(2013-II) 2da Practica - Cu(OH)2 (Funda II)

7/24/2019 (2013-II) 2da Practica - Cu(OH)2 (Funda II)

1/84

Cu(+2a) + 2H2O = Cu(OH)2 + 2H(+a)

T K Log(K)

C kJ J/K kJ

0 69.491 114.366 38.252 4.834E-008 -7.316

5 57.369 69.991 37.901 7.617E-008 -7.118

10 57.187 69.342 37.553 1.180E-007 -6.928

15 56.948 68.506 37.208 1.797E-007 -6.746

20 56.669 67.544 36.868 2.692E-007 -6.570

25 56.360 66.500 36.533 3.972E-007 -6.401

30 56.033 65.412 36.203 5.773E-007 -6.239

35 55.695 64.307 35.879 8.273E-007 -6.082

40 55.352 63.204 35.560 1.169E-006 -5.932

45 55.009 62.116 35.247 1.632E-006 -5.787

50 54.667 61.051 34.939 2.249E-006 -5.648

55 54.328 60.008 34.636 3.063E-006 -5.514

60 53.990 58.986 34.339 4.126E-006 -5.384

65 53.657 57.993 34.046 5.500E-006 -5.260

70 53.332 57.040 33.759 7.257E-006 -5.139

75 53.017 56.127 33.476 9.485E-006 -5.023

80 52.711 55.256 33.197 1.228E-005 -4.911

85 52.417 54.429 32.923 1.577E-005 -4.802

90 52.135 53.648 32.653 2.008E-005 -4.697

95 51.867 52.914 32.387 2.538E-005 -4.596

100 51.614 52.230 32.124 3.183E-005 -4.497

CuOH(+a) + H2O = Cu(OH)2 + H(+a)

T K Log(K)

C kJ J/K kJ

0 17.596 91.874 -7.500 2.718E+001 1.434

5 11.241 68.620 -7.846 2.975E+001 1.474

10 10.897 67.396 -8.186 3.238E+001 1.510

15 10.559 66.213 -8.520 3.504E+001 1.545

20 10.228 65.071 -8.848 3.773E+001 1.577

25 9.903 63.972 -9.171 4.044E+001 1.607

30 9.585 62.916 -9.488 4.315E+001 1.635

35 9.275 61.902 -9.800 4.585E+001 1.661

40 8.973 60.930 -10.107 4.853E+001 1.686

45 8.680 60.000 -10.409 5.119E+001 1.709

50 8.394 59.108 -10.707 5.381E+001 1.731

55 8.116 58.256 -11.000 5.639E+001 1.751

60 7.847 57.440 -11.290 5.892E+001 1.770

65 7.584 56.659 -11.575 6.139E+001 1.788

70 7.331 55.914 -11.856 6.381E+001 1.805

75 7.085 55.203 -12.134 6.617E+001 1.821

80 6.848 54.527 -12.408 6.847E+001 1.835

H S G

H

S

G


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85 6.619 53.884 -12.679 7.069E+001 1.849

90 6.399 53.274 -12.947 7.285E+001 1.862

95 6.189 52.698 -13.212 7.495E+001 1.875

100 5.987 52.155 -13.474 7.697E+001 1.886

Cu(OH)3(-a) + H(+a) = Cu(OH)2 + H2O

T K Log(K)

C kJ J/K kJ

0 -90.758 55.871 -106.020 1.888E+020 20.276

5 -83.126 83.761 -106.424 9.712E+019 19.987

10 -81.479 89.630 -106.857 5.180E+019 19.714

15 -79.811 95.469 -107.320 2.859E+019 19.456

20 -78.122 101.279 -107.812 1.629E+019 19.212

25 -76.413 107.059 -108.333 9.573E+018 18.981

30 -74.684 112.810 -108.882 5.790E+018 18.763

35 -72.935 118.531 -109.461 3.600E+018 18.556

40 -71.167 124.225 -110.068 2.298E+018 18.361

45 -69.379 129.889 -110.703 1.503E+018 18.177

50 -67.571 135.526 -111.367 1.007E+018 18.003

55 -65.745 141.135 -112.058 6.900E+017 17.839

60 -63.899 146.717 -112.778 4.830E+017 17.684

65 -62.034 152.273 -113.525 3.451E+017 17.538

70 -60.151 157.803 -114.301 2.514E+017 17.400

75 -58.248 163.307 -115.103 1.866E+017 17.271

80 -56.327 168.786 -115.934 1.410E+017 17.149

85 -54.387 174.240 -116.791 1.084E+017 17.035

90 -52.428 179.671 -117.676 8.465E+016 16.928

95 -50.451 185.079 -118.588 6.716E+016 16.827

100 -48.455 190.463 -119.527 5.409E+016 16.733

Cu(OH)4(-2a) + 2H(+a) = Cu(OH)2 + 2H2O

T K Log(K)

C kJ J/K kJ

0 -146.819 140.046 -185.072 2.480E+035 35.394

5 -132.336 192.986 -186.015 8.614E+034 34.935

10 -129.837 201.891 -187.002 3.165E+034 34.500

15 -127.307 210.745 -188.034 1.227E+034 34.089

20 -124.749 219.548 -189.109 5.001E+033 33.699

25 -122.161 228.300 -190.229 2.138E+033 33.330

30 -119.545 237.004 -191.392 9.568E+032 32.981

35 -116.899 245.658 -192.599 4.469E+032 32.650

40 -114.226 254.265 -193.849 2.175E+032 32.337

45 -111.524 262.824 -195.141 1.100E+032 32.041

H

S

G

H

S

G


3/84

50 -108.794 271.337 -196.477 5.775E+031 31.762

55 -106.037 279.806 -197.855 3.140E+031 31.497

60 -103.251 288.230 -199.275 1.766E+031 31.247

65 -100.438 296.611 -200.737 1.025E+031 31.011

70 -97.597 304.950 -202.241 6.136E+030 30.788

75 -94.729 313.249 -203.786 3.781E+030 30.57880 -91.833 321.507 -205.373 2.396E+030 30.379

85 -88.910 329.727 -207.001 1.559E+030 30.193

90 -85.959 337.909 -208.671 1.040E+030 30.017

95 -82.980 346.054 -210.380 7.114E+029 29.852

100 -79.975 354.164 -212.131 4.980E+029 29.697


4/84


5/84

[H(+a)] pH [Cu(+2a)] [CuOH(+a)] [Cu(OH)3(-a)]

