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7/30/2019 05535493 http://slidepdf.com/reader/full/05535493 1/3 Shortcut Nitrifictaon Denitrification Proecss Treating Old Landfill Leachate Ammonia Nitrogen LV Bin School of Environment & Urban Construction Wuhan Institute of Science and Technology Wuhan, China Email: [email protected] WANG Hong-yu YANG Kai Department of Municipal Engineering Wuhan University Wuhan, China   Abstract  — The effects of dissolved oxygen concentration, temperature and other operation facters on shortcut nitrification and denitrification process for the treatment of landfill leachate was studied in a sequencing batch reactor. The results showed that the termination of aeration could effectively control the reaction at the phase of nitrite and could get stable removal rate of ammonia nitrogen and relatively high accumulation rate of nitrite when dissolved oxygen concentration rapidly increased. The increase of dissolved oxygen concentration and temperature were propitious to the rise of volume loading in the process of shortcut nitrification and denitrification. It is relatively appropriate that the dissolved oxygen concentration and temperature was respectively about 1.0mg/L and more than 25 in the process of shortcut nitrification and denitrification process treating landfill leachate. When pH value was not controlled in the reaction process and temperature ranged from 25 to 28 and the dissolved oxygen concentration of nitrification was about 1.0mg/L and the ammonia nitrogen loading was less than 0.25gNH 4 + -N/(L.d), the effluent concentration of ammonia nitrogen and nitrite was respectively less than 15mg/L and 1mg/L and the removal rate of total nitrogen more than 98 .  Keywords  —  Landfill Leachate; Shortcut Nitrifictaon Denitrification; accumulation rate of nitrite I. ᓩ㿔 ⷁ⸱ ড⸱ ⫳⠽㜅∂Ꮉ㡎ᰃ䖥ᑈথሩ䍋ᴹⱘᮄ ൟ⫳⠽㜅∂ᡔᴃDŽ䆹ᡔᴃ 㡖㑺㛑⑤ǃޣᇥ∵⊹ѻ䞣 㡖ⳕऴ䴶⿃ㄝӬ⚍ˈফ 䍞ᴹ䍞ⱘ ⊼ˈ៤Ў∵∈⫳ ⠽㜅∂ お乚ඳⱘ⛁⚍ [1-3] DŽおⷁ⸱ ড⸱ ⫳⠽ 㜅∂Ꮉ㡎ᯊˈ䰤Ѣ䞛⫼ҎᎹ䜡 ⱘ∈ḋˈ㗠ᴀ䆩偠ҹൗ ഒ⏫Ⓒ⎆Ў おᇍ䈵ˈⳌ↨㗠㿔ˈЎᅲ䰙ⱘখ㗗ᑨ ⫼Ӌ DŽ ⱘⷁ⸱ ড⸱ Ꮉ㡎⬅Ѣᕜ䲒 ᣕ〇ᅮǃ䕗催 ⱘѮ⸱䝌Ⲥ∂⿃㌃⥛˄Ѯ⸱䝌Ⲥ∂⌧ᑺ/ ˄Ѯ⸱䝌Ⲥ∂⌧ +⸱䝌Ⲥ∂⌧ᑺ˅˅ˈϨⷁ⸱ ѻ⫳ⱘѮ⸱䝌Ⲥ∂໘ ⧚ ϡᅠ Ӯ ᇍ⦃ ๗䗴 ៤Ѡ ∵ ᶧㄝ ॳ ˈ㗠 䰤 њ ⱘᑨ ⫼DŽᴀ䆩偠Ў㦋ᕫൗഒ⏫Ⓒ⎆ⷁ⸱ ড⸱ Ꮉ㡎〇ᅮⱘ Ѯ⸱䝌Ⲥ⿃㌃ঞ䕗Ԣⱘ ∈Ѯ⸱䝌Ⲥ∂⌧ᑺ˄1mg/L ҹ ϟ˅ˈ おњ⒊㾷⇻˄ DO˅ⱘ ᮍᓣǃDO ⌧ᑺ⏽ᑺ ᴵӊᇍⷁ⸱ ড⸱ Ꮉ 㡎ⱘ ᕅડᚙމDŽ II. 䆩偠ᴤ ᮍ⊩   A. 䆩偠㺙㕂  ᴀお䞛⫼ⱘ䆩偠㺙㕂Ў SBR ডᑨˈডᑨⳈᕘ 30 cmˈ催 38 cmˈᬜᆍ⿃ 21 L˗ⶀᯊ䖯∈ˈᲱ⇨ˉ≝ ⎔ˉᥦ∈ㄝ᪡䖛䞛⫼㞾 ᮍᓣˈ䆩偠㺙㕂བ 1 ᠔⼎DŽ  B. 䆩偠ᴤ   䆩偠⫼∈প㞾℺∝ᶤൗഒ฿ඟᳳ⏫Ⓒ⎆ˈ Ё⇼ ∂Ў 750~1450 mg/LˈCOD Ў 780~1420 mg/LˈBOD Ў 65~120 mg/Lˈ  pH Ў 8.2 8.7DŽ⾡∵⊹Ў ៤❳ⱘ ∵⊹ড⸱ ∵⊹DŽ  C. ᵤᮍ⊩  ⇼∂˖䩴⇣䆩 ᑺ⊩˗Ѯ⸱䝌Ⲥ∂˖  N-˄1-˅ЭѠ㛎 ᑺ⊩˗⸱䝌Ⲥ∂˖呱佭㤝䜮 ⊩˗COD˖䞡䫀䝌䪒⊩˗ ԭഛᣝ ޚᮍ⊩⌟ᅮDŽ   D. ∵⊹  ∵⊹ 䖛Ёˈডᑨ⏽ᑺ  pH 27ćǃ7.5 Ꮊে˗䖤㸠ᳳ 24hˈ᪡ᎹᑣЎᲱ⇨ˉ᧙ᢠ Project supported by Hubei Provincial Department of Education (No.Q20091710) 1 2 3 4 5 6 7 1ˊᥦ∈ㅵ 2ˊᥦ⊹ㅵ 3ˊᲱ⇨ⷖ༈ 4ˊ᧙ᢠ 5ˊ⏽Ҿ༈ 6ˊ⒊㾷⇻Ҿ༈ 7ˊ  pH   1 䆩偠㺙㕂 978-1-4244-7739-5/10/$26.00 ©2010 IEEE

