先生九十华诞学术报告会，会议由戴立信院士主持，钱长涛研究员介绍黄耀曾院士的科学业绩，会上有香港中文大学黄乃正和谢作伟教授、浙江大学黄宪教授、日本东京工业大学Jiro Tsuji教授、南开大学周其林教授和上海有机所的唐勇研究员作了专题学术报告。另外，台湾大学彭旭明教授、台湾中研院化学研究所陆天尧教授和上海有机所的麻生明研究员都在他们的大会报告中祝贺黄耀曾院士九十华诞。同时有机所还在所内举行了庆贺黄耀曾先生生日的活动。

七、对外开放

实验室今年继续出资和课题组共同邀请一些国外学者专家到有机所进行顺访外，并以实验室名义邀请了一些比较著名的科学家到实验室进行专门的访问，在作学术报告后，还与所内尤其是实验室内的科学家进行面对面的工作访谈，使我们科研人员在有机所就了解了一些国际学科发展动态。

金属有机化学国家重点实验室学术委员会

第一届第二次会议简报

金属有机化学国家重点实验室第一届学术委员会第二次会议于今年10月23－26日在福州武夷山邮电宾馆召开。十四位委员中有九位出席会议，中科院高技术局化工处白路娜老师和国家基金委化学部杜灿屏老师、陈拥军老师与会指导。会议由学术委员会主任钱长涛研究员主持。这次会议的议程是1) 室主任汇报实验室一年来的工作情况，2) 专家学术报告和交流，3) 部分课题组工作进展情况汇报，4) 国际学术会议介绍，5)今后工作讨论。

一.实验室主任麻生明研究员汇报了实验室室一年来的工作

麻生明主任首先欢迎并感谢各位领导和专家的到会，并感谢大家在过去一年中对我们实验室工作的大力指导和支持。然后麻生明研究员汇报了实验室一年来的工作，重点介绍实验室一年来在仪器装备的更新、2002－2003年实验室基金申请及最后资助情况、实验室所承担的国家重大项目的检查情况、成果、论文发表和具体工作进展、人才培养和课题管理等方面的工作。

二．专家学术报告和交流

会上由南京大学游效曾院士和上海有机所戴立信院士、唐勇研究员分别作了题为“光电功能配合物的组装”、“不对称分子内Heck反应的区域选择性问题”、“镍系铁系烯烃聚合催化剂的研究进展、机遇与挑战”三个精彩的学术报告，与会代表对每一个报告都进行了充分的讨论和交流，大家觉得受益非浅。

三. 课题组工作进展汇报和讨论

这次会上共有五个课题组进行工作汇报，分别由上海有机所许旭副研究员(手性合成新产物的色谱分析方法)、上海有机所侯雪龙研究员(手性配体合成及其在不对称反应中的应用)、北京大学甘良兵教授(金属催化下富勒烯氧化物的合成)、中科院福建物构所陈忠宁研究员(金属炔基簇化学及其光电性能研究)、淮北煤炭师范学院王磊教授(绿色有机合成反应方法学)到会汇报工作。委员们认真听取了他们的进展情况和今后工作设想，并就研究工作中的问题提出了中肯的意见和建议，进行了广泛的学术交流。

四．国际学术会议介绍和讨论

本次会上共介绍了三个国际会议的内容：

1. 上海有机所的钱长涛研究员介绍了2002年7月在希腊科呼岛召开的第20届国际金属有机化学会议的情况, 重点介绍了5个大会报告的内容。

2. 上海有机所的麻生明研究员介绍了今年7月中旬在新西兰基督城召开的14th 有机

合成国际会议的基本情况，重点介绍了大会报告中我们实验室比较感兴趣的问题。

3. 上海有机所的戴立信院士介绍了今年4月底在香港召开的亚洲手性会议的情况。

本次会议参加人数大约为100人，其中工业界代表较多，工作很出色，戴先生本人在这次香港会议上代表上海有机所作了大会报告，介绍上海有机所在这方面的最新工作。

通过这些介绍和讨论，使到会委员们及时了解国际上金属有机化学研究的热点和掌握目前文献还来不及报道的热门资料，对拓宽工作思路起到了一定的作用。

五．今后工作讨论

会上委员们对实验室的学术方向、发展方针、研究课题设置和国际学术交流、实验室的建设和管理等方面进行了讨论，尤其是对实验室今后的发展提出了不少建设性建议。

总之，本次学委会会议讨论热烈，交流充分，学术气氛浓厚，与会者都认为收获较大。最后大家一致认为国家重点实验室来之不易，今后一定要坚持“金属有机化学”的学术方向作为学科发展的目标，保持实验室在反应方法学方面的特色，利用外单位优势，进行材料化学方面的合作，吸引国内外最优秀的人才到实验室来工作。即坚持基础研究的特点不变，又要多考虑把研究工作与国家现代化建设和国民经济发展需求相结合。希望金属有机化学国家重点实验室成为一个国际一流的金属有机化学研究基地，为国家解决重大科学问题，发展金属有机化学。

2002～2003资助课题一览表

序号姓名单位

题目

2002-01 陆熙炎上海有机所具有高合成效率的新有机合成反应的研究

2002-02 钱长涛上海有机所新型后期过渡金属催化剂的设计与合成及其

催化烯烃聚合反应研究

2002-03

麻生明上海有机所金属参与的碳-碳键形成反应研究

2002-04

侯雪龙上海有机所平面手性环芳烷配体的设计、合成及其应用

2002-05 沈延昌上海有机所金属有机参与的高选择性合成方法学研究

2002-06 陈家碧

上海有机所

多金属桥卡宾和桥卡拜络合物及其在催化

反应中的应用研究

2002-07 邓敏智上海有机所新型Suziki偶联反应及一些生物活性产物

的全合成

2002-08 姜标上海有机所不对称Pauson-Khand反应研究及在复杂

生物碱合成中的应用

2002-09 施敏上海有机所

Baylis-Hillman反应的研究

2002-10 丁奎岭上海有机所

新型C2对称性手性配体的设计、合成及其

金属络合物在催化不对称反应中的应用研究

2002-11 唐勇上海有机所

新型硫、碲叶立德的合成、设计及其在有机

合成中的应用

2002-12 张兆国上海有机所

碳－氧键的反应化学研究

2002-13 赵刚上海有机所

芳基锌试剂参与的不对称碳碳键形成反应研究

2002-14 许旭上海有机所

手性合成新产物的色谱分析方法研究

2002-15 宋礼成南开大学

巴基球碳簇过渡金属有机化合物的合成及非

线性光学性质研究

2002-16 黄宪浙江大学过渡金属参与下聚合物负载有机硒化合物的

固相反应

2002-17 沈琪苏州大学非茂基稀土配合物的合成及其反应性能的研究

2002-18 康北笙中山大学间隔基团调控的多齿杂氮配位化合物及螺旋

结构规律

2002-19 张永敏浙江大学稀土金属、过渡金属介入的选择性有机合成反应

2002-20 席振峰北京大学双金属有机合成试剂的发现与发展

2002-21 曹卫国上海大学

利用胂叶立德立体选择性合成多官能基有机

环化合物

2002-22 周锡庚复旦大学稀土烃硫基化合物的氧化反应研究

2002-23 庞震复旦大学手性半活性配体对金属有机化合物反应性的

影响及其应用

2002-24 王佰全南开大学桥连茂金属化合物的合成结构及催化烯烃

聚合研究

2002-25 王绍武

安徽师范大学新型立体位阻诱导单电子还原反应研究

2002-26 秦金贵武汉大学聚二茂铁基硅烷的设计、合成与固体磁性

2002-27 殷元骐兰化所非环戊二烯基配位的铑手性簇合物的合成

2002-28 甘良兵北京大学金属促进的多加成富勒烯环氧化物C60(0)n

的合成

2002-29 范青华化学所基于树状大分子手性催化剂的氟两相催化

反应研究

2002-30 朱成建南京大学手性镓、铟金属有机化合物的合成及其导向的

有机反应研究

2002-32 陈忠宁福建物构所金属有机分子导线、分子簇和分子笼

不对称合成中的应用

2002-34 王磊

淮北煤炭微波促进纳米钯粉催化无溶剂有机合成反应

师范学院的研究

2002年全室专利申请、授权一览表

2002年申请专利

编号

专利名称

申请日

专利号

发明人

1

乙烯齐聚催化剂、合成方法和用途

020520

PCT/CN02/00337

钱长涛、陈耀峰

2

含给电子基团有机配体的二价稀土配合物、合成方法与应用

020823

02136621.7

钱长涛、陈耀峰、邹刚、李楠、李杨、邹丰楼

3

一种平面手性[2.2]对环芳烷恶唑啉膦配体、合成方法及用途

020830

02136741.8

巫循伟、侯雪龙、戴立信

4

外消旋的联二酚的光学拆分方法

020524

02111829.9

丁奎岭、杜海峰

5

一种顺式卤代菊酸的生产方法

020719

02136131.2

姜标、张小兵、魏慧玲、高红兰

6

一种合成氮杂环化合物的方法

020925

02137124.5

陆琤、陆熙炎

7

一种二氢呋喃杂环化合物及其合成方法

020925

02137123.7

陆琤、陆熙炎

8

2,5-cis-二取代的吡咯烷衍生物、合成方法及其用途

020719

02136129.0

麻生明、焦宁

9

光学活性2，3－联烯醇和联烯醇脂、合成方法及其用途

020625

02112225.3

麻生明、徐代旺、李祖义

10

光学活性2,3－联烯醇和联烯醇酯、合成方法及其用途

0212

　