1.00E+00 0.0 2.517E+006 2.473E-002 1.045E-019

3.16E-01 0.5 2.517E+005 7.820E-003 3.303E-019

1.00E-01 1.0 2.517E+004 2.473E-003 1.045E-018

3.16E-02 1.5 2.517E+003 7.820E-004 3.303E-018

1.00E-02 2.0 2.517E+002 2.473E-004 1.045E-017

3.16E-03 2.5 2.517E+001 7.820E-005 3.303E-017

1.00E-03 3.0 2.517E+000 2.473E-005 1.045E-016

3.16E-04 3.5 2.517E-001 7.820E-006 3.303E-016

1.00E-04 4.0 2.517E-002 2.473E-006 1.045E-015

3.16E-05 4.5 2.517E-003 7.820E-007 3.303E-015

1.00E-05 5.0 2.517E-004 2.473E-007 1.045E-014

3.16E-06 5.5 2.517E-005 7.820E-008 3.303E-014

1.00E-06 6.0 2.517E-006 2.473E-008 1.045E-013

3.16E-07 6.5 2.517E-007 7.820E-009 3.303E-013

1.00E-07 7.0 2.517E-008 2.473E-009 1.045E-012

3.16E-08 7.5 2.517E-009 7.820E-010 3.303E-012

1.00E-08 8.0 2.517E-010 2.473E-010 1.045E-011

3.16E-09 8.5 2.517E-011 7.820E-011 3.303E-011

1.00E-09 9.0 2.517E-012 2.473E-011 1.045E-010

3.16E-10 9.5 2.517E-013 7.820E-012 3.303E-010

1.00E-10 10.0 2.517E-014 2.473E-012 1.045E-009

3.16E-11 10.5 2.517E-015 7.820E-013 3.303E-009

1.00E-11 11.0 2.517E-016 2.473E-013 1.045E-008

3.16E-12 11.5 2.517E-017 7.820E-014 3.303E-008

1.00E-12 12.0 2.517E-018 2.473E-014 1.045E-007

3.16E-13 12.5 2.517E-019 7.820E-015 3.303E-007

1.00E-13 13.0 2.517E-020 2.473E-015 1.045E-006

3.16E-14 13.5 2.517E-021 7.820E-016 3.303E-006

1.00E-14 14.0 2.517E-022 2.473E-016 1.045E-005

3.16E-15 14.5 2.517E-023 7.820E-017 3.303E-005

1.00E-15 15.0 2.517E-024 2.473E-017 1.045E-004

3.16E-16 15.5 2.517E-025 7.820E-018 3.303E-004

1.00E-16 16.0 2.517E-026 2.473E-018 1.045E-003

3.16E-17 16.5 2.517E-027 7.820E-019 3.303E-003

1.00E-17 17.0 2.517E-028 2.473E-019 1.045E-002

3.16E-18 17.5 2.517E-029 7.820E-020 3.303E-002

1.00E-18 18.0 2.517E-030 2.473E-020 1.045E-001

3.16E-19 18.5 2.517E-031 7.820E-021 3.303E-001

1.00E-19 19.0 2.517E-032 2.473E-021 1.045E+000

3.16E-20 19.5 2.517E-033 7.820E-022 3.303E+000

1.00E-20 20.0 2.517E-034 2.473E-022 1.045E+001


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0 1 2 3 4 5 6 7 8 9

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25%

30%

35%

40%45%

50%

55%

60%

65%

70%

75%

80%

85%

90%

95%

100%

Diagrama de P

"

# Co!e$ra!i%

0 1 2 3 4 5 6 7 8 9 10

-15

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5

Diagrama


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-45

-40

-35

-30

-25

-20

"H

ogCuT*

0 1 2 3 4 5 6 7 8 9

1.000E-043

1.000E-039

1.000E-035

1.000E-031

1.000E-027

1.000E-023

1.000E-019

1.000E-015

1.000E-011

1.000E-007

1.000E-003

1.000E+001

Diagrama

ogCuT*


8/84

"H


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[Cu(OH)4(-2a)] [CuT] [Cu(+2a)]/[CuT] [CuOH(+a)]/[CuT]

4.67636871E-034 2.517E+006 1.000E+000 9.823E-009

4.67636871E-033 2.517E+005 1.000E+000 3.106E-008

4.67636871E-032 2.517E+004 1.000E+000 9.823E-008

4.67636871E-031 2.517E+003 1.000E+000 3.106E-007

4.67636871E-030 2.517E+002 1.000E+000 9.823E-007

4.67636871E-029 2.517E+001 1.000E+000 3.106E-006

4.67636871E-028 2.518E+000 1.000E+000 9.823E-006

4.67636871E-027 2.518E-001 1.000E+000 3.106E-005

4.67636871E-026 2.518E-002 9.999E-001 9.822E-005

4.67636871E-025 2.518E-003 9.997E-001 3.105E-004

4.67636871E-024 2.520E-004 9.990E-001 9.814E-004

4.67636871E-023 2.525E-005 9.969E-001 3.097E-003

4.67636871E-022 2.542E-006 9.903E-001 9.728E-003

4.67636871E-021 2.596E-007 9.699E-001 3.013E-002

4.67636871E-020 2.765E-008 9.105E-001 8.944E-002

4.67636871E-019 3.303E-009 7.622E-001 2.368E-001

4.67636871E-018 5.095E-010 4.941E-001 4.854E-001

4.67636871E-017 1.364E-010 1.846E-001 5.733E-001

4.67636871E-016 1.317E-010 1.911E-002 1.878E-001

4.67636871E-015 3.384E-010 7.439E-004 2.311E-002

4.67636871E-014 1.047E-009 2.404E-005 2.362E-003

4.67636871E-013 3.305E-009 7.618E-007 2.366E-004

4.67636871E-012 1.045E-008 2.409E-008 2.366E-005

4.67636871E-011 3.308E-008 7.610E-010 2.364E-006

4.67636871E-010 1.049E-007 2.399E-011 2.357E-007

4.67636871E-009 3.350E-007 7.514E-013 2.334E-008

4.67636871E-008 1.091E-006 2.307E-014 2.266E-009

4.67636871E-007 3.771E-006 6.676E-016 2.074E-010

4.67636871E-006 1.512E-005 1.665E-017 1.635E-011

4.67636871E-005 7.980E-005 3.155E-019 9.800E-013

0.0004676369 5.721E-004 4.400E-021 4.323E-014

0.0046763687 5.007E-003 5.028E-023 1.562E-015

0.0467636871 4.781E-002 5.266E-025 5.173E-017

0.4676368714 4.709E-001 5.346E-027 1.661E-018

4.6763687136 4.687E+000 5.371E-029 5.276E-020

46.7636871361 4.680E+001 5.380E-031 1.671E-021

467.6368713609 4.677E+002 5.382E-033 5.287E-023

4676.368713609 4.677E+003 5.383E-035 1.672E-024

46763.68713609 4.676E+004 5.383E-037 5.288E-026

467636.8713609 4.676E+005 5.383E-039 1.672E-027

4676368.713609 4.676E+006 5.383E-041 5.288E-029


10/84

10 11 12 13 14 15 16 17 18 19 20

edomia!ia

[Cu(+2a)]/[CuT]

[CuOH(+a)]/[CuT]

[Cu(OH)3(-a)]/[CuT]

[Cu(OH)4(-2a)]/[CuT]

11 12 13 14 15 16 17 18 19 20

e &'errum

log[Cu(+2a)]


11/84

log[CuOH(+a)]

log[Cu(OH)3(-a)]

log[Cu(OH)4(-2a)]

10 11 12 13 14 15 16 17 18 19 20

e &'errum

[Cu(+2a)]

[CuOH(+a)]

[Cu(OH)3(-a)]

[Cu(OH)4(-2a)]


12/84


13/84

[Cu(OH)3(-a)]/[CuT] [Cu(OH)4(-2a)]/[CuT] log[CuT] log[Cu(+2a)]

