NMLD Dung Quat 2-09

8/13/2019 NMLD Dung Quat 2-09

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TP ON DU KH QUC GIA VIT NAM

VIN DU KH VIT NAM

TRUNG TM NGHIN CU V PHT TRIN CH BIN DU KHwww.pvpro.com.vn

12/22/2013

S LC V CNG NGH

NH MY LC DU DUNG QUT

Thc hin: Phng Cng ngh Lc duTrnh by: L Dng Hi


2/74

2RESEARCH & DEVELOPMENT CENTER FOR PETROLEUM PROCESSING

Vietnam Petroleum Institute

2TRUNG TM NGHIN CU V PHT TRIN CH BIN DU KH

NI DUNG

B tr mt bng

Phn xng cng ngh

H thng ph tr

Cht lng sn phm


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Btr mtbngnh myDin tch: 338ha


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Btr mtbngnh my

Khu bchaduth

Khu cc phn

xng phtr

Khu nh hnh

chnh

Khu bchasn

phmtrung gian

Cc phn xngcng ngh

Mrng

FlareRFCC, LTU,

NTU, PRU

SWS, ARU,

PRU, SRU

HDT-LCO CDU, KTUNHT, CCR,

ISOMXl chtthi

Nc-Kh nn-in


5/74




SPM v kho chaduth

SPM Tu Aframax (80.000 tn du th)

2 ng ng 50

Gia nhit ng ng n 50o

C

Bchaduth6bdung tch 59.000 m3

15 ngy vnhnh nh my


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Phn xngcng nghchnh

Unit K hiu Vai tr Cng sut thitk

Nh bnquyn

011 CDU Chngctduth 148.000 BPSD -012 NHT Xl naphtha 23.500 BPSD UOP013 CCR Reforming 21.100 BPSD UOP

014 KTU Xl Kerosene 10.000 BPSD Merichem015 RFCC Cracking cn 69.700 BPSD Axens/IFP016 LTU Xl LPG 21.000 BPSD Merichem017 NTU Xl naphtha RFCC 45.000 BPSD Merichem018 SWS Xl ncchua 82,91 m3/h -

019 ARU Ti sinh amin 102,5 m3

/h -020 CNU Trung ho cnthi 1,5 m3/h Merichem021 PRU Thu hipropylene 19.535 kg/h -022 SRU Thu hiluhunh 5 TPD -023 ISOM Isomer ho 6.500 BPSD UOP024 HDT-LCO Xl light cycle oil 28.826 BPSD Axens


7/747RESEARCH & DEVELOPMENT CENTER FOR PETROLEUM PROCESSING



Xng 95/92

Xng 90

Du th BchH hoc Dubai

(tia15%)

Scng ngh





CM PHN XNG CDU

X l 100% du chua Dubai (0,35%wt S)Linh hot thay i im ct

Cm thit b chnh

Tch mui

Thit b gia nhit du th

Thp chng ct chnh Thp n nh sn phm nh

Thp lm kh tch nc





CM PHN XNG CDU

Du th

LPG TO RFCC GAS

RECOVERY SYSTEM

FULL RANGE NAPHTHA TO NHT

T1005

T1006

T1107

D 1104

OFFGAS TO RFCCWCC

OFFGAS TO WCC ON RFCC

Corrosion inhibitor injection

KEROSENE TO BLENDING

HYDROCABON TO SLOP

LGO TO BLENDING

HGO TO STORAGE

RESIDUE TO STORAGE. RFCC

1

T1104

T1103

T1102

1

12

4

15

23

26

35

42

4348

11

22

34

38

T 1101

H 1101

E1112

E1116

E1122

SUPERHEAD LP STEAME1117

Antifoulant Injector

Neutraliser injection

Antiflouant Injector

Demulsifer Injector

OFFGAS TO H1101

D 1106




10TRUNG TM NGHIN CU V PHT TRIN CH BIN DU KHr

ISOMER

Heavy Naphtha

Hydrogen

CCR

NHT

Untreated

Naphtha

Reformate

Light Naphtha Isomerate

LPGSPLITTER

To LCO-HDT

Fuel Gas

Fuel Gas

REGEN

Regen

Cat

Spent Cat

CmNHT-ISOM-CCR





NHT

Sour gas

Feed Surge

Drum

Light Naphtha

Heavy Naphtha

Splitte

r

Re

actor

Charge

Heater

Stripper

Heater

Separator

Recycle gasCompressor

Full Range

Naphtha

MP Steam

Fuel

gas

Cooling

water

Receiver

Receiver

Strippe

r

Xc tc Co,Mo/Al2O3





Makeup Gas

Light naphtha

Reactors

Feed

Dryers

Net Gas Scruber

Dryers Isomerate

nC6, methyl C5 reprocessing

Clo

injection Stabilizer D

eisohexanizer

Methanator

To Fuel gas

Condenser

SurgeDrum Heater

ISOM

DIH process





CCR

Continuous Catalytic Reforming process





Xng 95/92

Xng 90


(tia15%)

Scng ngh





RFCC

Chuynho cnnngtCDU,cng nghRFCC hinicaIFP/StoneWebber (Axens) &

xl kh

Vnhnh chmaxdistillate/max gasoline (max

propylene?)