麻生明等

11

过渡金属络合物和有机碱协同催化CO2与杂环化合物反应的新方法

020125

02110653.3

沈玉梅、段伟良、施敏

12

合成环状碳酸酯或恶唑酮类化合物的新方法

020125

02110652.5

沈玉梅、段伟良、施敏

13

复合型金属络合物催化芳香族化合物的绿色硝化方法

020315

02111062.x

施敏、崔世聪

14

苯酚类化合物的绿色硝化方法

021114

02145268.7

施敏、崔世聪

15

烯烃聚合及共聚合催化剂、合成方法及其用途

020617

PCT/CN02/00425

孙秀丽、胡蔚秋、王聪、唐勇、张玉良、夏春安

16

新型烯烃聚合催化剂

020209

02110844.7

唐勇、胡蔚秋、孙秀丽、王聪、张玉良

17

具有手性的多齿恶唑啉配体及其与主族金属或第三族到第十三族过渡金属的配合物、合成方法及其用途

020712

02112354.3

唐勇、周剑

18

烯烃聚合催化剂、合成方法及其用途

021213

02151294.9

张玉良、唐勇等

19

高选择性地制备手性仲醇的新方法

020329

02111215.0

赵刚、胡建兵

2002年授权专利

编号

专利名称

专利号

发明人

1

一种具有多种手性中心的二茂铁恶唑啉配体、合成方法及用途

00127948.3

游书力、侯雪龙、戴立信

2

（1－三氟甲基）烯基硼酸的制备及其应用

00125767.6

姜标等

3

一种通过气相光氯化反应制备氯甲基三甲基硅烷的方法和装置

00119457.7

姜标等

4

三氟乙酰基苯乙酮肟及其衍生物的合成方法

99113670.5

姜标等

5

一种合成B－卤代丁烯酸内酯的方法

99119945.6

麻生明等

2002年金属有机化学国家重点实验室来访人员名单

Dr. Fuquan Song

University of East Anglia, UK

2002.03

Prof. J. M. Basset

The French Academy of Sciences

2002.03.03-03.05

Prof. Walter WeissensteinerThe Institute of Organic Chemistry

University of Vienna

2002.05.13-05.19

Dr. Lukas Hintermann

Tokyo Institute of Technology, Japan2002.05.20-05.26

Prof. Lin Pu

Virginia University, USA

2002.05.20-05.23

Prof. Chao-Jun Li

Tulane University, USA

2002.05

Prof. Xumu Zhang

The Penn. State University, USA

2002.07

Prof. Guigen Li

Texas Tech. University

2002.07

Prof. Ziling Xue

University of Tennessee, USA

2002.08.14-08.15

陈小华博士

上海华远分析仪器有限公司

2002.09.04

Prof. H. Schumann

柏林工业大学

2002.09.26-09.28

Prof. Hans-Guenther SchmalzUniversity of Cologne, Germany

2002.10.09-10.10

Prof. Merritt Andrus

Brigham Young University, USA

2002.11.20-11.24

Dr. Tony Y. Zhang

Eli Lilly Company

2002.12

Prof. Kotohiro Nomura

Nara Institute of Science and Technology2002.11

熊照明

Bochringer-Ingelheins药业公司

2002.12.25

二00二年论文目录

课题负责人：陆熙炎课题编号： 2002-01

1.Palladium(II)-Catalyzed Highly Regio- and Diastereoselective Cyclization of Difunctional Allylic N-Tosylcarbamates. A Convenient Synthesis of Optically Active 4-Vinyl-2-oxazolidinones and Total Synthesis of 1,4-Dideoxy-1,4-imino-L-xylitol

Lei, A.; Liu, G.; Lu, X.*

J. Org. Chem. 2002, 67, 974-980.

39

2.Palladium(II)-Catalyzed Coupling Reactions of Intramolecular Carbopalldation of Alkyne with Allylic Compounds

Liu, G.; Lu, X.*

Tetrahedron Lett. 2002, 43, 6791-6794.

46

3.Palladium(II)-Catalyzed Three-Component Coupling Reaction Initiated by Acetoxypalladation of Alkynes: An Efficient Route to (,(-Unsaturated Carbonyls

Zhao, L.; Lu, X.*

Org. Lett. 2002, 4, 3903-3906.

50

4.PdII-Catalyzed Intramolecular Cyclization of Alkynes with Aldehydes, Ketones or Nitriles Initiated by Acetoxypalladation of Alkynes

Zhao, L.; Lu, X.*

Angew. Chem. Int. Ed. 2002, 41, 4343-4345.

54

5.Highly Regioselective Construction of Spirocycles via Phosphine-Catalyzed [3+2] Cycloaddition

Du, Y.; Lu, X.*; Yu, Y.

J. Org. Chem. 2002, 67, 8901-8905.

57

6.Tandem reactions to Construct Heterocycles via Phosphine-Catalyzed Umpolung Addition and Intramolecular Conjugate Addition

Lu, C.; Lu, X.*

Org. Lett. 2002, 4, 4677-4679.

62

7.An Unexpected Reaction of Allylic Propynoate underPalladium(II) Catalysis

Zhang, Z.; Lu, X.*; Lang, S.

Chin. J. Chem. 2002, 20, 1287-1290.

65

课题负责人：钱长涛课题编号： 2002-02

1.Synthesis and crystal structure of one carbon-atom bridged lutetium complex

[Ph2C(Flu)(Cp)]LuN(TMS)2 and catalytic activity for polymerization of polar monomers

Changatao Qian, Wanli Nie, Yaofeng Chen, Jie Sun

J. Organometal. Chem., 2002, 645, 82-86.

69

2. Synthesis, structural characterization and catalytic behavior of one-atom bridged fluorenyl cyclopentadienyl lanthanocene complexes with Cs-or C1-symmetry

Wanli Nie, Changtao Qian, Yaofeng Chen, Sun Jie

J. Organometal. Chem., 2002, 647, 114-122.

74

3.One-Pot Synthesis of Tetrahydroquinolines Catalyzed by Dy(OTf)3 in Aqueous Solution

Ruifang Chen, Changtao Qian

Synth. Commun., 2002, 32, 2543-2548.

83

4. La(O-I-Pr)3 Catalyzed Three-Component Condensation Reaction:A Convenient Synthesis of N,N-Dialkyl-a-cyanoamines

Peipei Sun, Changtao Qian, Limin Wang and Ruifang Chen

Synth. Commun., 2002, 32, 2973-2978.

89

5. One-Pot Syntheses of 3,4-Dihydropyrimidine-2 (1 H)-thiones Catalyzed by La(OTf )3


Chin. J .Chem., 2002, 20, 427-430.

95

6. Recent Advances in Organic Reaction Catalyzed by Lanthanide(III) Complexes


Chin. J. Chem., 2002, 20, 407-419.

99

7. Synthesis,Structure and Reactivity of Lanthanocene Complexes

Changtao Qian, Chengjian Zhu

Chin. J. Chem., 2002, 20, 519-535.

112

课题负责人：麻生明课题编号： 2002-03

1．Efficient Synthesis of 2,3-Dihydrofurans via the Highly Selective Pd(0)-Catalyzed

Coupling-Cyclization Reaction of 3,4-Allenols with Aryl Iodides

Shengming Ma* and Wenzhong Gao

Synlett 2002, 65-68.

129

2．Mechanistic Switch Leading to Highly Efficient Chirality Transfer in Pd(0)-Catalyzed Coupling-Cyclization of Aryl Iodides with 1:1 Acid-Base Salts of 2,3-Allenoic Acids and L-(-)-Cinchonidine or D-(+)-/L-(-)--Methylbenzylamine. Enantioselective Synthesis of Highly Optically Active 3-Aryl Polysubstituted Butenolides

Shengming Ma* and Zhangjie Shi

Chem. Commun. 2002, 540-541.

133

3. Control of Regioselectivity in Pd(0)-Catalyzed Coupling-Cyclization Reaction of 2-(2’,3’-Allenyl)malonates with Organic Halides

Shengming Ma*, Ning Jiao, Shimin Zhao, and Hairong Hou

J. Org. Chem. 2002, 67, 2837-2847.

135

4.K2CO3-Catalyzed Michael Addition-Lactonization Reaction of 1,2-Allenyl Ketones with Electron-withdrawing Group Substituted Acetates. An Efficient Synthesis of -Pyrone Derivatives

Shengming Ma,* Shaohu Yin, Lintao Li, and Fenggang Tao

Org. Lett. 2002, 4, 505-507.

