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    Chemiphase

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    Microbial Enhanced Oil Recovery-

    I

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    I I Introduction

    Strategy

    Challenges Forward

    Conclusion5

    2

    3

    4 Where Next

    1

    I I

    Case-Histories

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    F

    C

    C

    Why do we need to employ when we arealready producing oil?

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    Peak oil is the point in timewhen the maximum rate ofglobal petroleum extractionis reached, after which therate of production enters

    terminal decline.

    I E (IE) 2008 2013 I 2008, IEA 2020 2030C 20 .

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    After Peak Oil

    A

    . . William J. Cummings, Exxon-Mobil company spokesman, December 2005

    As Peak Oil is reached all the easily accessible oil has been extracted and further extraction usingconventional extraction techniques will become increasingly expensive.

    Finding New Reserves will prove more expensive and less attractive, transportation and refiningcosts are denting profits.

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    New Oil Reserves- a viable option?

    It is pretty clear that there is not much chance of finding any significant

    quantity of new cheap oil. Any new or unconventional oil is going to be

    expensive.

    Lord Ron Oxburgh, a former chairman of Shell, October 2008

    Known - 4 barrels consumed for every 1 barrel discovered.

    Conclusion- We need to extract as much oil from known sources

    as possible

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    15-50% of CRUDE OIL IN MOST RESERVOIRS

    HOW DO WE ACHIEVE BETTER RESULTS

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    : Reservoir drive comes from a number of natural mechanisms.

    These include:

    1. natural water displacing oil downward into the well,

    2. expansion of the natural gas at the top of the reservoir,

    3. expansion of gas initially dissolved in the crude oil,

    4. gravity drainage resulting from the movement of oil.

    , .

    During this stage typical oil recovery is between 5-25% of thetotal oil residing in the well.

    (525% )

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    (1025% )

    , . ;

    to increase reservoir pressure (replacing or increasing the natural reservoirdrive)

    to bring the oil to the surface.

    by natural gas injection, gas lift (which injects a mixture of gases intothe bottom of a production well, to reduce the overall density of fluid in the well-bore)

    is 10-25% of the total oil residing in the well

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    Using the best estimates of %yield, we can see that there is at least:

    50%

    C

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    Mid point

    2ndhalfWhen you plot the production of an aggregate of oil fields, it

    approximates a bell curve

    Top of the curve

    1sthalf

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    Many oil fields,have alreadypeaked.

    The US peakedin 1970.

    53 of 68 oilproducing

    countries are indecline.

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    B .

    Its a large deposit of stones or

    sandstone sandwiched between twolayers of impervious rock. Thehollow spaces between the stonesor sand are filled with thick andviscous oil.

    It takes time for oil to ooze fromzones of high pressure to the zoneof low pressure near the pipe.

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    Your Text here

    5-25% yield 10-50% yield 40-88% yield

    SecondaryExtraction

    H ?

    PrimaryExtraction

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    Thermal

    Chemical

    Gas Lift

    ?

    EOR Techniques

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    Partial EMORSuccess

    with water-flooding

    Field Studies1930-1940s

    No Technical

    ManagementControl

    Small Oilcompanies

    Inconclusive

    Lack ofunderstanding

    400 tests madeIn USA

    EMORHistory

    1920Claude Zobell

    EOR processes were thought as unpredictable with various limiting factors - such

    as microbe types, reservoir properties, fluid properties, infrequent testing

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    Employing EOR techniques will increase the life and productivity of a well.

    Fundamentally, the mechanisms that govern oil release due to beneficialmicrobial growth are very much the same as those proven anddemonstrable chemical and physical effects, derived from well known

    EOR techniques.

    Our programme can be manipulated to act in a number ofbeneficial ways;

    Producing bio-surfactants

    Producing bio-polymers Increasing the gas drive

    Bio-cracking

    Bio-film plugging

    Bio-competitive exclusion

    C ?

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    An oil field emptiesrapidly at the start and

    yields lots of oil.

    Then the flowslows downgradually.

    Towards the endthe flow eases to

    a trickle.

    An oil field yields itscontents over the years,

    something like this.