Cmthitbchnh Reactor/Regeneration Flue Gas Treatment Fractionation

Gas Recovery Section





RFCC (tt)

Nguyn liu vo phn xng: cn chng ct kh quyn(sch, paraffinic) v kh, LPG (vo gas plant)

Sn phm:

Kh: off-gas; LPG c cha propylene;

RFCC Naphtha giu olefin (RON: 91)

LCO (light cycle oil)

DCO (decant oil)

Xc tc: RE-USY (c Sn) vi lngb sung hng ngy5,5/15,2 tn





KTU

Xl kerosene: axit naphthenic, luhunh, ncvtpchtkhcttiu chunKero/JetA1

Cng nghMerichem vicc cmthitbchnh NAPFININGSM trung ho axit naphthenic

MERICAT IISM xl luhunhv loibmui

AQUAFINING loibcc muisodium cn st li

SALT DRIER khlngnctdo v gimlngncbo ho

CLAY FILTER loibcc htrncn li, him, muihuc, nhtng, chthotngbmt





LTU-NTU

LTU: X l LPG Loi b H2S, RSH, COS

Cng ngh tch loi Thiolex ca Merichem

Xc tc MEA

NTU: X l RFCC naphtha

Tch loi H2S v RSHRSSH

Cng ngh Mericat ca Merichem





HDT-LCO

X l tch loi lu hunh khi LCO, GO(LGO,HGO)

Hm lng S trong sn phm

Bch H: 20 50 ppm

Chua: 150 - 350 ppm

Hot ng lin tc, ti sinh xc tc sau 2 nmTui th xc tc: 5 nm





HDT-LCO

H2 Make-up

WashingWater

HEX

Quench streams

RecycleCompressor

Feed

Reactor

HPSeparator

Lean Amine

Dryer

MPS

Wild

Naph. To

RFCC/CD

U

StripperT-2401

Reactor Heater

H2 recycle

Treated LCO

To FG

18

To SWS

Rich

Amine

AmineAbs





PRU

Tch LPG thnh hn hp C4/propane v propylen v lmsch propylenesn xut nha PP

Thit b chnh

Thp tch C3/C4Thp tch C2-

Thp tch

propane/propylene

(190 a)


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Phn xngcng nghkhc

SOURWATER

FROM CDU

FROM NHT

FROM RFCC

FROM CCR

(NNF)

FROM

SOUR FLARE

(NNF)

CNU

SWS

SRUARU

DESALTER

SOUR WATER

TREATMENT

------

------

------

------

------

------TANK


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Xng 95/92

Xng 90


(tia15%)

Cc phn xngcng ngh

+ SRU,

SWS,

CNU,

ARU


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Cmphn xngphtr, tinch

Sn xut in, hi ncSn xut nit

Cung cp nc ngt

Cung cp nc binKho cha sn phm trung gian

H thng phi trn

Kho cha sn phm

Cng xut sn phm ,


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Bchatrung gian


26/74




Hthngphitrn

BLENDING

Fuel gas

BLENDING

Isomerate

Reformate

RFCC

naphtha

Kero

LGO

HGO

LCO

DCO

C4s


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ngngdnsnphm


28/74




Khu bchasnphm


29/74




Cngxutsnphm


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CHT LNG SN PHM XNG VDIESEL

Tiu chun cht lng sn phm ca nh my

Cht lng sn phm nh my

Tiu chun cht lng Vit Nam

Xu hng cht lng sn phm nhin liu


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EURO SPECIFICATION IN GASOLINE


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EURO SPECIFICATION IN DIESEL


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XNG

So snh vi TCVN: p ng v tt hn (MON)

So vi tiu chun Euro: EURO II and EURO III (tr olefin)