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  • 7/30/2019 05535493

    1/3

    Shortcut Nitrifictaon Denitrification Proecss Treating

    Old Landfill Leachate Ammonia Nitrogen

    LV Bin

    School of Environment & Urban Construction

    Wuhan Institute of Science and Technology

    Wuhan, China

    Email:[email protected]

    WANG Hong-yu YANG Kai

    Department of Municipal Engineering

    Wuhan University

    Wuhan, China

    AbstractThe effects of dissolved oxygen concentration,temperature and other operation facters on shortcut nitrification

    and denitrification process for the treatment of landfill leachate

    was studied in a sequencing batch reactor. The results showed

    that the termination of aeration could effectively control the

    reaction at the phase of nitrite and could get stable removal rateof ammonia nitrogen and relatively high accumulation rate of

    nitrite when dissolved oxygen concentration rapidly increased.

    The increase of dissolved oxygen concentration and temperature

    were propitious to the rise of volume loading in the process of

    shortcut nitrification and denitrification. It is relatively

    appropriate that the dissolved oxygen concentration and

    temperature was respectively about 1.0mg/L and more than 25

    in the process of shortcut nitrification and denitrification

    process treating landfill leachate. When pH value was not

    controlled in the reaction process and temperature ranged from

    25 to 28 and the dissolved oxygen concentration of

    nitrification was about 1.0mg/L and the ammonia nitrogen

    loading was less than 0.25gNH4+-N/(L.d), the effluent

    concentration of ammonia nitrogen and nitrite was respectivelyless than 15mg/L and 1mg/L and the removal rate of total

    nitrogen more than 98 .

    KeywordsLandfill Leachate; Shortcut Nitrifictaon Denitrification;accumulation rate of nitrite

    I.

    [1-3]

    /

    +

    1mg/L

    DO DO

    II.

    A. SBR

    30 cm 38 cm 21 L

    1

    B.

    750~1450 mg/LCOD 780~1420 mg/LBOD

    65~120 mg/L pH 8.2 8.7

    C. N-1-

    COD

    D. pH

    277.5 24h

    Project supported by Hubei Provincial Department of Education (No.Q20091710)

    1

    23

    4

    5 6 7

    1

    2

    3

    4

    5

    6

    7 pH

    1

    978-1-4244-7739-5/10/$26.00 2010 IEEE

  • 7/30/2019 05535493

    2/3

    + 23h+ 1h

    NaHC03

    pH DO 2

    DO 0.75mgL

    2.4

    pH 25d

    10mg/L

    98 7900 8100mg/L MLVSS/MLSS 0.78

    III.