146

5.Tuning of Regioselectivity in the Coupling Reaction Involving Allenic/Propargylic Palladium Species

Shengming Ma* and Aibin Zhang

J. Org. Chem. 2002, 67, 2287-2294.

149

6.Palladium(0)-Catalyzed Coupling-Cyclization Reaction of Polymer-Supported Aryl Iodides with 1,2-Allenyl Carboxylic Acids. Solid Phase Parallel Synthesis of Butenolides

Shengming Ma,* Dehui Duan, and Yizhong Wang

J. Combin. Chem. 2002, 4, 239-247.

157

7.Unexpected Dramatic Substituent Effect for Tuning of the Selectivity in the Double Ring-Closing Metathesis Reaction of N-Containing Tetraenes. An Efficient Synthesis of Bicyclic Izidine Alkaloid Skeletons

Shengming Ma* and Bukuo Ni

Org. Lett. 2002, 4, 639-641.

166

8.Efficient Synthesis of Benzocyclohexanes via Intramolecular Friedel-Crafts Reaction of Halogen Free 6-Acetoxy-4-alkenyl Arenes

Shengming Ma* and Junliang Zhang


169

9.Efficient Synthesis of 4-(2'-Alkenyl)-2,5-dihydrofurans, 5,6-Dihydro-2H-pyrans via the Pd-Catalyzed Cyclizative Coupling Reaction of 2,3- or 3,4-Allenols with Allylic Halides


J. Org. Chem. 2002, 67, 6104-6112.

173

10.Novel Oxidative Cyclization/Dimerization Reaction of 2,3-Allenoic Acids and 1,2-Allenyl Ketones. An Efficient Synthesis of 4-(3’-Furanyl)butenolide Derivatives

Shengming Ma* and Zhanqian Yu

Angew. Chem. Int. Ed. 2002, 41, 1775-1778.

182

11.Unexpected Sequential Addition-Elimination Reaction of 1-Aryl-2,3-allenols with LiX. Synthesis and Synthetic Application of 1-Aryl-3-Halo-1,3-dienes

Shengming Ma* and Guanwei Wang


186

12.Steric Hindrance-Controlled Pd(0)-Catalyzed Coupling-Cyclization of 2,3-Allenamides and Organic Iodides. An Efficient Synthesis of Iminolactones and -Hydroxy--lactams

Shengming Ma* and Hexin Xie

J. Org. Chem. 2002, 67, 6575-6578.

190

13.Efficient Preparation of Highly Optically Active S-(-)-2,3-Allenols and R-(+)-2,3-Allenyl Acetates via a Clean Novozyme-435-Catalyzed Enzymatic Separation of Racemic 2,3-Allenols.

Daiwang Xu, Zuyi Li, and Shengming Ma*

Chem. Eur. J. 2002, 8, 5012-5018.

194

14.Efficient Synthesis of Optically Active 2,3-Allenols via the Simple CuBr-Mediated Reaction of Optically Active Propargylic Alcohols with Paraformadehyde

Shengming Ma*, Hairong Hou, Shimin Zhao, and Guangwei Wang

Synthesis 2002, 1643-1645.

201

15.Tuning the Reaction Paths in Palladium(0)-Catalyzed Coupling-Cyclization Reaction of Amino Allenes with Organic Halides. A Substituent Switch


Org. Lett. 2002, 4, 2989-2992.

204

16． ntramolecular Triple Heck Reaction. An Efficient Entry to Fused Tetracycles with a Benzene Core

Shengming Ma* and Bukuo Ni

J. Org. Chem. 2002, 67, 8280-8283.

208

17. Palladium(0)–Catalyzed Three-Component Tandem Double Addition-Cyclization

Reaction: A Facile One–Pot Highly Chemo-, Regio- and Stereo-selective Synthesis of Cis-Pyrrrolidine Derivatives from 2-(2’,3’-Dienyl)malonates, Organic Halides, and Imines

Shengming Ma* and Ning Jiao

Angew. Chem. Int. Ed. 2002, 41, 4737-4740.

212

18.联烯化学进展

麻生明*

中国科学进展，2001，15，30-31.

216

19. 1,2-联烯亚砜和1,2-联烯砜的反应

Qi Wei and Shengming Ma*

Chin. J. Org. Chem. (有机化学) 2002, 22, 254-261.

218

20.Ru催化的C-H键的活化反应

Activation Reactions of Ru-catalyzed Arylic or Olefinic C-H Bonds

Shicao Yu and Shengming Ma*


226

21.光学活性炔丙醇的合成

Synthesis of Optically Active Propargylic Alcohols

Qiwen He and Shengming Ma*


237

22.Accurate Mass Determination of Amino Alcohol Derivatives by Turboionspray/Time-of-Flight Mass Spectrometry

Geng Yu, Yin-Long Guo*, Shimin Zhao, and Shengming Ma*

Chin. J. Chem. 2002, 20, 272-276.

250

23.Dramatic Solvent Effect in the Reduction of 2,3-Allenoic Acid Esters. A Simple Synthesis of 2,3-Allenols from 2,3-Allenoates

Shaohu Yin, Shengming Ma,* Ning Jiao, and Fenggang Tao

Chin. J. Chem. 2002, 20, 707-710 .

255

24.The Synthesis of (+) or (-)-2-(8'-Diphenylphosphinonaphthyl-1')oxazoline Ligands and Their Application in Pd-Catalyzed Allylic Alkylation Reaction

Shengming Ma* and Dehui Duan

Chin. J. Chem. 2002, 20, 1363-1368.

259

课题负责人：侯雪龙课题编号： 2002-04

1.A Facile Synthesis of Enantiopure 2-Aziridinesulfinimines and Their Highly Diastereoselective Reactions with Phosphite Anions

Bin-Feng Li, Ming-Jie Zhang, Xue-Long Hou and Li-Xin Dai

J. Org. Chem., 2002, 67, 2902-2906.

265

2.Tributylphosphine: A Remarkable Promoting Reagent for Ring Opening Reaction of Aziridines

Xue Long Hou*, Ren-Hua Fan, Li-Xin Dai

J. Org. Chem., 2002, 67, 5295-5300.

270

3.The Role of Planar Chirality of S, N- and P, N-Ferrocene Ligands in Palladium-Catalyzed Allylic Substitutions

Shu-Li You, Xue-Long Hou,*, Li-Xin Dai,*, Yi-Hua Yu and Wei Xia

J. Org. Chem., 2002, 67, 4684-4695.

276

4.Stereocontrolled Aziridination of Imines via Sulfonium Ylide Route and the Mechanistic Study

Xiao-Fang Yang, Ming-Jie Zhang, Xue-Long Hou* and Li-Xin Dai

J. Org. Chem., 2002, 67, 8097-8103.

288

5. Reaction of (-Carbanion of Imines with N-Tosylimines: A Facile Route to (-Amino Aldehydes and 1,3-Diamines

Xue-Long Hou* Yu-Mei Luo, Ke Yuan and Li-Xin Dai

J. Chem. Soc., Perkin 1, 2002, 1487-1490.

295

6.New Chiral N, S-Ligands with Thiophenyl at Benzylic Position Palladium (II)-Catalyzed Enantioselective Allylic Alkylation

Hao Wu, Xun-Wei Wu, Xue-Long Hou*, Li-Xin Dai and Quan-Rui Wang

Chin. J. Chem., 2002, 20, 816-818.

299

课题负责人：沈延昌课题编号： 2002-05

1. New Polyfluorinated Organotin Reagents. Stereoselective Synthesis of

Z--fluoro--trifluoromethylvinylstannanes

Yanchang Shen, Guoping Wang

Org. Lett. 2002, 4, 2083-2085.

302

2.A Convenient Synthesis of Perfluoroalkylated Indolizinylphosphonates

Yanchang Shen, Yuming Zhang, Guo-Fang Jiang

Synthesis 2002, 714-716.

305

3. A Convenient Stereocontrolled Route to Trifluoromethylated Penta-2E,4E- or

2Z,4E-dienenitriles

Yanchang Shen, Yuming Zhang, Jie Sun

Synthesis 2002, 2674-2680.

308

4. Regiospecific Synthesis of Perfluoroalkylated Pyrrolo[2,1-a]isoquinolinyl

phosphonates

Yanchang Shen, Yuming Zhang, Jie Sun

J. Fluorine Chem. 2002, 116, 157-161.

315

5. “One-pot” Synthesis of (Z)-2-Aryl-1-(2-cyanoethyl)ethenylphosphonates via

Hexamethylphosphoramide-promoted Sequential Transformation

Guoping Wang, Yanchang Shen

Heteroatom Chem. 2002, 13, 116-119.

320

6. Regiocontrolled Reaction of Allylic Phosphonate: Synthesis of 3-Methoxycarbonyl-

1,3-dienylphosphonates and 1-[(3-Methoxycarbonyl)-allyl-vinylphosphonates

Yanchang Shen, Guo-Fang Jiang


324

7. Reaction of Grignard reagents with Diethyl Perfluoroacyl(1-cyanoethnyl) phosphonates. Synthesis of Perfluoroalkylated -Unsaturated Nitriles with Predominant Z-Selectivity

Shen, Yanchang Jiang, Guo-Fang

Chin. J. Chem. 2002, 20, 1375-1378.

328

课题负责人：陈家碧课题编号： 2002-06

1.Remarkable Reactions of Cationic Carbyne Complexes of Manganese, Rhenium,and Diiron with Carbonylmetal Anions.

Jiabi Chen*, Ruitao Wang Coordination Chemistry Reviews, 2002, 231(1-2), 109-149.