Tnh cht BchH Mixed

RON

MON

>= 90.2/92.2/95.2

81.2/83.2/85.2

Sulfur, ppm < 10Benzen, %vol


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DIESEL

Tnh cht Bach HoMG Bach HoMD MixedMG MixedMD

Cetane Index 55 53 53 50

Sulfur, ppm 154 147 1020 1482

ASTM D86

90%vol, oC

348 368 350 368

pnghuhtcc chtiu TCVN ngoi trim90%chngct

pngEURO III ividuBchHv EURO II viduMixed


35/74




Ktlun

NMLD Dung Qut c thit k vi cc phn xngcng ngh hin i, ch bin du ngt, parafinic vkhng c VDU, HDS gasoline FCC

Nh my cn c nhng vn cn gii quyt Ngun nguyn liu du th Bch H ang gim dn (thp hn

cng sut nh my)

Cht lng sn phm (tng lai)

S thiu ht cng sut ca phn xng CCR Cng sut hin ti ca SRU v cht lng kh thi khi chy duhn hp (mixed)

Mt s ti nghin cu ca PVPro phc v cho DQR
http://c/Documents%20and%20Settings/COMPUTER.LDHAI/Desktop/BSR-PVPRO.ppthttp://c/Documents%20and%20Settings/COMPUTER.LDHAI/Desktop/BSR-PVPRO.ppt


36/74




Ti liutham kho

Ti liu FEED 2004, EPCC 2006, OM 2007 ca DQR

Ti liu ging dy ca DQR

Raze Shadeghbeigi, Fluid Catalytic Cracking Handbook

Robert Meyer, Handbook of Petroleum Refining

Processes, 3rd Edition, 2003


37/74





38/74




Q & A


39/74




Sdng KTU


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Sdng KTU (tt)


41/74




SWS

FROM SOUR

FLARE PUMP OUT

P-1805

EFFLUENT

TREAMENT

FROM CDU

FROM NHT

FROM LCO-HDT

FROM RFCC

FROM CCR

LIGHT SLOPS

ANTI-FOAM

POLYSULPHIDE

P-1801 P-1802

D-1801

T-1802T-1801

E-1801P-1804

P-1803

E-1805E-1803

E-1804

E-1802

TK-1801

COLD CONDENSATE

TO SRU

TO INCENERATOR

TO CDU

DESALTER

KEROSENE

H2S

NH3

6.0

9090

1.2

6.3

165

1.7

130


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ARU

Rich Amine

To Light Slops

To Sour Flare

Boiler Feed Water

Flash Drum

Filter

Lean Amine Cooler

Condenser

Lean/Rich Amine

Ex E-1901

Reflux

Drum

Reboiler

E-1903A/B

Lean Amine

To Fuel Gas

Condensate

LP Steam

1

3

26

126.5

1. 2

1. 35

121

De-mineral

Water

Corrosion

Inhibitor

T-1901

E-1904

D-1901

E-1902

D-1902

S


43/74




SRU

Sn xut lu hunh t dng kh giu H2S i t cc phnxng SWS v ARU, t dng kh t ARU v CNU

Qu trnh Clauss

H2S + O2SO2 + H2O

H2S + SO2S + H2O

Cc b phn chnh Thu hi lu hunh

Cha v tch kh lu hunh lng

L thiu hu

Che chn lu hunh

CNU


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CNU

Trung ho kim v x l nc thi t cc phnxng KTU, LTU, CNU, NHT, LCO-HDT, nhmy x l nc thi

S dng cng ngh trung ho trit MIRICONca Merichem

Ph i


45/74




Phn xngsnxutin

Sn xut v cung cp in, hi nc

Nhin liu t l: FO hoc Fuel gas (C4 d)

in: 4 turbin hi cng sut 27 MW, cung cp 81MW

4 l hi: 196 T/h, 107 kg/cm3, 505oC cung cp hi

nc HHP, HP, MP v LPS dng thit b lm lnh bng nc bin

C t


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Cung cpncngt

246 m3/h

120 m3/h

99 m3/h

4 m3/h

C bi


47/74




Cung cpncbin

50.000 m3/h

34.500 m3/h

12.000 m3/h

22.500 m3/h

34.500 m3/h

22.500 m3/h

S t Nit


48/74




SnxutNit

Sn xut, tn cha v cung cp nit di dnglng, kh

Thit b lm lnh

Bn cha nit lng

Thit b bay hi nit lng

S t it


49/74




Snxutnit

347 m3/h

647 m3/h 10 ngyvn hnh

95 m3/h

F l t


50/74




Fuel gas system

Thu fuel gas

Ho hi off-spec LPG/Propylene v C4s d

Cung cp fuel gas cho l t gia nhit trong

cc phn xng cng ngh


51/74





52/74




Fl


53/74




Flare

B h h t i


54/74




Bchasnphmtrung gian

TT K hiu B cha Slngv Dung tch (m3)