4.150E-026 1.858E-040 6.4009655703 6.400965566

1.312E-024 1.858E-038 5.4009655795 5.400965566

4.149E-023 1.858E-036 4.4009656087 4.400965566

1.312E-021 1.858E-034 3.4009657009 3.400965566

4.149E-020 1.858E-032 2.4009659926 2.400965566

1.312E-018 1.858E-030 1.4009669151 1.400965566

4.149E-017 1.858E-028 0.4009698322 0.400965566

1.312E-015 1.858E-026 -0.5990209434 -0.599034434

4.149E-014 1.857E-024 -1.5989917744 -1.599034434

1.312E-012 1.857E-022 -2.5988995468 -2.599034434

4.145E-011 1.856E-020 -3.5986080263 -3.599034434

1.308E-009 1.852E-018 -4.597687443 -4.599034434

4.109E-008 1.839E-016 -5.5947890635 -5.599034434

1.273E-006 1.802E-014 -6.5857483637 -6.599034434

3.778E-005 1.691E-012 -7.5583238531 -7.599034434

1.000E-003 1.416E-010 -8.481117259 -8.599034434

2.050E-002 9.179E-009 -9.2928631952 -9.599034434

2.422E-001 3.428E-007 -9.865150235 -10.599034434

7.931E-001 3.550E-006 -9.8803799111 -11.599034434

9.761E-001 1.382E-005 -9.47054808 -12.599034434

9.976E-001 4.466E-005 -8.9799818981 -13.599034434

9.996E-001 1.415E-004 -8.4808740446 -14.599034434

9.995E-001 4.474E-004 -7.9808339765 -15.599034434

9.986E-001 1.414E-003 -7.4804232466 -16.599034434

9.955E-001 4.457E-003 -6.9790987134 -17.599034434

9.860E-001 1.396E-002 -6.4749337659 -18.599034434

9.572E-001 4.285E-002 -5.9620196429 -19.599034434

8.760E-001 1.240E-001 -5.4235390461 -20.599034434

6.908E-001 3.092E-001 -4.820372342 -21.599034434

4.140E-001 5.860E-001 -4.0980096134 -22.599034434

1.826E-001 8.174E-001 -3.2425283562 -23.599034434

6.598E-002 9.340E-001 -2.3004476616 -24.599034434

2.185E-002 9.781E-001 -1.320496568 -25.599034434

7.014E-003 9.930E-001 -0.3270341689 -26.599034434

2.229E-003 9.978E-001 0.6708778099 -27.599034434

7.059E-004 9.993E-001 1.670215425 -28.599034434

2.233E-004 9.998E-001 2.67000575 -29.599034434

7.064E-005 9.999E-001 3.6699394239 -30.599034434

2.234E-005 1.000E+000 4.6699184476 -31.599034434

7.064E-006 1.000E+000 5.6699118141 -32.599034434

2.234E-006 1.000E+000 6.6699097164 -33.599034434


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Diagrama de

"H

ogCuT*

0 1 2 3 4 5 6 7 8 9 10 1

0

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10

Diagrama de


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-15

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ogCuT*

5 6 7 8 9 10

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-4

Diagrama de

ogCuT*


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"H


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solu!l!"a"

log[CuOH(+a)] log[Cu(OH)3(-a)] log[Cu(OH)4(-2a)] log([Cu(+2a)]/[CuT])

-1.6067805747 -18.9810386358 -33.3300912537 -4.266170123424E-009

-2.1067805747 -18.4810386358 -32.3300912537 -1.349081427183E-008

-2.6067805747 -17.9810386358 -31.3300912537 -4.266169916634E-008

-3.1067805747 -17.4810386358 -30.3300912537 -1.349081240161E-007

-3.6067805747 -16.9810386358 -29.3300912537 -4.266168034843E-007

-4.1067805747 -16.4810386358 -28.3300912537 -1.349079354265E-006

-4.6067805747 -15.9810386358 -27.3300912537 -4.266149176278E-006

-5.1067805747 -15.4810386358 -26.3300912537 -1.349060496353E-005

-5.6067805747 -14.9810386358 -25.3300912537 -4.265960607798E-005

-6.1067805747 -14.4810386358 -24.3300912537 -0.0001348872

-6.6067805747 -13.9810386358 -23.3300912537 -0.0004264076

-7.1067805747 -13.4810386358 -22.3300912537 -0.001346991

-7.6067805747 -12.9810386358 -21.3300912537 -0.0042453704

-8.1067805747 -12.4810386358 -20.3300912537 -0.0132860703

-8.6067805747 -11.9810386358 -19.3300912537 -0.0407105808

-9.1067805747 -11.4810386358 -18.3300912537 -0.1179171749

-9.6067805747 -10.9810386358 -17.3300912537 -0.3061712388

-10.1067805747 -10.4810386358 -16.3300912537 -0.733884199

-10.6067805747 -9.9810386358 -15.3300912537 -1.7186545228

-11.1067805747 -9.4810386358 -14.3300912537 -3.128486354

-11.6067805747 -8.9810386358 -13.3300912537 -4.6190525359

-12.1067805747 -8.4810386358 -12.3300912537 -6.1181603893

-12.6067805747 -7.9810386358 -11.3300912537 -7.6182004575

-13.1067805747 -7.4810386358 -10.3300912537 -9.1186111874

-13.6067805747 -6.9810386358 -9.3300912537 -10.6199357205

-14.1067805747 -6.4810386358 -8.3300912537 -12.1241006681

-14.6067805747 -5.9810386358 -7.3300912537 -13.6370147911

-15.1067805747 -5.4810386358 -6.3300912537 -15.1754953878

-15.6067805747 -4.9810386358 -5.3300912537 -16.778662092

-16.1067805747 -4.4810386358 -4.3300912537 -18.5010248206

-16.6067805747 -3.9810386358 -3.3300912537 -20.3565060778

-17.1067805747 -3.4810386358 -2.3300912537 -22.2985867724

-17.6067805747 -2.9810386358 -1.3300912537 -24.278537866

-18.1067805747 -2.4810386358 -0.3300912537 -26.2720002651

-18.6067805747 -1.9810386358 0.6699087463 -28.2699122439

-19.1067805747 -1.4810386358 1.6699087463 -30.2692498589

-19.6067805747 -0.9810386358 2.6699087463 -32.269040184

-20.1067805747 -0.4810386358 3.6699087463 -34.2689738579

-20.6067805747 0.0189613642 4.6699087463 -36.2689528816

-21.1067805747 0.5189613642 5.6699087463 -38.2689462481

-21.6067805747 1.0189613642 6.6699087463 -40.2689441504


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12 13 14 15 16 17 18 19 20

Souiidad

log[CuT]

log[Cu(+2a)]

log[CuOH(+a)]

log[Cu(OH)3(-a)]

log[Cu(OH)4(-2a)]

EC# #1 #2 & #3

12 13 14 15 16 17 18 19 20

Souiidad


19/84

log[CuT]

EC# #1 #2 & #3

11 12 13 14 15

Souiidad

log[CuT]