332

2. Novel Reactions of Cationic Carbyne Complexes of Manganese and Rhenium with Polymetal Carbonyl Anions. An Approach to Trimetal Bridging Carbyne Complexes

Nu Xiao, Qiang Xu, Susumu Tsubota, Jie Sun and Jiabi Chen*

Organometallics, 2002, 21, 2764-2772.

373

3.Remarkable Nucleophilic Addition to and Ring-breaking of Cycloheptatrienyl

ligand in Reactions of (-[1-3-(:4-7-(-Cycloheptatrienyl]tricarbonyliron-

tricarbonylmanganeseand -rhenium with Aryllithium Reagents

Nu Xiao, Shu Zhang, Zhilei Qiu, Ronghua Li, Beihan Wang, Qiang Xu, Jie Sun and Jiabi Chen*


382

4. Novel N-Nucleophilic Addition to and Ring-Breaking of Coordinated Cycloocta- tetraene in Diiron Bridging Carbyne Complexes

Shu Zhang, Qiang Xu, Jie Sun, and Jiabi Chen*,


389

5. Unusual Reactions of Cationic Bridging Carbyne Complexes of Dimethylsilane-bridged Bis((5-cyclopentadienyl)diiron Tricarbonyl with

Carbonylmetal Anions.

Ruitao Wang, Jie Sun, Jiabi Chen*, Qiang Xu, Yoshie Souma

J. Organomet. Chem., 2002, 658, 214-227.

392

课题负责人：邓敏智课题编号： 2002-07

1． Remarkable co-catalystis by copper(I) oxide in the palladium catalyzed

cross-coupling of arylboronic acid with ethyl bromoacetate

Xing-xin Liu and Ming-zhi Deng

Chem. Commun., 2002, 622-623.

406

2． A Novel Method for the Construction of (Z,E)- or (Z,Z)-Conjugated Alkadienyl

Carboxylates

Rong He and Ming-zhi Deng

Org. Lett, 2002, 4, 2759-2762.

408

3． Rong He and Ming-zhi Deng, Selective reduction of stereodefined cyclopropyl

substituted acrylate esters to the corresponding propionate esters

Rong He and Ming-zhi Deng

Tetrahedron, 2002, 58, 7613-7617.

412

4． Facile Stereoselective Syntheses of Aryl Substituted (,(-Unsaturated Esters

Containing a Trifluoromethyl Group

Rui-qi Pan, Ping-an Wang and Ming-zhi Deng

Heteroatom Chemistry, 2002, 13, 287-290.

417

5．高能量密度材料二硝基氧化偶氮呋咱的合成研究

王家坡，邓敏智

含能材料，2002, 10(2), 56-58.

6．四唑类铅铜锶盐的制备及其在固体推进剂中的应用试探

杜恒，邓敏智

固体火箭技术，2002, 4, 147-149.

7． 4-羟基-3,5-二硝基吡啶氮氧化物铅及铜盐的合成

郑玉梅，邓敏智

火炸药学报，2002, 25(4), 51-52.

课题负责人：姜标课题编号： 2002-08

1. Enantioselective Synthesis of Marine Indole Alkaloid Hamacanthin B

Jiang Biao; Yang Cai-Guang; Wang Jun

J. Org. Chem. 2002, 67, 1396-1398.

421

2. High Diastereoselectivity in Intermolecular Carbonyl Ylide Cycloaddition with Aryl Aldehyde Using Methyl Diazo(trifluoromethyl)acetate

Jiang Biao; Zhang Xiaobing; Luo Zhaohui

Org. Lett. 2002, 4, 2453-2455.

424

3. Structure-Based 3-D-QSAR Analysis of Marine Indole Alkaloids

Jiang Biao; Xiong Wen-Nan; Yang Cai-Guang; Jiang Hua-Liang; Cheng Feng;

Chen Kai-Xian

Bioorganic and Medicinal Chemistry 2002, 10, 2775-2778.

427

4. Enantioselective alkynylation of a prochiral ketone catalyzed by C2-symmetric diamino diols

Jiang Biao; Feng Yan

Tetrahedron Letters 2002, 43, 2975-2977.

431

5. Asymmetric aminohydroxylation of vinyl indoles: a short enantioselective synthesis of the bisindole alkaloids dihydrohamacanthin A and dragmacidin A,

Yang Cai-Guang; Wang Jun; Tang Xiao-Xia; Jiang Biao

Tetrahedron: Asymmetry 2002, 13, 383-394.

434

6. Enantioselective synthesis of the aminoimidazole segment of dragmacidin D

Yang Cai-Guang; Wang Jun; Jiang Biao


446

7. Regio- and stereoselective synthesis of chiral ((S)-(Z)-trifluoromethyl-(-aryl-

enamines

Jiang Biao; Zhang Fangjiang; Xiong Wennan

Tetrahedron 2002, 58, 261-264.

450

8. Stereoselective synthesis of (Z)-trifluoromethyl enamines and their Lewis

acid-mediated conversion into (E)-isomers


Tetrahedron 2002, 58, 265-270.

454

9. The regio- and stereoselective addition of carbon nucleophiles to trifluoromethyl

phenylsulfanyl acetylene: a novel and expeditious approach to 3-trifluoromethyl furans



460

10. Highly Enantioselective Alkynylation of Keto Ester: An Efficient Method for

Constructing a Chiral Tertiary Carbon Center

Jiang, Biao; Chen, Zili; Tang, Xiaoxia

Org. Lett. 2002, 4, 3451-3453.

463

11. Highly enantioselective alkynylation of aldehydes catalyzed by a readily available chiral amino alcohol-based ligand

Biao Jiang, Zili Chen, Wennan Xiong

Chem. Commun. 2002, 1524-1525.

466

12. Zn(ODf)2: preparation and application in asymmetric alkynylation of aldehydes

Zili Chen, Wennan Xiong, Biao Jiang

Chem. Commun. 2002, 2098-2099.

468

13. Methyl 3,3-difluoro-2-trimethylsilyloxyacrylate: preparation and Mukaiyama-type

aldol condensation as a novel route to difluoro-keto ester derivatives

Biao Jiang, Xiaobing Zhang and Guoqiang Shi

Tetrahedron Letters 2002, 43, 6819 – 6821.

470

14. Alkynylation of carbonyl compounds with terminal acetylenes promoted by ZnCl2

and Et3N: simple, mild and efficient preparation of propargylic alcohols

Biao Jiang and Yu-Gui Si


473

15. Enantioselective Synthesis of Slagenins A-C

Jiang, Biao; Liu, Jia-Feng; Zhao, Sheng-Yin

Org. Lett. 2002, 3951-3953.

476

16. Catalytic Diastereoselective Pauson-Khand Reaction: an Efficient Route to

Enantiopure Cyclopenta[c]proline Derivatives

Jiang Biao; Xu Min

Org. Lett. 2002, 4077-4080.

479

17. A Convenient Synthesis of N-Fluorenylmethoxycarbonyl-N-Methyl-L-Cysteine

Derivatives [Fmoc,Me-Cys(R)-OH]

Jia-Feng Liu, Xiao-xia Tang, Biao Jiang

Synthesis 2002, 1499-1501.

483

18. A Convenient Procedure for Preparation of a Novel Allylphenoxytriazine Monomer

and the Properties of Its Copolymer with Bismaleimide(BMI)

Qiang Fang, Biao Jiang, Yi-Hua Yu, Xiao-Bing Zhang, Lu-Xia Jiang

J. Appl. Polym. Sci. 2002, 86, 2279-2284.

486

19. Preparing Functional Bis(indole) Pyrazine by Stepwise Cross-coupling Reactions: An

Efficient Method to Construct the Skeleton of Dragmacidin D

Cai-Guang Yang, Gang Liu, and Biao Jiang

J. Org. Chem. 2002, 67, 9392-9396.

492

20. Zn(II)-Mediated Alkynylation-Cyclization of o-Trifluoroacetyl Anilines: One-Pot

Synthesis of 4-Trifluoromethyl-Substituted Quinoline Derivatives

Biao Jiang and Yu-Gui Si

J. Org. Chem. 2002, 67, 9449-9451.

497

课题负责人：施敏课题编号： 2002-09

1.Titanium(IV) Bromide and Boron(III) Tribromide Promoted Baylis-Hillman Reactions of Arylaldehydes with 3-Butyn-2-one.

Min Shi* and Chun-Jiang Wang

Helv. Chim. Acta, 2002, 85, 841-846.

500

2.The Reaction of Amines with Benzyl Halides Under CO2 Atmosphere.

Min Shi* and Yu-Mei Shen

Helv. Chim. Acta, 2001, 84, 3357-3365.

506

3.C2-Symmetric Dialkoxyphosphoramide and Dialkoxythiophosphoramide Derivatives of (1R, 2R)-1,2-Diaminocyclohexane as Chiral Ligands for the Titanium(IV) Alkoxide-promoted Asymmetric Addition Reactions of Diethylzinc to Arylaldehydes.

Min Shi,* Xiao-Feng Wu, and Guobin Rong

Chirality, 2002, 14, 90-95.

515

4.Lewis Base and L-Proline Co-Catalyzed Baylis-Hillman Reaction of Arylaldehydes with Methyl Vinyl Ketone.