    A. DO

    DO

    DO

    DO

    2

    0

    15

    30

    45

    60

    75

    90

    105

    120

    135

    360

    380

    400

    420

    440

    460

    480

    500

    0 100 200 300 400 500 600 700 800 900

    0

    2

    4

    6

    8

    10

    DO

    mg/L

    mg/L

    mg/L

    (mi n)

    2

    2 15mg/L

    15mg/L

    DO

    DO

    DO

    DO

    15mg/L

    DO

    DO

    15mg/L

    B. DO DO 0.75mg/L1.0mg/L

    1.5mg/L

    8000mg/L DO

    15mg/L

    1

    1 DO

    gNH4+ N/L.d

    DO0.75mg/L

    DO1.0mg/L

    DO1.5mg/L

    0.21 0.35 0.48 0.26

    0.23 0.37 0.57 0.47

    0.25 6.29 0.47 0.31

    0.27 18.14 0.94 0.620.29 42.97 9.48 12.46

    0.31 57.94 24.87 20.73 mg/L

    1 DO

    1.0mg/L 1.5mg/L

    1mg/L DO

    0.75mg/L 1.0mg/L 17

    DO 1.5mg/L

    DO 0.75mg/L 1.0mg/L

    DO

    DO 1.0mg/L

    C. 272522 15

    DO 1.0mg/L DO

    DO

    2

    2

    gNH4+ N/L.d

    (mg/L)

    27 25 22 15

    0.21 0.48 0.36 9.64 57.49

    0.23 0.57 0.84 29.50 97.02

    0.25 0.47 0.59 71.83 177.59

    0.27 0.94 10.45 96.40 216.2

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    2 25

    27

    1mg/L 15 25

    20

    25

    D. pH pH

    pH

    pH

    pH

    DO

    12h DO

    + 11h 1h 25

    28 DO 1.0 mg/L

    7900 8200mg/L 3

    800

    900

    1000

    1100

    1200

    1300

    1400

    1500

    82

    84

    86

    88

    90

    92

    94

    96

    98

    100

    0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38

    0.15

    0.20

    0.25

    0.30

    0.35

    gNH4+N/L.

    d

    d

    0

    20

    40

    60

    80

    100

    120

    140

    160

    180

    mg/L

    mg/L

    3 pH

    3 pH

    pH 6.9~8.437d

    15mg/L

    96

    0.25gNH4+

    N/ L.d

    1mg/L 98

    0.27gNH4

    +N/L.d 0.30gNH4

    +

    N/L.d 70mg/L

    160mg/L 94

    88 0.25gNH4+

    N/L.d

    25 28 DO

    1.0mg/LpH

    15mg/L 1mg/L 98

    IV.

    1 DO 15mg/L

    DO DO

    2DO

    DO 0.75mg/L 1.0mg/L

    DO

    25

    25

    3 pH 25

    28 DO 1.0mg/L DO

    0.25gNH4+

    N/L.d

    15mg/L 1mg/L

    98

    REFERENCES

    [1] G. Lu P. Zheng F. Y. Xia, Partial nitrification of ammonia-containing wastewater, Journal of Zhejiang University(Agric. &LifeSci.), vol.30, pp, 241-246, March 2004.

    [2] X. L. Zhang, D. Ch. Peng, Zh. Y. Wang, Influence of Organic Matterson Nitrification at Low DO in Biological Turbulent Bed Reactor. ChinaWater & Wastwater, vol. 18, pp. 10-13, May 2002.

    [3] R. V. KempenJ. W. Mulder C. A. UijterlindeOverviewa fullscale experience of the SHARON process for treatment of rejectionwater of digeste sludge dewatering. Water Science and Technology, vol.44, pp. 145-152, January 2001.

    [4] A. Uygur, F. Karg, Biological nutrient removal from pre-treated landfillleachate in a sequencing batch reactor. Journal of EnvironmentalManagement vol 74, pp. 9-14, January 2004.

    [5] F. KargiM. Y. Pamukoglu, Repeated fed-batch biological treatment ofpre-treated landfill leachate by powdered activated carbon addition.Enzyme and Microbial Technology, vol. 34, pp.422-428, May 2004.

    [6] S. Aslan, L. Miller, M. Dahab, Ammonium oxidation via nitriteaccumulation under limited oxygen concentration in sequencing batchreactors. Bioresource Technology, vol 100, pp.659-664, June 2009.

    [7] J. H. Guo, Y. Z. Peng, S. Y. Wang, Y. N. Zheng, Long-term effect ofdissolved oxygen on partial nitrification performance and microbialcommunity structure. Bioresource Technology, vol. 100, pp. 623-626,June 2009.