EC# #1 #2 & #3


20/84


21/84

log([CuOH(+a)]/[CuT]) log([Cu(OH)3(-a)]/[CuT]) log([Cu(OH)4(-2a)]/[CuT])

-8.0077461449 -25.3820042061 -39.731056824

-7.5077461542 -23.8820042153 -37.7310568332

-7.0077461833 -22.3820042444 -35.7310568624

-6.5077462756 -20.8820043367 -33.7310569547

-6.0077465673 -19.3820046284 -31.7310572464-5.5077474898 -17.8820055509 -29.7310581688

-5.0077504068 -16.3820084679 -27.7310610859

-4.5077596313 -14.8820176924 -25.7310703104

-4.0077888003 -13.3820468614 -23.7310994794

-3.5078810279 -11.882139089 -21.7311917069

-3.0081725483 -10.3824306094 -19.7314832274

-2.5090931317 -8.8833511928 -17.7324038107

-2.0119915111 -7.3862495722 -15.7353021902

-1.521032211 -5.8952902721 -13.74434289

-1.0484567215 -4.4227147826 -11.7717674006-0.6256633156 -2.9999213767 -9.8489739947

-0.3139173795 -1.6881754406 -8.0372280585

-0.2416303397 -0.6158884008 -6.4649410187

-0.7264006635 -0.1006587246 -5.4497113426

-1.6362324947 -0.0104905558 -4.8595431737

-2.6267986766 -0.0010567377 -4.3501093557

-3.62590653 -0.0001645911 -3.8492172091

-4.6259465982 -0.0002046593 -3.3492572772

-5.6263573281 -0.0006153892 -2.8496680071

-6.6276818612 -0.0019399223 -2.3509925403

-7.6318468087 -0.0061048698 -1.8551574878

-8.6447609318 -0.0190189929 -1.3680716109

-9.6832415285 -0.0574995896 -0.9065522076

-10.7864082327 -0.1606662938 -0.5097189117

-12.0087709613 -0.3830290224 -0.2320816403

-13.3642522185 -0.7385102796 -0.0875628976

-14.8063329131 -1.1805909742 -0.0296435921

-16.2862840067 -1.6605420678 -0.0095946857

-17.7797464058 -2.1540044669 -0.0030570848

-19.2776583846 -2.6519164457 -0.0009690637

-20.7769959996 -3.1512540607 -0.0003066787

-22.2767863247 -3.6510443858 -9.700372829371E-005

-23.7767199985 -4.1509780597 -3.06776148275104E-005

-25.2766990223 -4.6509570834 -9.70134788841223E-006

-26.7766923888 -5.1509504499 -3.06785899957048E-006

-28.2766902911 -5.6509483522 -9.70144540900842E-007

EC# Cu #1 2


22/84

'g/ #2 2

'g/ #3 2

EC# * #1 3.15E-05

'ol/ #2 3.15E-05

'ol/ #3 3.15E-05

EC# * #1 -4,.2.

log['ol/] #2 -4,.2.

log['ol/] #3 -4,.2.

E* g*,al las '!*as sul* ,aaa, o* ",*as " ,s!"

E* l ,a*go " 55 a 142 u'pl o* los l'!s p,'!s!l*o "'os ",*os " 10.5 u 11 po, p,au!* pa,a


23/84

! l pH pa,a s aso ua " 60 a 80 po"'os "!,

l'!s p,'!s!ls.

Os,a'os * la g,:a a"u*a u !s u* '*!'o logl pH;88.


24/84


25/84


26/84

3.15E-05

os *o 'u& !"os.

p,o sa'os uo "aa, las u,as.


27/84

u u'pl o* los

[CuT];-990 ua*"o"!, u s

a"as).


28/84


29/84

Cu(+2a) + 2H2O = Cu(OH)2 + 2H(+a)