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    GP-ProBiologica1000

    Biology

    GP-ProSurF342

    CHEMISTRY

    H 2 ,

    AI GAI

    GAIN 30% Increase in Yield

    Product 1 Product 2

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    342

    Anti Scale &

    CorrosionAgents

    Product

    A

    PowerfulCleaner,Dewaxer &DeGreaser

    TransportingAgents forHeavier Oils &Asphaltenes

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    2

    30%

    342

    &

    &

    &

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    Oxidises H2S andminimises corrosion

    EnvironmentallyAcceptable

    Self Transporting

    throughOil pay-zones

    High Salinity and TempResistance

    Produces PowerfulBio-Surfactants

    For Descaling, Dewaxingand Oil Flow

    Title

    Part B

    GP-ProBiologica 1000

    Ability to degrade

    heavier oilsasphaltene,sto lighter,

    recoverable products

    30%

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    Test Data

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    Increase in oil production afterintroduction of MEOR

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    Live data from WeatherfordLive Data Logging System

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    More data available on request

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    Several different

    trialblends tested

    Daily productiondosage rates

    supplied

    Well monitoredfor noticeable

    changes

    Data collated by

    well operators

    3 different test periods,independently carried out at

    UKs 2nd largest operationCarried out in 2010/2012

    over three to 6 month trials

    MEOR Trials

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    2

    &

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    1.6%Increase ofOil to Water

    Ratio

    24%Increase

    In Oil ReductionSRB &H2S

    Levels

    MinimisedCorrosion

    And Scaling

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    Before During After

    OIL 136bpd

    Oil:Water 9:3

    H2S 500ppm

    SRB 1x108

    OIL 169bpd

    Oil:Water 11:9

    H2S 3ppm

    SRB 10-100

    OIL 140bpd

    Oil:Water 9:8

    H2S 200ppm

    SRB 1x104

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    For We Do Not Want To See The Sun Go Down On Your Oil Production !!!

    Our Proven Technology for Increasing Oil Well Yields

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    OUR MISSION

    Develop a SophisticatedDevelop a SophisticatedDevelop a SophisticatedDevelop a Sophisticated Programme forProgramme forProgramme forProgramme forthe existing International Marginal Production Oilthe existing International Marginal Production Oilthe existing International Marginal Production Oilthe existing International Marginal Production Oil----wellwellwellwellMarketMarketMarketMarket

    Increase oil production from Marginal fields by 30% orIncrease oil production from Marginal fields by 30% orIncrease oil production from Marginal fields by 30% orIncrease oil production from Marginal fields by 30% ormoremoremoremore

    The ExtraThe ExtraThe ExtraThe Extra----Production would be a direct result ofProduction would be a direct result ofProduction would be a direct result ofProduction would be a direct result ofharvesting the Extraharvesting the Extraharvesting the Extraharvesting the Extra HHHHeavieroileavieroileavieroileavieroil CCCComponents thatomponents thatomponents thatomponents thatnormally would remain down hole.normally would remain down hole.normally would remain down hole.normally would remain down hole.

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    ;

    C

    A C (E), :

    1. C D2. 3. D

    4. C 5. F.

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    C E B

    C D 150 $/

    I 130 $/

    E 145 $/

    105 $/

    A F I 102 $/

    2030 $/

    *I , I &

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    /

    /

    , & /

    &

    / &

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    I 30% G

    E D E

    , A

    C, F

    F E

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    C

    I ,

    I G

    :

    E , I

    D C, I ( )

    B, I F C, F

    !!

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    B ( ) & D & C C

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    (

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    C E A F E

    B F C &

    C E E, EA C

    E

    !!

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    I 15% , .

    E. G

    , , , .

    /I , .

    !!

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    F B

    , , , 70C. 90 D C.

    C2, , , .

    .

    !!

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    Cost versus Reward for various EOR techniques

    MEOR/Surfactant Projects

    from:S

    imandouxetal.(1990)Managing

    theCostof

    EnhancedOil

    Recovery.

    IFTJournal,vol

    1.

    Viscosiy

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    yModifiers

    Rig & Plant

    Cleaning

    AsphalteneDispersants

    Scale Controladditives

    Biocides &Microbiological

    treatments

    Waste WaterAdditives

    Corrosioninhibitors

    Wax/ParaffinRemovaladditives

    Antifoulants

    Refinery

    Demulsifiers

    Drilling

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    DrillingAdditives

    Rig & PlantCleaning

    AsphalteneDispersants

    MEOR & EORProgrammes

    Biocides &Microbiological

    treatments

    Chelant & Acidtreatments

    Corrosioninhibitors

    Wax/ParaffinRemovaladditives

    Demulsifiers

    Cetane

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    Improvers

    Antifoam

    Pour Pointadditives

    FuelPerformance

    packages

    Bio-PackageSpark

    Aids/antiwear

    Detergents

    CombustionImprovers

    FuelDehazers

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    Chemiphase Ltd