Min Shi,* Jian-Kang Jiang, and Chao-Qun Li

Tetrahedron Lett., 2002, 43, 127-130.

521

5.The Synthesis of New Chiral Rhodium Complexes and Their Crystal Structures

Min Shi* and Gui-Xin Lei

Applied Organometa. Chem., 2002, 16, 55-60.

525

6.Titanium(IV) Chloride, Boron(III) Chloride, Zirconium(IV) Chloride and Amine-Promoted Baylis-Hillman Reaction.

Min Shi,* Jian-Kang Jiang, and Shi-Cong Cui

Molecules, 2001, 6, 852-868.

531

7.Transition Metal Catalyzed Reactions of Propargylamine with Carbon Dioxide and Carbon Disulfide.


J. Org. Chem., 2002, 67, 16-21.

548

8.Perfluorinated rare earth metals catalyzed nitration of aromatic compounds.

Min Shi* and Shi-Cong Cui

J. Fluor. Chem., 2002, 113, 207-209.

554

9.VO(acac)2 Catalyzed Oxidative Coupling Reactions of Phosphonium Salts.

Min Shi* and Bo Xu

J. Org. Chem., 2002, 67, 294-297.

557

10. Axially Dissymmetric Binaphthyldiimine Chiral Salen Type Ligands For

Copper-Catalyzed Asymmetric Aziridination.

Min Shi,* Chuan-Jiang Wang, and Albert S. C. Chan

Tetrahedron:Asymmetry, 2001, 12, 3105-3111.

561

11. Reactions of 5,5-dimethyl-4-methylene-1,3-dioxolan-2-one with amines in the

presence of palladium catalyst.

Min Shi,* Yu-Mei Shen, and Ya-Jun Chen

Heterocycles, 2002, 57, 245-257.

568

12. Lewis base effects in the Baylis-Hillman reaction of imines with methyl vinyl

ketones.

Min Shi* and Yong-Mei Xu

Eur. J. Org. Chem., 2002, 696-701.

581

13. The reactions of thiols and diphenyldisulfide with the terminal substituted

methylenecyclopropanes.

Bo Xu, Yu Chen† and Min Shi*


587

14. Baylis-Hillman Reaction of Arylaldehydes with Phenyl Vinyl Ketone, Phenyl

Acrylate and Phenyl Thioacrylate.

Min Shi,* Chao-Qun Li, and Jian-Kang Jiang

Helv. Chim. Acta, 2002, 85, 1051-1057.

591

15.Synthesis of a Novel Copper(II) Complex and Its Crystal Structure.

Min Shi,* and Jian-Kang Jiang

J. Organometa. Chem., 2002, 650, 274-278.

598

16. Axially Dissymmetric (R)-(+)-5,5’,6,6’,7,7’,8,8’-Octahydro-[1,1’]

binaphthyldiimine Chiral Salen Type Ligands For Copper-Catalyzed Asymmetric

Aziridination.

Min Shi* and Chun-Jiang Wang, Chirality, 2002, 14, 412-416.

603

17. A Novel Reaction of 1,8-Diazabicyclo[5.4.0]undec-7-ene [DBU] or 1,5-Diazabicyclo

-[4.3.0]non-5-ene [DBN] with Benzyl Halides in the Presence of Water.


Helv. Chim. Acta, 2002, 85, 1355-1363.

608

18. Electrophilic Aromatic Nitration Using Perfluorinated Rare Earth Metal Salts in

Fluorous Phase.


Chem. Commun., 2002, 994-995.

617

19. Baylis-Hillman reactions of N-arylidenediphenylphosphinamides with methyl vinyl

ketone, methyl acrylate, and acrylonitrile.

Min Shi* and Gui-Ling Zhao


619

20. Synthesis of Mixed Carbonate via a Three-Components Coupling of Alcohol, CO2,

and Alkyl Halide in the Presence of K2CO3 and Tetrabutylammonium Iodide.


Molecules, 2002, 7, 386-393.

623

21. The Lewis acids catalyzed ring opening reactions of methylenecyclopropanes with

alcoholic or acidic nucleophiles.

Min Shi* and Bo Xu

Org. Lett., 2002, 4, 2145-2148.

631

22. The diastereoselective Baylis-Hillman reaction of chiral non-racemic N-sulfinimines

with cyclopent-2-en-1-one.



635

23. Friedel-Crafts reaction catalyzed by perfluorinated rare earth metals.

Min Shi*, Shi-Cong Cui

J. Fluor. Chem., 2002, 116, 143-147.

641

24.Catalytic asymmetric Baylis-Hillman reaction of imines with methyl vinyl ketone and

methyl acrylate.


Angew. Chem. Int. Ed. Engl. 2002, 41, 4507-4510.

646

25.The First Synthesis and Isolation of

(=Bis(aryloxy)phosphinesulfenyl Iodide P-Sulfides) from the Reaction of S,S’ -(Diphenylstannylene) O,O,O’,O’-Tetraaryl Bis[phosphorodithioates] (=[(Diphenylstannylene)bis(thio)]bis[bis(aryloxy)phosphine P-Sulfides]) with N-Iodosuccinimide.

Min Shi* and Shinji Kato†

Helv. Chim. Acta, 2002, 85, 2559-2563.

650

26. A Novel Chiral Silver(I) Complex via the Reaction of Thiaxazolidinethione with

AgOAc.

Min Shi,* Jian-Kang Jiang and Gui-Ling Zhao

Eur. J. Inorg. Chem., 2002, 3264-3267.

655

27. Lewis base effects in the Baylis-Hillman reaction of arylaldehydes and

N-arylidene-4-methylbenzenesulfonamides with -unsaturated cyclic ketones.

Min Shi,* Yong-Mei Xu, Gui-Ling Zhao and Xiao-Feng Wu

Eur. J. Org. Chem., 2002, 3666-3679.

659

28. Titanium(IV) Bromide and Boron(III) Tribromide Promoted Reactions of

Arylaldehydes with 3-Butyn-2-one, Methyl Propiolate and Propynenitrile.


Tetrahedron, 2002, 58, 9063-9074.

673

29. A Novel Ring-Opening Reaction of Methylenecyclopropanes with Aromatic Amines

Catalyzed By Lewis Acids.

Min Shi,*a Yu Chen,b Bo Xua and Jie Tang,b


685

30. An Exploration of Asymmetric Baylis-Hillman Reaction Catalyzed by Quinidine

Derived Chiral Amine.

Min Shi* and Jian-Kang Jiang


691

31. Axially Dissymmetric Binaphthyldiimine Chiral Salen-Type Ligands For Catalytic

Asymmetric Addition of Diethylzinc to Aldehyde.



698

32. One pot aza-Baylis-Hillman reaction of arylaldehyde, diphenylphosphinamide with

methyl vinyl ketone in the presence of TiCl4, PPh3, and Et3N.

Min Shi* and Gui-Ling Zhao


704

33.The Reactions of DMSO with Arylaldehydes in the Presence of Sodium Hydride


J. Chem. Res., 2002, 422-427.

708

34. Boron(III) Tribromide or Titanium(IV) Bromide and Lewis Base Promoted

Baylis-Hillman Reaction.


Chin. J. Chem., 2002, 20, 277-285.

714

35. Axially Dissymmetric Chiral (R)-N,N′-Bis(2-hydroxy-3,5-di-tert-butyl-arylmethyl)-

1,1′- binaphthalene-2,2′-diamine as Chiral Ligands in the Reaction of Diethylzinc to aldehydes.

Min Shi,* Wei-Liang Duan,† and Rong, Guo-bin,†

Chin. J. Chem., 2002, 20, 1319-1325.

723

课题负责人：丁奎岭课题编号： 2002-10

1. Molecular assembly in an inclusion crystal of tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid

B. Ji, C. Du, Y. Zhu, K. Ding*

J. Chem. Cryst. 2000, 30, 783-788.

(该文章去年因抽印件未到，没有列入，今年抽印件刚到)。

730

2. Discovery of Exceptionally Efficient Catalysts for Solvent-free Enantioselective Hetero-Diels-Alder Reaction

J. Long, J. Hu, X. Shen, B. Ji, K. Ding

J. Am. Chem. Soc. 2002, 124, 10-11.

736

3. To Probe the Origin of Activation Effect of Carboxylic Acid and (+)-NLE in Tridentated Titanium Catalyst Systems

Yu Yuan, Xin Li, Jie Sun, and Kuiling Ding*

J. Am. Chem. Soc. 2002, 124, 14866-14867.

738

4. Dramatically Synergetic Effect of Carboxylic Acid Additive on Tridentate Titanium Catalyzed Enantioselective Hetero-Diels-Alder Reaction: Additive Acceleration and Nonlinear Effect

Yu Yuan, Jiang Long, Jie Sun, and Kuiling Ding*

Chem. Eur. J., 2002, 8, 5033-5042.

740

5. 3,3’-Br2BINOL-Zn Complex: A highly Efficient Catalyst for Enantioselective Hetero-Diels-Alder Reaction

Haifeng Du, J. Long, J. Hu, X. Li, K. Ding

Org. Lett., 2002, 4, 4349-4352.

