P3HT

P3HTP3HT() P3HT () P3HT() P3HT

Poly(3-hexylthiophene) P3HT

P3HT/toluene0.050.10.20.30.51.01.52.03.0 wt%P3HT/toluene80 OC

P3HT/toluene0.50.7wt%1.01.52.03.0wt%

61/minP3HT/toluene0.1wt%0.2wt%0.3wt%0.5wt%0.7wt%1.0wt%1.5wt%2.0wt%3.0wt%2426283032343638404244464850525456586062646668707274767880P3HT/toluene

,wt%

Higher emission energy (0-0 band) Single chain or intrachain emissionLower emission energy (0-1, 0-2 band) Aggregated state of polymer chainS0 (Ground state)S1 (Excited state)8 PL

PL0.2 wt%2.0 wt%P3HT/toluene5.0oCmin-1

UV-vis

UV-vis

P3HT/toluene0.3wt% 2.0wt%UV-vis1/minP3HT/toluene0.1wt%0.2wt%0.3wt%0.5wt%0.7wt%1.0wt%1.5wt%2.0wt%3.0wt%8078767472706866646260585654525048464442403836343230282624P3HT/toluene

PL

P3HT/toluene0.2 wt%2.0 wt%PL PL UV-vis

P3HT/toluene0.3wt%2.0wt%UV-vis

UV-vis

n=Avramin=22D n=11D Avrami equation P3HT/toluene UV-vis 610nm 0-2Avrami equation Avrami equation 1.392.03

AFM1.6 wt% P3HT

DLS80 O C25 O C80 O C5 POM

2.0 wt% P3HT/Toluene OMPOM0.3 wt% P3HT/Toluene OMPOM21

1.0 wt%P3HT/Toluene 400 POM POMPL0-10-2

UV-visP3HTP3HT

Avrami equationn2.03~1.392D1D2DPOMP3HT/tolueneP3HT/toluene -P3HT/toluene P3HT/toluene (1) Roncali, J. Chem. Rev. 1992, 92, 711.(2) McCullough, R. D.; Ewbank, P. C. In Handbook of Conducting Polymers, 2nd ed.; Skotheim, T. A., Elsenbaumer, R. L., Reynolds, J. R., Eds.; Marcel Dekker: New York, 1998; p 225.(3) McCullough, R. D.; Lowe, R. D.; Jayaraman, M.; Andersion, D. J. Org. Chem. 1993, 58, 904. (4 ) Li, Y. C.; Chen, K. B.; Chen, H. L.; Hsu, C. S.; Tsao, C. S.; Chen, J. H.; Chen, S. A. Langmui, 2006, 22, 11009.(5) Rahman, M. H,; Chen, C. Y.; Liao, S. C.; Chen, H. L.; Tsao, C. S.; Chen, J. H. Liao, J. L.; Ivanov, V. A.; Chen, S. A. Macromolecular 2007, 40, 6572.(6) Rahman, M. H.; Chen, C. Y.; Chen, H. L.; Chen, J. H.; Liao, S. C.; Liao, J. L.; Ivanov, V. A.; Chen, S. A. Langmuir 2009, 25, 1667.(7) Chen, J. H.; Chang, C. S.; Chang, Y. X.; Chen, C. Y.; Chen, H. L. Macromolecules 2009, 42, 1306.(8) Li, Y. C.; Chang, Y. X.; Chuang, P. Y.; Chen, H. L.; Chen, J. H.; Hsu, C. S.; Chen, K. B.; Tsao, C. S.; Chen, S. A. Langmuir 2009, 25, 4668.(9) Tracy, M. A.; Pecora, R. Annu. Rev. Phys. Chem. 1992, 43, 525. (10) Petekidis, G.; Fytas, G.; Witteler, H. Colloid Polym. Sci. 1994, 272, 1457.(11) Tiesler, U.; Rehahn, M.; Ballauff, M.; Petekidis, G.; Vlassopoulos, D.; Maret, G.; Kramer, H. Macromolecules 1996, 29, 6832. (12) Van der Schoot, P.; Odijk, T. J. J. Chem. Phys. 1992, 97, 515.(13) Wegner, G. Mol. Cryst. Liq. Cryst. 1993, 235, 1. (14) Jamieson, A. M.; Southwick, J. G.; Blackwell, J. Faraday Symp. Chem. Soc. 1983, 18, 131.(15) Ferrari, M. E.; Bloomfield, V. Macromolecules 1992, 25, 5266.(16) Weissenburg, P.; Odijk, T.; Cirkel, P.; Mandel, M. Macromolecules 1995, 28, 2315. (17) Richtering, W.; Gleim, W.; Burchard, W. Macromolecules 1992, 25, 3795.10. Meyer, E. L.; Fuller, G. G.; Clark, R. C.; Kulicke, W.-M. Macromolecules 1993, 26, 504.Burroughes, J. H.; Bradly, D. D. C.; Brown, A. R.; Marks, R. N.; Mackay, K. Friend, R. H.; Burns, P. L.; Holmes, A. B. Nature 1990, 347, 539. Friend, R. H.; Gymer, R. W.; Holmes, A. B.; Burroughes, J. H.; Marks, R. N.; Taliani, C.; Bradley, D. D. C.; dos Santos, D. A.; Brdas, J. L.; Lglund, M.; Salaneck, W. R. Nature 1999, 397, 121. Spreitzer, H.; Becker, H.; Kluge, E.; Kreuder, W.; Schenk, H.; Demandt, R. and Schoo, H. Adv. Mater. 1998, 10, 1340.Nguyen, T. Q.; Doan, V.; Schwartz, B. L. J. Chem. Phys. 1999, 110, 4068.(22) Niemi, V. M.; Knuuttila, P.; Osterholm, J. E.; Korvela, J. Polymer 1992, 33, 1559.(23) Chen, T.-A.; Wu, X.; Rieke, R. D. J. Am. Chem. Soc. 1995, 117, 233.(24) Chen, T.-A.; Rieke, R. D. Synth. Met. 1993, 60, 175.(25) Siroinghaus, H.; Brown, P. J.; Friend, R. H.; Nielson, M. M.; Beehguaard, K.; Langeveld-Voss, B. M. W.; Spierling, A. J. H.; Janssen, R. A. J.; Meiger, E. W.; Herwing, P.; de Leeuw, D. M. Nature 1999, 40, 685.(26) Rughoopath, S. D. D. V.; Hotta, S.; Heeger, A. J.; Wudl, F. J. Polym. Sci., Polym. Phys. Ed. 1987, 25, 1071.(27) Yue, S.; Berry, G. C.; McCoullough, R. D. Macromolecules 1996, 29, 933.(28) Kobashi, M.; Takeuchi, H. Macromolecules 1998, 31, 7273.(29) Malik, S.; Jana,T.; and Nandi, A. K. Macromolecules 2001, 34, 275.

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