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7/31/2019 OMADA-3
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6 o
3
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(NATIVE COPPER: Cu )
1. : Cu Ag As
2. : .
3. :
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4. :
(. 6.1, 6.2)
5. : (60-90%),
As6. :
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6.1. ( Cu) (Cup ) ( ) ( )
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6. 2. ( ) , ( ) , ()
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7. : ,
, (. 6.3)
8. :
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9. :
) ) )
( . 6.3) )
, , ,
, ( . 6.4) )
(111)
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6.3. ( Cu) (Cup ) ( ) . ( )
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6.4. (Cu) , (Cup) (Lim)
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10. :
:
: ,
: (. 6.1 6.4)
: 11. : ,
,
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(CUPRITE: Cup )
1. : Cu 2 O2. : .
(, ) (. 6.5).
(. 6.6) 3. :
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6.5. (Cup) (Mch) ( ) .
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6.6. ( ) ( ) ()
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4. :
(. 6.7 ) , 5. : (20-30%)6. :
7. :
(. 6.8 6.10)
8. : ( ) (. 6.11 6.13)
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6.7. ( Cu ) (Cup ) (Lim)
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6.8. Cup (Mch) ( ). ( )
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6.9. (Cup) (Mch) ( ). ( )
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6.10. (Cup) (Mch) ( ). ( )
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6.11. (Cup) (Mch) ( ) ( ). ( )
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6.12. (Cu ), (Cup) (Mch) ( ). ( )
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6.13. (Cup) (Mch) ( ) ( ),
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6.14. (Cup) (Mch) ( ) ( ),
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6.15. (Cup) ( Cu ),
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10. :
: , (.6.7 6.15)
: ,
:
11. :
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( MALACHITE: Mch and AZURITE: Azur )
1. : CuCO 3 .Cu(OH) 2 2CuCO 3 .Cu(OH) 2
2. : .
3. :
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4. :
5. :
6. : , (. 6.16 6.25)
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6. 16. (Mch) (Cup) ( ). ( )
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6. 17. (Mch) (Py) (Lim) ( ).
( )
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6.1 8 .
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6.1 9 . (Azur) (Cup) . ( ) ( )
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6. 20 . (Azur) (Cup) ( ) ( )
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5. :
) (. 6.21 6.22)
) (. 6.23 6.25 )
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6.21. (Cup) (Azur) ( ) ( ),
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6. 2 2. (Azur) (Cup) ( ) ( )
( )
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6.23. (Mch)
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6. 24. .
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6.25. ,
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(CHALCOCITE: Cc)
1. : Cu 2S. (Ag, Fe, Mn Se, Te) 2. :
) ( - Cu 2S):
103 oC , , (001)
(. 6.26),
) , >103 oC
) ( - Cu 2 S)
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6.2 6 . (Cc) (001) (Bor)
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6.2 7. (Neod) (Cov) ( ) ( ),
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)
. (. 6.28) ) ( )
3. :
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4. :
(. 6.29 6.30)
5. : (20-30%)
6. : 7. : ,
() , (. 6.31 6.32) .
8. :
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6.29. (Cc) , (Py) (Bor).
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6.30. (Cc) , (Py) (Bor)
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6. 32. , ( ). ( )
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9. :
.
(.6.33 6.46).
.. (. 6.40 6.41) ,
.
( , (. 6.46 )
.
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!!!
: - ( )
(. 6.41 6.42) -
(. 6.37 6.43)
- (. 6.44 6.45)
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6. 33. (Bor) (Cc)
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6.34. (Py) (Cpy) (Cc) (Gg)
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6. 35. (Cpy)
(Sph) (Gg) (Cc)
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6.36. : (Ga), (Cpy) (Sph) (Cc)
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6. 3 7. (Py) , (Cpy)
(Cc) , (Sph) (Gg)
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6. 3 9. (Py) , (Cpy)
(Cc) , (Sph)
(Cc)
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6.40. (Ga) (Cc) (Cc)
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6. 41. (Cpy) (Cc) , (Sph),
(Cc) ( ) (Gg)
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6.42. (Cpy)
(Cc)
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6.43. (Sph) (Cc)
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6. 44. (Ga) , (Sph) , (Cpy), (Py) (Gg) . .
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6. 45. (Cpy), (Sph), (Ga) , (Gg) . ( )
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6.46. .
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10. :
(. 6.35 6.36) :
:
,
: (. 6.33 6.46)
: 11. :
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(COVELLITE: Cov)
1. : CuS2. : .
(0001)
3. :
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4. : ( )
(. 6.47 6.48 ).
(. 6.49) 5. :
(10- 27%), (3 -
14%)
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6.47. (Cov) (Py), ( )
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6.48. ( ) ( )
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6.49. , (
) ( ). , ( )
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6. : ,
(. 6.47 6.50) .
: , : ( . 6.50)
: ,
: , (. 6.51)
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6.50. ( ) 0 0 90 0 . : , :
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6.5 1. ( ) 0 0 90 0 ( : ).
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7. : (. 6.52 6.55)
( ). 4
. (. 6.56)
8. :
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6.52. (Cov), (Luz) (Gg) ( )
( ),
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6.53. (Cov) (Py) ( ) ( ),
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6.5 4. (Cov) (Neod) ( ) ( ),
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6.55 (Py) (Cpy) (Cov)
( ). ( ) ( )
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6.55 (Py) (Cpy) (Cov)
( ). ( ) ( )
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6.56. ( ) ( ) ( ),
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9. :
. (. 6.47 6.48)
. (. 6.57 6.61)
.
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6.57. (Py) (Cpy) (Cov)
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6.58. (Cov)
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6.59. (Py) (Cpy) ( ) + ( ) (Gg)
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6.60.
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6.61.
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10. :
: , (. 6.60 6.61)
: ( )
11. :
.
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(BORNITE: Bor )
1. : Cu 5 FeS 4 Cu 3FeS 3 Cu 9 FeS 6
2. : >228 oC
3. :
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4. : .
(. 6.62 6.64).
. , , (. 6.65 6.66) 5. :
(18-28%)6. :
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6.63. (Bor) (Cpy) (Py)
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6.64. (Bor) (Py) (Cc)
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6.65. (Bor) ( ) ( ), (Cc)
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6.66. (Bor) ( ) ( ).
(Cc) (Py)
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7. : , . ,
8. :
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7. :
) (. 6.67 6.68) )
(111))
(100) , (. 6.69)
) +
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6.67. (Bor) (Cc)
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6.68. (Bor) (Cc)
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6.69. (Bor) (Cpy) .
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10. : : ,
, ()
: ,
:
( . 6.70)
11. :
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6.70 (Bor) (Cov) (Cc) ( ) ( ),