750

6. Acid-free Hetero-Diels-Alder Reaction of Danishefsky’s Diene with Imines

Y. Yuan, X. Li, K. Ding

Org. Lett., 2002, 4, 3309-3311.

754

7. Synthesis of A New Type of Chiral Amino Phosphine Ligands for Asymmetric Catalysis

Yi Wang, Xin Li and Kuiling Ding*

Tetrahedron Asymmetry, 2002, 13, 1291-1297.

757

8. A New Method for Optical Resolution of BINOL by Molecular Complexation with (S)-5-Oxopyrrolidine-2-carboxanilide

Haifeng Du, Yang Wang, Jie Sun, Jiben Meng and Kuiling Ding*

Tetrahedron Lett., 2002, 43, 43, 5273-5276.

764

9. The synthesis of a new generation of MAP ligands containing two types of chiral elements for asymmetric catalysis

Y. Wang, X. Li, K. Ding*


768

10. The Synthesis of Aminophosphine Ligands with Binaphthyl Backbones for Silver(I)-catalyzed Enantioselective Allylation of Benzaldehyde

Yi, Wang, Baoming Ji, Kuiling Ding*

Chin. J. Chem. 2002, 20, 1300-1312.

771

课题负责人：唐勇课题编号： 2002-11

1. A novel Chiral Sulfonium Ylide: Highly Enantioselective Synthesis of Vinylcyclopropanes

S. Ye, Zheng-Zheng Huang, Chun-An Xia, Y. Tang*, L.-X. Dai

J. Am. Chem. Soc. 2002, 124, 2432-2433.

784

2. Side Arm Approach in Ligand Design and Pseudo-C3-symmetry in Asymmetric Catalysis

Jian Zhou, Yong Tang*

J. Am. Chem. Soc. 2002, 124, 9030-9031.

786

3. Wittig-Type Olefination Catalyzed by PEG-telluride

Zheng-Zheng Huang, Song Ye, Wei Xia, Yi-Hua Yu, Yong Tang*

J. Org. Chem. 2002, 67, 3096-3103.

788

4. An Unexpected Catalyst for Wittig-type Reaction and Dehalogenation

Zheng-Zheng Huang, Yong Tang*

J. Org. Chem. 2002, 67, 5320-5326.

796

5. Telluronium Ylides in Cyclopropanation and Catalytic Olefination

Yong Tang*, Song Ye, Zheng-Zheng Huang, Yao-Zeng Huang


803

课题负责人：张兆国课题编号： 2002-12

1．钯催化的酰胺羰基化反应

王峰,张兆国

有机化学, 2002, 8, 536-542.

807

课题负责人：赵刚课题编号： 2002-13

1. Enantioselective reduction of (–keto sulfones using NaBH4/ Me3SiCl system

catalyzed by polymer-supported chiral sulfonamide

Gang Zhao*, Jian-bing Hu, Zhan-shan Qian and Wei-xing Yin

Tetrahedron Asymmetry, 2002, 13, 2095-2098.

814

课题负责人：许旭课题编号： 2002-14

1. 美国药典中的毛细管电泳法

王前，许旭*

药学进展，2002，26(5)：308-310.

818

课题负责人：宋礼成课题编号： 2002-15

1. Reactions of Butterfly Complex Anions of Type [((-RTe)((-CO)Fe2 (CO)6]- with Electrophiles. A New Route to (4-Se-Containing Double-Butterfly Clusters. Crystal Structures of ((-p-MeC6H4Te)((-PhCH2S C=S)Fe2(CO)6 and [((-RTe)Fe2(CO)6]2 ((4-Se) (R = Ph, p-BrC6H4 )

Li-Cheng Song, Qing-Mei Hu, Hong-Tao Fan, Ming-Yi Tang , Zhi-Yong Yang and Guo-Liang Lu

Organometallics, 2002, 21(12), 2468-2472 .

821

2. Syntheses and structural characterization of transition metal tetrahedral clusters

((5-RC5H4)(CO)8MoRu2H((3-S) and [((5-RC5H4) (CO)4MoRu((3-S)]2 generated by isolobal reactions

Li-Cheng Song, Guang-Huai Zeng, Qing-Mei Hu, Hua-Wei Cheng, Hong-Tao Fan

J. Organomet. Chem., 2002, 656, 228-233.

826

3. Syntheses and Characterizations of Novel One-dimensional Coordination Polymers

Self-assembling from Co(NCS)2 and Flexible Diester-bridged Pyridine-based Ligands

SONG, Li-Cheng, ZHANG, Wen-Xiong, HU, Qing-Mei

Chin. J. Chem., 2002, 20, 1421-1429.

832

课题负责人：黄宪课题编号： 2002-16

1. Polystyrene-Supported Benzyl Selenide; An Efficient Reagent for Highly

Stereocontrolled Synthesis of Olefins and allylic Alcohols

Huang, X.; Xu, W. M.


841

2. Polystyrene-Supported Selenosulfonates: Efficient Reagents for the Synthesis of Acetylenic Sulfones

Qian, H.; Huang, X.


844

3. Solid-Phase Synthesis of 4 (1H) –Quinolone and Pyrimidine Derivatives on a new Scaffold-Polymer-Bound Cyclic Malonic Acid Ester

Huang, X.; Liu, Z.-X.

J. Org. Chem., 2002, 67 (19), 6731-6737.

847

4. Stereoselective Michael-Aldol Tandem Reaction of Phenylselenomagnesium Bromide with Acetylenic Sulfones and Aldehydes. An Efficient Synthesis of Polyfunctionalized Allylic Alcohols

Huang, X.; Xie, M.-H.

Organic Lett., 2002, 4(8), 1331-1334.

854

5. Highly Stereoselective Three-Component Reactions of Phenylselenomagnesium Bromide, Acetylenic Sulfones, and Saturated Aldehydes/ketones or (, (-unsaturated Enals or Enones

Huang, X.; Xie, M.-H.

J. Org. Chem., 2002, 67 (25), 8895-8900.

858

6. Novel Tunable CuX2-mediated Cyclization Reaction of Cyclopropylideneacetic Acid, and Ester for the Facil Synthesis of 4-Halomethyl-2 (5H) – furanones and 4-Halo-5,6-dihydro-2H-pyran-2-ones

Huang, X.; Zhou, H.-W.

Organic Lett., 2002, 4, 4419-4422.

864

7. (Z)-(-Silyl-(, (-Unsaturated Ketones and Their Application in the Synthesis of 1, 4-Diketones

Zheng, W. X.; Huang, X.

Synthesis, 2002, 2497-2502.

868

8. Polystyrene-bound phenylseleninic acid: catalytic oxidation of aldehydes to carboxylic acids with hydrogen peroxide

Qian H.; Shao L.-X.; Huang X.

J. Chem. Research (S) 2002, 514-515.

874

课题负责人：沈琪课题编号： 2002-17

1 Synthesis, Reactivity, and Structure of Mixed-Ligand Ytterbium Complexes Supported by (-Diketiminate

Yingming Yao, Yong Zhang, Qi Shen, Kaibei Yu

Organometallics, 2002, 21(5), 819-824.

876

2 The Reactivity of (CH3C5H4)2LnNPh2(THF) (Ln = Y, Yb) with CS2 and PhNCS: Synthesis and Crystal Structures

Huanrong Li, Yingming Yao, Qi Shen, Linghong Weng

Organometallics, 2002, 21(12), 2529-2532.

882

3 Lanthanocene Amide Complexes as Single-Component Initiators for the Polymerization of (Dimethylamino)ethyl Methacrylate

Qi Shen, Yaorong Wang, Keda Zhang, Yingming Yao

J. Polym. Sci., Part A, Polym. Chem., 2002, 40(4), 612-616.

886

4 Synthesis, characterization of homoleptic lanthanide amidinate complexes and their catalytic activity for the ring-opening polymerization of (-caprolactone

Yunjie Luo, Yingming Yao, Qi Shen, Jie Sun, Linhong Weng

J. Organomet. Chem., 2002, 662, 144-149.

891

5 Synthesis and Reactivity of Organolanthanoid Complexes Containing N and S Ligands

Qi Shen, Yingming Yao

J. Organomet. Chem., 2002, 647, 180-189.

897

6 Synthesis and Structure of 1-Cyclopentylindenyl Lanthanide(II) Complexes and Their Catalytic Behavior for Polymerization of Acrylonitrile

Qi Min-Hua, Shen Qi, Gong Xin-Qiang, Shen Zhi-Quan, Weng Lin-Hong

Chin. J. Chem., 2002, 20(6), 564-569.

907

课题负责人：康北笙课题编号： 2002-18

1. Chair- and boat-configurations of silver(I) complexes of ditopic ligand involving benzimidazolyl substituents

Cai, Y. P., Su, C. Y., Zhang, H. X., Zhou, Z. Y., Zhu, L. X., Chan, A. S. C., Liu, H. Q., Kang, B. S.

Z. Anorg. Allg. Chem., 2002, 628 (11), 2321-2328.

913

2. Supramolecular Architectures Based on trans-Oxamidato-Bridged Copper(II) Synthons and Intramolecular Synergism

Zhang, H. X., Kang, B. S., Chen, Z. N., Xu, A. W., Liu, H. Q.

Comments Inorg. Chem., 2002, 23 (3), 231-248.