T K

C kJ J/K kJ

0 69.491 114.366 38.252 4.834E-008

5 57.369 69.991 37.901 7.617E-00810 57.187 69.342 37.553 1.180E-007

15 56.948 68.506 37.208 1.797E-007

20 56.669 67.544 36.868 2.692E-007

25 56.360 66.500 36.533 3.972E-007

30 56.033 65.412 36.203 5.773E-007

35 55.695 64.307 35.879 8.273E-007

40 55.352 63.204 35.560 1.169E-006

45 55.009 62.116 35.247 1.632E-006

50 54.667 61.051 34.939 2.249E-006

55 54.328 60.008 34.636 3.063E-00660 53.990 58.986 34.339 4.126E-006

65 53.657 57.993 34.046 5.500E-006

70 53.332 57.040 33.759 7.257E-006

75 53.017 56.127 33.476 9.485E-006

80 52.711 55.256 33.197 1.228E-005

85 52.417 54.429 32.923 1.577E-005

90 52.135 53.648 32.653 2.008E-005

95 51.867 52.914 32.387 2.538E-005

100 51.614 52.230 32.124 3.183E-005


T K

C kJ J/K kJ

0 17.596 91.874 -7.500 2.718E+001

5 11.241 68.620 -7.846 2.975E+001

10 10.897 67.396 -8.186 3.238E+001

15 10.559 66.213 -8.520 3.504E+001

20 10.228 65.071 -8.848 3.773E+001

25 9.903 63.972 -9.171 4.044E+001

30 9.585 62.916 -9.488 4.315E+001

35 9.275 61.902 -9.800 4.585E+001

40 8.973 60.930 -10.107 4.853E+001

45 8.680 60.000 -10.409 5.119E+001

50 8.394 59.108 -10.707 5.381E+001

55 8.116 58.256 -11.000 5.639E+001

60 7.847 57.440 -11.290 5.892E+001

H S G

H S G


30/84

65 7.584 56.659 -11.575 6.139E+001

70 7.331 55.914 -11.856 6.381E+001

75 7.085 55.203 -12.134 6.617E+001

80 6.848 54.527 -12.408 6.847E+001

85 6.619 53.884 -12.679 7.069E+001

90 6.399 53.274 -12.947 7.285E+001

95 6.189 52.698 -13.212 7.495E+001100 5.987 52.155 -13.474 7.697E+001

Cu(OH)3(-a) + H(+a) = Cu(OH)2 + H2O

T K

C kJ J/K kJ

0 -90.758 55.871 -106.020 1.888E+020

5 -83.126 83.761 -106.424 9.712E+019

10 -81.479 89.630 -106.857 5.180E+01915 -79.811 95.469 -107.320 2.859E+019

20 -78.122 101.279 -107.812 1.629E+019

25 -76.413 107.059 -108.333 9.573E+018

30 -74.684 112.810 -108.882 5.790E+018

35 -72.935 118.531 -109.461 3.600E+018

40 -71.167 124.225 -110.068 2.298E+018

45 -69.379 129.889 -110.703 1.503E+018

50 -67.571 135.526 -111.367 1.007E+018

55 -65.745 141.135 -112.058 6.900E+017

60 -63.899 146.717 -112.778 4.830E+017

65 -62.034 152.273 -113.525 3.451E+017

70 -60.151 157.803 -114.301 2.514E+017

75 -58.248 163.307 -115.103 1.866E+017

80 -56.327 168.786 -115.934 1.410E+017

85 -54.387 174.240 -116.791 1.084E+017

90 -52.428 179.671 -117.676 8.465E+016

95 -50.451 185.079 -118.588 6.716E+016

100 -48.455 190.463 -119.527 5.409E+016

Cu(OH)4(-2a) + 2H(+a) = Cu(OH)2 + 2H2O

T K

C kJ J/K kJ

0 -146.819 140.046 -185.072 2.480E+035

5 -132.336 192.986 -186.015 8.614E+034

10 -129.837 201.891 -187.002 3.165E+034

15 -127.307 210.745 -188.034 1.227E+034

H S G

H S G


31/84

20 -124.749 219.548 -189.109 5.001E+033

25 -122.161 228.300 -190.229 2.138E+033

30 -119.545 237.004 -191.392 9.568E+032

35 -116.899 245.658 -192.599 4.469E+032

40 -114.226 254.265 -193.849 2.175E+032

45 -111.524 262.824 -195.141 1.100E+032

50 -108.794 271.337 -196.477 5.775E+031

55 -106.037 279.806 -197.855 3.140E+031

60 -103.251 288.230 -199.275 1.766E+031

65 -100.438 296.611 -200.737 1.025E+031

70 -97.597 304.950 -202.241 6.136E+030

75 -94.729 313.249 -203.786 3.781E+030

80 -91.833 321.507 -205.373 2.396E+030

85 -88.910 329.727 -207.001 1.559E+030

90 -85.959 337.909 -208.671 1.040E+030

95 -82.980 346.054 -210.380 7.114E+029100 -79.975 354.164 -212.131 4.980E+029


32/84


33/84

[H(+a)] pH [Cu(+2a)]

Log(K) 1.00E+00 0.0 1.313E+007

3.16E-01 0.5 1.313E+006

-7.316 1.00E-01 1.0 1.313E+005

-7.118 3.16E-02 1.5 1.313E+004-6.928 1.00E-02 2.0 1.313E+003

-6.746 3.16E-03 2.5 1.313E+002

-6.570 1.00E-03 3.0 1.313E+001

-6.401 3.16E-04 3.5 1.313E+000

-6.239 1.00E-04 4.0 1.313E-001

-6.082 3.16E-05 4.5 1.313E-002

-5.932 1.00E-05 5.0 1.313E-003

-5.787 3.16E-06 5.5 1.313E-004

-5.648 1.00E-06 6.0 1.313E-005

-5.514 3.16E-07 6.5 1.313E-006-5.384 1.00E-07 7.0 1.313E-007

-5.260 3.16E-08 7.5 1.313E-008

-5.139 1.00E-08 8.0 1.313E-009

-5.023 3.16E-09 8.5 1.313E-010

-4.911 1.00E-09 9.0 1.313E-011

-4.802 3.16E-10 9.5 1.313E-012

-4.697 1.00E-10 10.0 1.313E-013

-4.596 3.16E-11 10.5 1.313E-014

-4.497 1.00E-11 11.0 1.313E-015

3.16E-12 11.5 1.313E-016

1.00E-12 12.0 1.313E-017

3.16E-13 12.5 1.313E-018

1.00E-13 13.0 1.313E-019

Log(K) 3.16E-14 13.5 1.313E-020

1.00E-14 14.0 1.313E-021

1.434 3.16E-15 14.5 1.313E-022

1.474 1.00E-15 15.0 1.313E-023

1.510 3.16E-16 15.5 1.313E-024

1.545 1.00E-16 16.0 1.313E-025

1.577 3.16E-17 16.5 1.313E-026

1.607 1.00E-17 17.0 1.313E-027

1.635 3.16E-18 17.5 1.313E-028

1.661 1.00E-18 18.0 1.313E-029

1.686 3.16E-19 18.5 1.313E-030

1.709 1.00E-19 19.0 1.313E-031

1.731 3.16E-20 19.5 1.313E-032

1.751 1.00E-20 20.0 1.313E-033

1.770


34/84

1.788

1.805

1.821

1.835

1.849

1.862

1.8751.886

Log(K)

20.276

19.987

19.71419.456

19.212

18.981

18.763

18.556

18.361

18.177

18.003

17.839

17.684

17.538

17.400

17.271

17.149

17.035

16.928

16.827

16.733

Log(K)

35.394

34.935

34.500

34.089

0

0%

5%

10%15%

20%

25%

30%

35%

40%

45%

50%

55%60%

65%

70%

75%

80%

85%

90%

95%

100%

D

# Co!e$ra!i%

0 1 2 3

0

5


35/84

33.699

33.330

32.981

32.650

32.337

32.041

31.762

31.497

31.247

31.011

30.788

30.578

30.379

30.193

30.017

29.85229.697

-45

-40

-35

-30

-25

-20

-15

-10

-5

ogCuT*

0 1 2

1.000E-023

1.000E-019

1.000E-015

1.000E-011

1.000E-007

1.000E-003

1.000E+001

ogCuT*


36/84

1.000E-043

1.000E-039

1.000E-035

1.000E-031

1.000E-027


37/84

[CuOH(+a)] [Cu(OH)3(-a)] [Cu(OH)4(-2a)] [CuT] [Cu(+2a)]/[CuT]