Working Gross

1TK-5201 A/B/C

B cha Xng Mogas 92/95 xut cho tu (Mini)

03 x 22.970 03 x 30.085

2TK-5203 A/B/C

B cha Xng Mogas 90 xut cho tu (Mini)

03 x 30.012 03 x 38.867

3TK-5205 A/B/C

B cha JET A1/Kerosen xut cho tu (Mini trong)

03 x 9.558 03 x 13.644

4 TK-5207 A/B/C B cha Diezen t xut cho tu (Mi chp) 03 x 48.391 03 x 54.723

5 TK-5211 A/B B cha FO xut cho tu v xe bn (Mi chp) 02 x 8.299 02 x 9.649

6 TK-5212A/B/C/D/E B cha LPG xut cho tu (B cu) 05 x 4.510 05 x 4.949

7TK-5213 A/B/C

B cha Propylen xut cho tu v ng ng(B cu)

03 x 3.340 03 x 3.710

Tngcng: 22 b 381.961 467.130

B cha


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Bcha

SPM


56/74




SPM

Tham kho thmSPM

Flushing oil

SPM data

Item unit ExistingVessel size DWT 111.000

Unloading rate m3/hr 6.000

Cargo volume m3/ship 120.000

Unloading time hrs 20

Mooring work hrs


57/74




S CNG NGH RFCC..\Operating manual\8474L-015-ML-

001-1.pdf

58

FLUE GAS TREATMENT
http://localhost/var/www/apps/conversion/tmp/Operating%20manual/8474L-015-ML-001-1.pdfhttp://localhost/var/www/apps/conversion/tmp/Operating%20manual/8474L-015-ML-001-1.pdfhttp://localhost/var/www/apps/conversion/tmp/Operating%20manual/8474L-015-ML-001-1.pdfhttp://localhost/var/www/apps/conversion/tmp/Operating%20manual/8474L-015-ML-001-1.pdfhttp://localhost/var/www/apps/conversion/tmp/Operating%20manual/8474L-015-ML-001-1.pdfhttp://localhost/var/www/apps/conversion/tmp/Operating%20manual/8474L-015-ML-001-1.pdfhttp://localhost/var/www/apps/conversion/tmp/Operating%20manual/8474L-015-ML-001-1.pdfhttp://localhost/var/www/apps/conversion/tmp/Operating%20manual/8474L-015-ML-001-1.pdfhttp://localhost/var/www/apps/conversion/tmp/Operating%20manual/8474L-015-ML-001-1.pdfhttp://localhost/var/www/apps/conversion/tmp/Operating%20manual/8474L-015-ML-001-1.pdfhttp://localhost/var/www/apps/conversion/tmp/Operating%20manual/8474L-015-ML-001-1.pdfhttp://localhost/var/www/apps/conversion/tmp/Operating%20manual/8474L-015-ML-001-1.pdfhttp://localhost/var/www/apps/conversion/tmp/Operating%20manual/8474L-015-ML-001-1.pdfhttp://localhost/var/www/apps/conversion/tmp/Operating%20manual/8474L-015-ML-001-1.pdfhttp://localhost/var/www/apps/conversion/tmp/Operating%20manual/8474L-015-ML-001-1.pdf


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59

FLUE GAS TREATMENT

FRACTIONATION


59/74




60

FRACTIONATION

GAS RECOVERY


60/74



61TRUNG TM NGHIN CU V PHTTRIN CH BIN DU KH

GAS RECOVERY

61


61/74




TCVN

LPG6

548-1999

TCNM Gasoline


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TCNM Gasoline

TCVN 6776 : 2005


63/74




TCVN 6776 : 2005TT Tn ch tiu Xng khng ch

90 92 951 Tr s octan, min

- theo phng php nghin cu (RON)- theo phng php mt (MON)