921

3. Silver(I) complex of 1,6-bis(benzimidazol-2-yl)-2,5-dioxa-hexane with network structure self-assembled by hydrogen bond and (…( stacking

Cai, Y. P., Chen, C. L., Zhang, L., Xu, A. W., Liu, J., Su, C. Y., Zhang, H. X., Zhang,

L., Kang, B. S.

Inorg. Chim. Acta, 2002, 342, 107-113.

939

4. Diphosphine mediated assembly of multinuclear silver complexes containing the thiolato ligand 2-mercaptobenzoxazole (Hmbo)

Kang, B. S., Zhang, L., Deng, L. R., Wang, X. J., Zhang, H. X., Liu, H. Q.

Sci. in China, (Eng), 2002, 45(5), 488-493.

946

5. 芳基柔性二齿配体在金属超分子自组装中的结构调控作用

刘俊，谭海燕，陈春龙，刘红科，康北笙

化学通报，2002，65 (6)，385-390.

952

6. Synthesis, structure, and characterization of an Ag complex of a hetero-armed tripodal ligand with diphosphine participation

Zhang, L., Liu, J., Deng, L. R., Zhang, H. X., Cai, Y. P., Liu, H. Q., Kang, B. S., Acta Chim. Sinica, 化学学报，2002，60 (4), 566-568.

958

课题负责人：张永敏课题编号： 2002-19

1.Synthesis of sulfones from arenesulfonyl chlorides and alkyl halides using the Sm/HgCl2 bimetallic system

Zhang JM, Zhang YM*

J. Chem. Res.(S) 2001, 516-517.

961

2.Direct construction of a quaternary carbon center utilizing an organosamarium reagent

Li ZF, Zhang YM*


963

3.Samarium diiodide promoted reductive cyclization of nitrodisulfides with nitriles: A new route to benzothiazoles

Zhong WH, Zhang YM*, Chen XY

J. Indian Chem. Soc. 2001, 78, 316-318.

967

4.Samarium diiodide mediated reductive addition reaction of 1-(phenylsulfonylmethyl) benzotriazole and 1-(benzoyloxymethyl) benzotriazole to aldehydes and ketones

Li ZF, Zhang YM*

J. Chem. Res.(S) 2001, 522-524.

970

5.A novel method for the synthesis of vicinal disulfonamides promoted by metallic samarium in aqueous media

Liu X, Liu YK, Zhang YM*


973

6.Synthesis of 3H-pyrroles promoted by samarium/iodine (cat.) system

Xu XL, Zhang YM*

Synth. Commun. 2002, 32, 2643-2650.

976

7.Sm/TiCl4 system induced reductive coupling reactions: synthesis of tetraarylfurans

Li ZF, Zhang YM*, Liu YK

J. Indian Chem. Soc. 2002, 79, 188-189.

984

8.Low-valent titanium induced cyclization of dimeric dianions of anils with triphosgene: A safe and efficient method for the syntheses of substituted imidazolidine-2-ones

Li ZF, Zhang YM*

Synth. Commun. 2002, 32, 2613-2618.

986

9.Coupling reaction of aryl halides promoted by NiCl2/PPh3/Sm0

Zheng XL, Zhang YM*

J. Chem. Res.(S) 2002, 562-563.

992

10.Intermolecular deoxygenative coupling of diarylketones and arylamides induced by Sm/SmI2 system

Xu XL, Zhang YM*

Tetrahedron 2002, 58, 503-505.

994

11.Direct construction of quaternary carbon center utilizing an allylsamarium bromide reagent

Li ZF, Zhang YM*

Tetrahedron 2002, 58, 5301-5306.

997

12.Preparation of dihomoallylic secondary amines through samarium mediated allylation of oximes

Fan XS, Zhang YM*


1003

13.The synthesis of N-(1-allyl-3-butenyl)-N-aryl amines by addition of organosamarium reagents to formanilides

Li ZF, Zhang YM*

J. Chem. Res.(S) 2002, 297-298.

1007

14.Tetrahydrofuran ring opening with acyloxyphosphonium bromide catalysed by allylsamarium bromide: a novel and effective method for the preparation of 4-bromobutyl esters

Liu YK, Zhang YM*

J. Chem. Res.(S) 2002, 15-16.

1009

15.New procedure for the preparation of 2,3-dihydro-1,5-benzothiazepin-4(5H)-ones promoted by samarium diiodide

Zhong WH, Chen XY, Zhang YM*

Synth. Commun. 2002, 32, 1085-1090.

1011

16.Conversion of bis(o-nitrophenyl)diselenides to heterocycles containing selenium and nitrogen with the aid of samarium diiodide

Chen XY, Zhong WH, Zhang YM*


1017

17.Formation of 1,2-diketones by samarium diiodide promoted reaction of N-acylbenzotriazoles

Wang XX, Zhang YM*


1022

18.SmI2-mediated facile one-pot preparation of 2,4-diarylquinolines from 3-aryl-2,1-benzisoxazoles

Fan XS, Zhang YM*


1025

19.Samarium diiodide mediated reductive coupling of 2-nitro-1,3-diphenyl-2-propen-1-one: synthesis of quinolines

Wang XX, Zhang YM*

Synth. Commun. 2002, 32, 3617-3620.

1028

20.SmI2-mediated synthesis of 2,4-diarylpyrroles from phenacyl azides

Fan XS, Zhang YM*


1032

21.Facile synthesis of polysubstituted cyclopentenylamines or γ-hydroxyamides by samarium diiodide

Xu XL, Zhang YM*

Synth. Commun. 2002, 32, 1891-1897.

1035

22.Michael additions of active methylene compounds to chalcones promoted by samarium(III) iodide

Ma YM, Zhang YM*

Synth. Commun. 2002, 32, 819-823.

1042

23.A novel tandem reaction of chalcone with malononitrile or ethylcyanoacetate promoted by samarium (III) iodide and followed by samarium (II) iodide

Ma YM, Zhang YM*

J. Chem. Res.(S) 2002, 288-290.

1047

24.Samarium trriodide mediated dethiocyanation of phenacyl thiocyanates and its application in carbon-carbon bond formation reactions

Fan XS, Zhang YM*

J. Chem. Res(S). 2002, 439-441.

1050

25.Tetrahydrofuran ring-opening with acyloxyphosphonium iodide catalyzed by samarium triiodide

Liu YK, Zhang YM*

Org. Prep. Proced. Int. 2002, 34, 213-217.

1053

26.Samarium chlorides catalysed Biginelli reaction: one-pot synthesis of 3,4-dihydropyrimidin-2(1H)-ones

Fan XS, Zhang YM*

J. Chem. Res.(S) 2002, 79, 436-438.

1058

27.Sm/BiCl3 system mediated Reformatsky type reactions of α-bromoacetophenone with aldehydes in THF-H2O solvent

Zhang JM, Zhang YM*

Chin. J. Chem. 2002, 20, 111-113.

1061

28.Sm0/AlCl3(6H2O体系促进叠氮化合物的化学选择性还原：一种制备胺的新方法。

张纪明，张永敏

合成化学, 2002, 498-500.

1064

29.Samarium-promoted chemoselective reduction of aromatic nitro compounds in ionic liquid

Zheng XL, Zhang YM*

Chin. J. Chem. 2002, 20, 925-928.

1067

30.Efficient debromination of vicinal α, β-dibromo carboxylic acid derivatives with the Sm/HOAc system

Wang XX, Zhang YM*

Chin. Chem. Lett. 2002, 13, 499-500.

1071

31.Reductive cleavage. of the Te-Te bond in diphenyl ditelluride by the Sm/CrCl3(cat.) system: Preparation of telluroesters and unsymmetrical phenyltellurides

Liu YK, Zhang YM*

Chin. J. Chem. 2002, 20, 202-206.

1073

32.Catalytic HgCl2-samarium system induced reductive coupling of nitriles with nitro compounds

Zhang JM, Zhang YM*

Chin. Chem. Lett. 2002, 13, 97-100.

1078

33.Reductive coupling cyclization of 1,1-dicyanoalkenes promoted by Sm0/HgCl2 (cat.) system

Zhang JM, Zhang YM*

Chin. J. Chem. 2002, 20, 688-691.

1082

34.Facile preparation of homoallyl β ',γ '-unsaturated amines via 1,2-addition of α,β-unsaturated imines with allylsamarium bromide

Chen J, Zhang YM*

Chin. J. Chem. 2002, 20, 103-106.

1086

35.An efficient Mg/SmI2 catalytic system for the intermolecular deoxygenative coupling of amides and ketones

Xu XL, Zhang YM*

Chin. J. Chem. 2002, 20, 1463-1465.

1090

36.A simple access to chalcones via modified mukaiyama aldol condensation promoted by SmI3/TMSCl

Fan XS, Zhang YM*

Chin. J. Chem. 2002, 20, 198-201.

1093

37.Facile formation of ytterbium diiodide and its use in the synthesis of allyl selenides

Su WK, Zhang YM*, Zheng YF, et al.

Chin. J. Chem. 2002, 20, 174-177.

1097

38.Indium mediated conjugate addition of allyl bromide to nitroalkenes in DMF-H2O media

Zhang JM, Zhang YM*

Chin. J. Chem. 2002, 20, 296-298.