3.361E-002 1.030E-020 1.16096670E-035 1.313E+007 1.000E+000

1.063E-002 3.256E-020 1.16096670E-034 1.313E+006 1.000E+000

3.361E-003 1.030E-019 1.16096670E-033 1.313E+005 1.000E+000

1.063E-003 3.256E-019 1.16096670E-032 1.313E+004 1.000E+0003.361E-004 1.030E-018 1.16096670E-031 1.313E+003 1.000E+000

1.063E-004 3.256E-018 1.16096670E-030 1.313E+002 1.000E+000

3.361E-005 1.030E-017 1.16096670E-029 1.313E+001 1.000E+000

1.063E-005 3.256E-017 1.16096670E-028 1.313E+000 1.000E+000

3.361E-006 1.030E-016 1.16096670E-027 1.313E-001 1.000E+000

1.063E-006 3.256E-016 1.16096670E-026 1.313E-002 9.999E-001

3.361E-007 1.030E-015 1.16096670E-025 1.313E-003 9.997E-001

1.063E-007 3.256E-015 1.16096670E-024 1.314E-004 9.992E-001

3.361E-008 1.030E-014 1.16096670E-023 1.316E-005 9.974E-001

1.063E-008 3.256E-014 1.16096670E-022 1.323E-006 9.920E-0013.361E-009 1.030E-013 1.16096670E-021 1.346E-007 9.750E-001

1.063E-009 3.256E-013 1.16096670E-020 1.419E-008 9.251E-001

3.361E-010 1.030E-012 1.16096670E-019 1.650E-009 7.957E-001

1.063E-010 3.256E-012 1.16096670E-018 2.408E-010 5.451E-001

3.361E-011 1.030E-011 1.16096670E-017 5.704E-011 2.302E-001

1.063E-011 3.256E-011 1.16096670E-016 4.450E-011 2.950E-002

3.361E-012 1.030E-010 1.16096670E-015 1.065E-010 1.233E-003

1.063E-012 3.256E-010 1.16096670E-014 3.267E-010 4.019E-005

3.361E-013 1.030E-009 1.16096670E-013 1.030E-009 1.275E-006

1.063E-013 3.256E-009 1.16096670E-012 3.257E-009 4.031E-008

3.361E-014 1.030E-008 1.16096670E-011 1.031E-008 1.274E-009

1.063E-014 3.256E-008 1.16096670E-010 3.268E-008 4.018E-011

3.361E-015 1.030E-007 1.16096670E-009 1.041E-007 1.261E-012

1.063E-015 3.256E-007 1.16096670E-008 3.372E-007 3.893E-014

3.361E-016 1.030E-006 1.16096670E-007 1.146E-006 1.146E-015

1.063E-016 3.256E-006 0.000001161 4.417E-006 2.972E-017

3.361E-017 1.030E-005 1.16096670E-005 2.191E-005 5.993E-019

1.063E-017 3.256E-005 0.0001160967 1.487E-004 8.831E-021

3.361E-018 1.030E-004 0.0011609667 1.264E-003 1.039E-022

1.063E-018 3.256E-004 0.011609667 1.194E-002 1.100E-024

3.361E-019 1.030E-003 0.1160966696 1.171E-001 1.121E-026

1.063E-019 3.256E-003 1.1609666956 1.164E+000 1.128E-028

3.361E-020 1.030E-002 11.6096669557 1.162E+001 1.130E-030

1.063E-020 3.256E-002 116.0966695573 1.161E+002 1.131E-032

3.361E-021 1.030E-001 1160.966695573 1.161E+003 1.131E-034

1.063E-021 3.256E-001 11609.66695573 1.161E+004 1.131E-036

3.361E-022 1.030E+000 116096.6695573 1.161E+005 1.131E-038


38/84

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

iagrama de Predomia!ia

[Cu(

[CuO

[Cu(

[Cu(

"H

4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Diagrama de &'errum


39/84

"H

3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Diagrama de &'errum


40/84

"H


41/84

[CuOH(+a)]/[CuT] [Cu(OH)3(-a)]/[CuT] [Cu(OH)4(-2a)]/[CuT] log[CuT]

2.560E-009 7.843E-028 8.843E-043 7.1182174532

8.096E-009 2.480E-026 8.843E-041 6.1182174556

2.560E-008 7.843E-025 8.843E-039 5.1182174632

8.096E-008 2.480E-023 8.843E-037 4.11821748732.560E-007 7.843E-022 8.843E-035 3.1182175633

8.096E-007 2.480E-020 8.843E-033 2.1182178037

2.560E-006 7.843E-019 8.843E-031 1.118218564

8.096E-006 2.480E-017 8.843E-029 0.1182209682

2.560E-005 7.842E-016 8.843E-027 -0.8817714291

8.096E-005 2.480E-014 8.842E-025 -1.881747388

2.560E-004 7.841E-013 8.841E-023 -2.8816713724

8.090E-004 2.478E-011 8.836E-021 -3.8814310773

2.554E-003 7.823E-010 8.820E-019 -4.880672071

8.031E-003 2.460E-008 8.772E-017 -5.87828056582.496E-002 7.647E-007 8.622E-015 -6.8708031929

7.490E-002 2.294E-005 8.181E-013 -7.8479622148

2.037E-001 6.240E-004 7.036E-011 -8.782513566

4.413E-001 1.352E-002 4.821E-009 -9.6182839684

5.893E-001 1.805E-001 2.035E-007 -10.2438424037

2.388E-001 7.316E-001 2.609E-006 -10.3516228852

3.157E-002 9.672E-001 1.091E-005 -9.972828585

3.254E-003 9.967E-001 3.554E-005 -9.4858720027

3.263E-004 9.996E-001 1.127E-004 -8.9871290844

3.263E-005 9.996E-001 3.564E-004 -8.4871513244

3.261E-006 9.989E-001 1.126E-003 -7.9868295069

3.253E-007 9.964E-001 3.553E-003 -7.4857744072

3.228E-008 9.889E-001 1.115E-002 -6.9824507937

3.152E-009 9.656E-001 3.443E-002 -6.4721045568

2.934E-010 8.987E-001 1.013E-001 -5.9409203518

2.406E-011 7.372E-001 2.628E-001 -5.3548793677

1.534E-012 4.700E-001 5.300E-001 -4.6594382906

7.150E-014 2.190E-001 7.810E-001 -3.8278166388

2.659E-015 8.146E-002 9.185E-001 -2.898277207

8.906E-017 2.728E-002 9.727E-001 -1.9231679919

2.870E-018 8.791E-003 9.912E-001 -0.9313455909

9.130E-020 2.797E-003 9.972E-001 0.066036048

2.893E-021 8.861E-004 9.991E-001 1.0652047534

9.153E-023 2.804E-004 9.997E-001 2.0649415435

2.895E-024 8.868E-005 9.999E-001 3.064858276

9.155E-026 2.804E-005 1.000E+000 4.0648319411

2.895E-027 8.869E-006 1.000E+000 5.064823613


42/84

2a)]/[CuT]

(+a)]/[CuT]

H)3(-a)]/[CuT]

H)4(-2a)]/[CuT]

0 1 2 3 4 5 6 7

-40

-35

-30

-25

-20

-15

-10

-5

0

5

10

Diagr

ogCuT*

0 1 2 3 4 5 6 7

10

Diagr


43/84

-15

-10

-5

0

5

ogCuT*

5 6 7 8

-8

-7

-6

-5

-4

Diagr

ogCuT*

log[Cu(+2a)]

log[CuOH(+a)]

log[Cu(OH)3(-a)]

log[Cu(OH)4(-2a)]

[Cu(+2a)]

[CuOH(+a)]

[Cu(OH)3(-a)]

[Cu(OH)4(-2a)]


44/84

-11

-10

-9


45/84

log[Cu(+2a)] log[CuOH(+a)] log[Cu(OH)3(-a)] log[Cu(OH)4(-2a)]

7.1182174521 -1.473502094 -19.9873203414 -34.9351802386

6.1182174521 -1.973502094 -19.4873203414 -33.9351802386

5.1182174521 -2.473502094 -18.9873203414 -32.9351802386

4.1182174521 -2.973502094 -18.4873203414 -31.93518023863.1182174521 -3.473502094 -17.9873203414 -30.9351802386

2.1182174521 -3.973502094 -17.4873203414 -29.9351802386

1.1182174521 -4.473502094 -16.9873203414 -28.9351802386

0.1182174521 -4.973502094 -16.4873203414 -27.9351802386

-0.8817825479 -5.473502094 -15.9873203414 -26.9351802386

-1.8817825479 -5.973502094 -15.4873203414 -25.9351802386

-2.8817825479 -6.473502094 -14.9873203414 -24.9351802386

-3.8817825479 -6.973502094 -14.4873203414 -23.9351802386

-4.8817825479 -7.473502094 -13.9873203414 -22.9351802386

-5.8817825479 -7.973502094 -13.4873203414 -21.9351802386-6.8817825479 -8.473502094 -12.9873203414 -20.9351802386