90

79

92

81

95

84

2 Hm lng ch, g/l, max 0,013

3 Thnh phn ct phn on:- im si u, oC- 10% th tch, max- 50% th tch, max

- 90% th tch, max- im si cui, oC, max- Cn cui, % th tch, max

Bo co70

120

190

215

2.0

4 n mn mingng 50oC/3 gi, max

22/12/2013

TCVN 6776 : 2005


64/74




TT Tn ch tiu Xng khng ch

90 92 95

5 Hm lng nha thc t ( ra dung mi), mg/100ml, max.

5

6 n nh xy ha, pht, min. 480

7 Hm lng lu hunh, mg/kg, max 500

8 p sut hi (Reid) 37,8 oC, kPa 43 - 75

9 Hm lng benzen, %th tch, max 2,5

10 Hydrocacbon thm, %th tch, max 40

11 Olefin, %th tch, max 38

12 Hm lng xy, % khi lng, max 2,7

13 Hm lng kim loi, mg/l 5

14 Khi lng ring ( 15oC), kg/m3 Bo co

15 Ngoi quan Trong, khng c tp cht l

lngTp. H Ch Minh

TCVN 6776 : 2005

KEROSENE


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KEROSENE


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TCVN

JET6

426-200

7

TCVN DO 5689 2005
http://localhost/var/www/apps/conversion/Ch%E1%BA%A5t%20l%C6%B0%E1%BB%A3ng%20x%C4%83ng%20d%E1%BA%A7u/TCVN%20chat%20luong%20nhien%20lieu/TCVN%20JET%206426-2007.pdfhttp://localhost/var/www/apps/conversion/Ch%E1%BA%A5t%20l%C6%B0%E1%BB%A3ng%20x%C4%83ng%20d%E1%BA%A7u/TCVN%20chat%20luong%20nhien%20lieu/TCVN%20JET%206426-2007.pdfhttp://localhost/var/www/apps/conversion/Ch%E1%BA%A5t%20l%C6%B0%E1%BB%A3ng%20x%C4%83ng%20d%E1%BA%A7u/TCVN%20chat%20luong%20nhien%20lieu/TCVN%20JET%206426-2007.pdfhttp://localhost/var/www/apps/conversion/Ch%E1%BA%A5t%20l%C6%B0%E1%BB%A3ng%20x%C4%83ng%20d%E1%BA%A7u/TCVN%20chat%20luong%20nhien%20lieu/TCVN%20JET%206426-2007.pdf


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68TRUNG TM NGHIN CU V PHT TRIN CH BIN DU KH22/12/2013Tp. H Ch Minh 68

TT Tn ch tiu Mc

1 Hm lng lu hunh, mg/kg, max. 500 2500

2 Ch s xtan, min. 46

3 Nhit ct, oC, 90% th tch, max. 360

4 im chp chy cc kn, oC, min. 55

5 nht ng hc 40oC, mm2/ s 2 - 4,56 Cn cc bon ca 10% cn chng ct, %kl, max. 0,3

7 im ng c, oC, max. + 6

8 Hm lng tro, %khi lng, max. 0,01

9 Hm lng nc, mg/kg, max. 200

10 Tp cht dng ht, mg/l, max. 1011 n mn mnh ng 50oC, 3 gi, max. Loi 1

12 Khi lng ring 15oC, kg/m3 820 - 860

13 bi trn, m, max. 460

14 Ngoi quan Sch, trong

TCVN DO 5689-2005

Tiu chun nhmy


68/74




Tiu chunnh my

FO


69/74




FO

70

MAX GAS MAX DIS

BCH H 395 339

CHUA 5330 3756


70/74




TCVN

FO6

239-200

2

Din tch nh my


71/74




Dintch nh my

Khu ch bin, khu ph tr v nh iu hnh 110

Khubnchaduth v hthngFlare 42

Khubnchasnphm 36

Khu ly nc bin, x l nc thi, ng ngcng ngh, ng 44

Din tch cng xut sn phm 106

Tngcng(ha) 338

Phn xng cng ngh


72/74




Phn xngcng ngh

NTU


73/74




NTU

X l RFCC naphtha: tch loi H2S v RSHRSSH

Cng ngh Mericat ca Merichem

B cha sn phm


74/74


Bchasnphm

TT K hiu Bcha

S lng v Dung tch (m3)

Working Gross

1TK-5201 A/B/C

B cha Xng Mogas 92/95 xut cho tu (Mini)

03 x 22.970 03 x 30.085

2TK-5203 A/B/C

B cha Xng Mogas 90 xut cho tu (Mini)

03 x 30.012 03 x 38.867

3TK-5205 A/B/C

B cha JET A1/Kerosen xut cho tu (Mi nitrong)

03 x 9.558 03 x 13.644

4TK-5207 A/B/C B cha Diezen t xut cho tu (Mi chp) 03 x 48.391 03 x 54.723

5 TK-5211 A/B B cha FO xut cho tu v xe bn (Mi chp) 02 x 8.299 02 x 9.649

6 TK-5212

A/B/C/D/EB cha LPG xut cho tu (B cu) 05 x 4.510 05 x 4.949

7TK-5213 A/B/C

B cha Propylen xut cho tu v ng ng(B cu)

03 x 3.340 03 x 3.710