1101

39.Organic reactions mediated by low-valent vanadium reagents and their applications in organic synthesis

Fan XS, Zhang YM*

有机化学 2002, 22, 1-10.

1104

课题负责人：席振峰课题编号： 2002-20

1. One-pot synthetic route to homoallylketones via selective combination of alkyne, ethylene and aldehyde mediated by AlCl3 and zirconocene

Changjia Zhao, Tao Yu and Zhenfeng Xi

Chem. Commun., 2002, 142-143.

1114

2. Novel reaction patterns of carbon disulfide with organolithium compounds via

cleavage of C=S bonds or via cycloaddition reaction

Jinglong Chen, Qiuling Song and Zhenfeng Xi

Tetrahedron Letters, 2002, 43, 3533-3535.

1116

课题负责人：曹卫国课题编号： 2002-21

1.The Knovenagel Condensation Reaction of Aromatic Aldehydes with Malononitrile in the Absence of Solvent and Catalyzed by Grinding

Ren Zhongjiao, Cao Weiguo and Tong Weiqi

Synth. Commun., 2002, 32(22), 3475-3479.

1119

2.Stereoselective Synthesis of Cis-1-carbomethoxy-2-aryl-3,3-

dicycanocyclo-propanes

Ren Zhongjiao, Ding Weiyu, Cao Weiguo, Wang Sihui and Huang Zhijing

Synth. Commun., 2002, 32(20), 3143-3148.

1124

3.Stereoselective Synthesis of trans--Methoxycarbonyl--aryl--butyrolactones

Chen Yali, Ding Weiyu, Cao Weiguo and Lu Cheng

Synth. Commun., 2002, 32(13), 1953-1960.

1130

4.

A Simple Approach to Highly Stereoselective Synthesis of N,N’-substituted Bis(trans--Bisubstituted--butyrolactam)

Sun Xiao-Hua, Chen Ya-Li, Ding Wei-Yu and Cao Wei-Guo

合成化学(Chin. J. Synth. Chem.), 2002, 10(3), 216-219.

1138

课题负责人：周锡庚课题编号： 2002-22

1. Insertion of Carbodiimide into the Ln(C (-Bond of Organolanthanide Complexes. Synthesis, Reaction and Characterization of Organolanthanide Amidinates (C5H5)2Ln[tBuN(C(nBu)(NtBu] (Ln = Er, Gd, Y)

Jie Zhang, Ruyi Ruan, Zehuai Shao, Ruifang Cai, Linhong Weng, Xigeng Zhou*,


1142

2. Novel Cp2LnX(Mediated Coupling(Cyclization of Propargyl Bromide: A New

Construction of Benzene Ring Skeleton

Ruyi Ruan, Jie Zhang, Xigeng Zhou, Ruifang Cai

Chem. Commun., 2002, 538-539.

1147

3. Insertion into lanthanide-ligand bonds in organolanthanide chemistry

Xigeng Zhou, Ming Zhu

J. Organomet. Chem., 2002, 647, 28-49.

1149

4. Synthesis, structure and reactivity of ethylthioethylcyclo- pentadienyl lanthanide complexes Cpt2LnCl (Ln = Sm, Gd, Er) and CptLnCl2(THF)3 ( Ln = Gd, Er)

Xigeng Zhou, Lixin Zhang, Chunmei Zhang, Jie Zhang, Ming Zhu, Ruifang Cai, Zu-En Huang, Zixiang Huang, Qiangjin Wu

J. Organomet. Chem., 2002, 655, 120-126.

1171

课题负责人：庞震课题编号： 2002-23

课题负责人：王佰全课题编号： 2002-24

1. Synthesis and structures of cycloalkylidene-bridged biscyclopentadienyl tetracarbonyl diiron complexes C(CH2)n[((5-C5H4)Fe(CO)]2((-CO)2 ( n = 4, 5 and 6)

Xu, S., Zhang, J., Zhu, B., Wang, B., Zhou, X., Weng, L.

Transition Met.Chem., 2002, 27, 58-61.

1178

2. Synthesis, structure and polymerization catalytic properties of doubly bridged bis(cyclopentadienyl) dinuclear titanium and zirconium complexes

Xu, S., Dai, X., Wu, T., Wang, B., Zhou, X., Weng, L.

J. Organomet.Chem., 2002, 645, 212-217.

1182

3. Synthesis, structure and polymerization catalytic properties of germyl bridged bis(cyclopentadienyl) metallocenes

Xu, S., Dai, X., Wang, B., Zhou, X.

J. Organomet.Chem., 2002, 645, 262-267.

1188

4. A study of the reaction between phenyl substituted cyclopentadiene and iron pentacarbonyl: The unusual structure of (–complex ((4-C5Ph4H)Fe(CO)3

Xu, S., Yuan, F., Zhuang, Y., Wang, B., Li, Y., Zhou, X.

Inorg.Chem.Commun., 2002, 5, 102-104.

1194

5. Synthesis and polymerization catalytic properties of aryl-substituted tetramethylcyclopentadienyl zirconocenes

Deng, X., Wang, B., Xu, S. Zhou, X., Yang, L., Li, Y., Hu, Y., Li, Y., Zou, F.

J. Mol. Catal. A: Chem., 2002, 184, 57-64.

1197

6. 柄型金属有机化合物(V)锗桥连茚基及取代茚基锆化合物的合成及催化烯烃聚合

徐善生, 田公路, 王佰全, 周秀中, 梁波, 赵亮

高等学校化学学报, 2002, 23, 595-599.

1205

7. Synthesis and structure of a novel cluster with trigonal-bipyramidal Ge2Ru3 core accompanied by unusual cleavage of Ge-C bonds

Zhang, Y., Wang, B., Xu, S., Zhou, X.

Chin. J. Chem, 2002, 20, 1388-1392.

1210

8. 柄型金属有机化合物(VI)四甲基二硅氧桥连不对称茂金属化合物的合成, 结构及催化乙烯聚合

徐善生, 吴涛, 崔惠玲, 王佰全, 周秀中, 邹丰楼, 李杨

高等学校化学学报, 2002, 23, 1891-1895.

1215

9. 联苯基桥连双核茂锆化合物的合成及催化乙烯聚合

邓小斌, 徐善生, 王佰全, 周秀中, 杨玲, 李于飞, 胡友良

高等学校化学学报, 2002, 23, 2089-2092.

1220

10. 四甲基二硅桥连双环戊二烯基四羰基二铁的芳香异腈取代及热重排反应

徐善生, 杨柳, 李颖, 王佰全, 周秀中

化学学报, 2002, 60, 2197-2202.

1224

课题负责人：王绍武课题编号： 2002-25

1. 含茂基稀土金属有机络合物催化剂在有机合成中的应用

杨高升，盛恩宏，程林，周双六，孙益民，王绍武*

中国稀土学报，2002， 20， 97-106.

1230

课题负责人：秦金贵课题编号： 2002-26

1. Synthesis and Characterization of a Series of New Functional

Poly(ferrocenylenesilanes) for Nonlinear Optics

Liu Yun-Yang, Zhang Xuan, Tang Hong-Ding, Wang Ting-Jun, Qin Jin-Gui,

Liu Dao-Yu, Li Shao-Jun, Ye Cheng

Chin. J. Chem. 2002, 20, 1199-1204.

1240

课题负责人：殷元骐课题编号： 2002-27

课题负责人：甘良兵课题编号： 2002-28

1. Fullerenes as t-butylperoxy radical trap, metal catalysed reaction of t-butyl

hydroperoxide with fullerenes and formation of the first fullerene mixed peroxides C60(O)(OOt-Bu)4 and C70(OOt-Bu)10

Liangbing Gan, Shaohua Huang，Xiang Zhang, Aixin Zhang, Bichu Cheng, Hao Cheng, Xiaolei Li, Gao Shang

J. Am. Chem. Soc., 2002, 124, 13384-13385.

1246

课题负责人：范青华课题编号： 2002-29

课题负责人：朱成建课题编号： 2002-30

课题负责人：陈忠宁课题编号： 2002-32

1. Utilizing Diruthenium Components for the Design of Cyanide-linked Tri-and

Trtranuclear Organometallic Complexes with Multistep One-electronRedox Processes

Li-Yi Zhang, Jing-Lin Chen, Lin-Xi Shi, Zhong-Ning Chen*

Organometallics 2002, 21, 5919-5925.

1248

课题负责人：王磊课题编号： 2002-34

1. A novel metal samarium promoted reduction of sodium alkyl thiosulfates without activating agent in water

Wang Lei, Li Pinhua and Zhou Li


1255

课题负责人：廖世健

1. Extremely Active Catalysts for the Hydrogenation of Terminal Alkenes

Yin-Heng Fan, Shi-Jian Liao, Jie Xu, Fu-Dong Wang, Yan-Long Qian,

Ji-Ling Huang

J. Cat. 2002, 205, 294-298.

1258

2. Thermal Stability of Nano-KH Particles and Their Chemical Reactivities

Fan Yin-Heng, Liao Shi-Jian, Li Wei-Na, Xu Jie, Wang Fu-Dong

物理化学学报，2002， 18，55－58.

1263

PAGE

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