-7.8817825479 -8.973502094 -12.4873203414 -19.9351802386

-8.8817825479 -9.473502094 -11.9873203414 -18.9351802386

-9.8817825479 -9.973502094 -11.4873203414 -17.9351802386

-10.8817825479 -10.473502094 -10.9873203414 -16.9351802386

-11.8817825479 -10.973502094 -10.4873203414 -15.9351802386

-12.8817825479 -11.473502094 -9.9873203414 -14.9351802386

-13.8817825479 -11.973502094 -9.4873203414 -13.9351802386

-14.8817825479 -12.473502094 -8.9873203414 -12.9351802386

-15.8817825479 -12.973502094 -8.4873203414 -11.9351802386

-16.8817825479 -13.473502094 -7.9873203414 -10.9351802386

-17.8817825479 -13.973502094 -7.4873203414 -9.9351802386

-18.8817825479 -14.473502094 -6.9873203414 -8.9351802386

-19.8817825479 -14.973502094 -6.4873203414 -7.9351802386

-20.8817825479 -15.473502094 -5.9873203414 -6.9351802386

-21.8817825479 -15.973502094 -5.4873203414 -5.9351802386

-22.8817825479 -16.473502094 -4.9873203414 -4.9351802386

-23.8817825479 -16.973502094 -4.4873203414 -3.9351802386

-24.8817825479 -17.473502094 -3.9873203414 -2.9351802386

-25.8817825479 -17.973502094 -3.4873203414 -1.9351802386

-26.8817825479 -18.473502094 -2.9873203414 -0.9351802386

-27.8817825479 -18.973502094 -2.4873203414 0.0648197614

-28.8817825479 -19.473502094 -1.9873203414 1.0648197614

-29.8817825479 -19.973502094 -1.4873203414 2.0648197614

-30.8817825479 -20.473502094 -0.9873203414 3.0648197614

-31.8817825479 -20.973502094 -0.4873203414 4.0648197614

-32.8817825479 -21.473502094 0.0126796586 5.0648197614


46/84

8 9 10 11 12 13 14 15 16 17 18 19 20

ma de Souiidad

log[Cu

log[Cu(

log[Cu

log[Cu(

log[Cu(

EC# #1

"H

8 9 10 11 12 13 14 15 16 17 18 19 20

ma de Souiidad


47/84

log[C

EC#

"H

10 11 12 13 14 15 16

ama de Souiidad

log[C

EC#


48/84

"H


49/84

log([Cu(+2a)]/[CuT]) log([CuOH(+a)]/[CuT]) log([Cu(OH)3(-a)]/[CuT])

-1.111897535856E-009 -8.5917195472 -27.1055377946

-3.516128653043E-009 -8.0917195496 -25.605537797

-1.111897514915E-008 -7.5917195572 -24.1055378046

-3.516128573816E-008 -7.0917195812 -22.6055378286-1.111897386988E-007 -6.5917196572 -21.1055379046

-3.516127294550E-007 -6.0917198977 -19.6055381451

-1.111896106032E-006 -5.5917206579 -18.1055389054

-3.516114484158E-006 -5.0917230622 -16.6055413096

-1.111883296078E-005 -4.5917306649 -15.1055489123

-3.515986390286E-005 -4.0917547059 -13.6055729533

-0.0001111755 -3.5918307216 -12.105648969

-0.0003514706 -3.0920710167 -10.6058892641

-0.0011104769 -2.592830023 -9.1066482704

-0.0035019821 -2.0952215282 -7.6090397756-0.010979355 -1.602698901 -6.1165171484

-0.0338203331 -1.1255398791 -4.6393581265

-0.0992689819 -0.690988528 -3.2048067754

-0.2634985795 -0.3552181255 -1.8690363729

-0.6379401442 -0.2296596903 -0.7434779377

-1.5301596627 -0.6218792088 -0.1356974562

-2.9089539629 -1.5006735089 -0.0144917564

-4.3959105452 -2.4876300913 -0.0014483387

-5.8946534635 -3.4863730095 -0.0001912569

-7.3946312235 -4.4863507695 -0.0001690169

-8.894953041 -5.486672587 -0.0004908344

-10.3960081407 -6.4877276867 -0.0015459341

-11.8993317542 -7.4910513003 -0.0048695477

-13.4096779911 -8.5013975371 -0.0152157845

-14.9408621961 -9.5325817422 -0.0463999896

-16.5269031802 -10.6186227263 -0.1324409737

-18.2223442573 -11.8140638033 -0.3278820508

-20.0539659091 -13.1456854551 -0.6595037025

-21.9835053409 -14.5752248869 -1.0890431343

-23.958614556 -16.050334102 -1.5641523494

-25.950436957 -17.5421565031 -2.0559747505

-27.9478185959 -19.039538142 -2.5533563894

-29.9469873013 -20.5387068473 -3.0525250947

-31.9467240914 -22.0384436374 -3.5522618848

-33.9466408239 -23.5383603699 -4.0521786173

-35.946614489 -25.0383340351 -4.5521522825

-37.9466061609 -26.538325707 -5.0521439544


50/84

EC# Cu #1

'g/ #2

'g/ #3

EC# * #1

'ol/ #2

'ol/ #3

EC# * #1

log['ol/] #2

log['ol/] #3

]

+2a)]

H(+a)]

OH)3(-a)]

OH)4(-2a)]

#2 & #3


51/84

E* g*,al las '!*as sul* ,aaa,E* l ,a*go " 59 a 151 u'pl o* l

*o "'os ",*os " 10.5 u 11! l pH pa,a s aso ua " 60

l'!s p,'!s!ls.

Os,a'os * la g,:a a"u*a u

l pH;93.


52/84


53/84

log([Cu(OH)4(-2a)]/[CuT])

-42.0533976918

-40.0533976942

-38.0533977018

-36.0533977259-34.0533978019

-32.0533980423

-30.0533988026

-28.0534012068

-26.0534088095

-24.0534328506

-22.0535088662

-20.0537491613

-18.0545081676

-16.0568996729-14.0643770457

-12.0872180238

-10.1526666726

-8.3168962702

-6.6913378349

-5.5835573534

-4.9623516536

-4.4493082359

-3.9480511542

-3.4480289142

-2.9483507317

-2.4494058314

-1.9527294449

-1.4630756818

-0.9942598868

-0.5803008709

-0.275741948

-0.1073635998

-0.0369030316

-0.0120122467

-0.0038346477

-0.0012162866

-0.000384992

-0.0001217821

-3.85145609211515E-005

-1.21797428358182E-005

-3.85160979724862E-006


54/84

2

2

2

3.15E-05

3.15E-05

3.15E-05

-4,.2.2

-4,.2.2

-4,.2.2


55/84

o* ",*as " ,s!"uos *o 'u& !"os.os l'!s p,'!s!ls p,o sa'os u

o, p,au!* pa,a *o "aa, las u,as.80 po"'os "!, u u'pl o* los

!s u* '*!'o log[CuT];-104 ua*"o

o*lus!* po"'os "!, u s!=a*"o ,oas a,o*aa"as).


56/84


57/84

Cu(+2a) + 2H2O = Cu(OH)2 + 2H(+a)

T K

C kJ J/K kJ

0 69.491 114.366 38.252 4.834E-008

5 57.369 69.991 37.901 7.617E-008

10 57.187 69.342 37.553 1.180E-007

15 56.948 68.506 37.208 1.797E-007

20 56.669 67.544 36.868 2.692E-007

25 56.360 66.500 36.533 3.972E-007

30 56.033 65.412 36.203 5.773E-007

35 55.695 64.307 35.879 8.273E-007

40 55.352 63.204 35.560 1.169E-006

45 55.009 62.116 35.247 1.632E-006

50 54.667 61.051 34.939 2.249E-006

55 54.328 60.008 34.636 3.063E-006

60 53.990 58.986 34.339 4.126E-006

65 53.657 57.993 34.046 5.500E-006

70 53.332 57.040 33.759 7.257E-006

75 53.017 56.127 33.476 9.485E-006

80 52.711 55.256 33.197 1.228E-005

85 52.417 54.429 32.923 1.577E-005

90 52.135 53.648 32.653 2.008E-005

95 51.867 52.914 32.387 2.538E-005

100 51.614 52.230 32.124 3.183E-005


T K

C kJ J/K kJ

0 17.596 91.874 -7.500 2.718E+001

5 11.241 68.620 -7.846 2.975E+001

10 10.897 67.396 -8.186 3.238E+001

15 10.559 66.213 -8.520 3.504E+001

20 10.228 65.071 -8.848 3.773E+001

25 9.903 63.972 -9.171 4.044E+001

30 9.585 62.916 -9.488 4.315E+001

35 9.275 61.902 -9.800 4.585E+001

40 8.973 60.930 -10.107 4.853E+001

45 8.680 60.000 -10.409 5.119E+001

50 8.394 59.108 -10.707 5.381E+001

55 8.116 58.256 -11.000 5.639E+001

60 7.847 57.440 -11.290 5.892E+001

65 7.584 56.659 -11.575 6.139E+001

70 7.331 55.914 -11.856 6.381E+001

75 7.085 55.203 -12.134 6.617E+001

H S G

H S G


58/84

80 6.848 54.527 -12.408 6.847E+001

85 6.619 53.884 -12.679 7.069E+001

90 6.399 53.274 -12.947 7.285E+001

95 6.189 52.698 -13.212 7.495E+001

100 5.987 52.155 -13.474 7.697E+001

Cu(OH)3(-a) + H(+a) = Cu(OH)2 + H2O

T K

C kJ J/K kJ

0 -90.758 55.871 -106.020 1.888E+020

5 -83.126 83.761 -106.424 9.712E+019

10 -81.479 89.630 -106.857 5.180E+019

15 -79.811 95.469 -107.320 2.859E+019

20 -78.122 101.279 -107.812 1.629E+019

25 -76.413 107.059 -108.333 9.573E+018

30 -74.684 112.810 -108.882 5.790E+018

35 -72.935 118.531 -109.461 3.600E+018

40 -71.167 124.225 -110.068 2.298E+018

45 -69.379 129.889 -110.703 1.503E+018

50 -67.571 135.526 -111.367 1.007E+018

55 -65.745 141.135 -112.058 6.900E+017

60 -63.899 146.717 -112.778 4.830E+017

65 -62.034 152.273 -113.525 3.451E+017

70 -60.151 157.803 -114.301 2.514E+017

75 -58.248 163.307 -115.103 1.866E+017

80 -56.327 168.786 -115.934 1.410E+017

85 -54.387 174.240 -116.791 1.084E+017

90 -52.428 179.671 -117.676 8.465E+016

95 -50.451 185.079 -118.588 6.716E+016

100 -48.455 190.463 -119.527 5.409E+016

CuO2(-2a) + 2H(+a) = Cu(OH)2

T K

C kJ J/K kJ

0 -148.217 173.046 -195.484 2.430E+037

5 -146.021 181.013 -196.370 7.585E+036

10 -144.062 187.994 -197.293 2.506E+036

15 -142.286 194.211 -198.248 8.723E+035

20 -140.648 199.848 -199.234 3.186E+035

25 -139.110 205.050 -200.246 1.217E+035

30 -137.642 209.934 -201.284 4.845E+034

35 -136.220 214.588 -202.345 2.007E+03440 -134.826 219.076 -203.429 8.623E+033

45 -133.447 223.443 -204.536 3.837E+033

H S G

H S G


59/84

50 -132.078 227.714 -205.664 1.765E+033

55 -130.715 231.900 -206.813 8.376E+032

60 -129.360 235.997 -207.982 4.096E+032

65 -128.003 240.040 -209.173 2.060E+032

70 -126.633 244.061 -210.383 1.065E+032

75 -125.248 248.068 -211.613 5.649E+03180 -123.845 252.070 -212.864 3.072E+031

85 -122.420 256.076 -214.134 1.710E+031

90 -120.971 260.096 -215.424 9.743E+030

95 -119.492 264.138 -216.735 5.673E+030

100 -117.982 268.213 -218.066 3.373E+030


60/84


61/84

[H(+a)] pH [Cu(+2a)]

Log(K) 1.00E+00 0.0 3.940E+004

3.16E-01 0.5 3.940E+003

-7.316 1.00E-01 1.0 3.940E+002

-7.118 3.16E-02 1.5 3.940E+001

-6.928 1.00E-02 2.0 3.940E+000

-6.746 3.16E-03 2.5 3.940E-001

-6.570 1.00E-03 3.0 3.940E-002

-6.401 3.16E-04 3.5 3.940E-003

-6.239 1.00E-04 4.0 3.940E-004

-6.082 3.16E-05 4.5 3.940E-005

-5.932 1.00E-05 5.0 3.940E-006

-5.787 3.16E-06 5.5 3.940E-007

-5.648 1.00E-06 6.0 3.940E-008

-5.514 3.16E-07 6.5 3.940E-009

-5.384 1.00E-07 7.0 3.940E-010

-5.260 3.16E-08 7.5 3.940E-011

-5.139 1.00E-08 8.0 3.940E-012

-5.023 3.16E-09 8.5 3.940E-013

-4.911 1.00E-09 9.0 3.940E-014

-4.802 3.16E-10 9.5 3.940E-015

-4.697 1.00E-10 10.0 3.940E-016

-4.596 3.16E-11 10.5 3.940E-017

-4.497 1.00E-11 11.0 3.940E-018

3.16E-12 11.5 3.940E-019

1.00E-12 12.0 3.940E-020

3.16E-13 12.5 3.940E-021

1.00E-13 13.0 3.940E-022

Log(K) 3.16E-14 13.5 3.940E-023

1.00E-14 14.0 3.940E-024

1.434 3.16E-15 14.5 3.940E-025

1.474 1.00E-15 15.0 3.940E-026

1.510 3.16E-16 15.5 3.940E-027

1.545 1.00E-16 16.0 3.940E-028

1.577 3.16E-17 16.5 3.940E-029

1.607 1.00E-17 17.0 3.940E-030

1.635 3.16E-18 17.5 3.940E-031

1.661 1.00E-18 18.0 3.940E-032

1.686 3.16E-19 18.5 3.940E-033

1.709 1.00E-19 19.0 3.940E-034

1.731 3.16E-20 19.5 3.940E-035

1.751 1.00E-20 20.0 3.940E-036

1.770

1.788

1.805

1.821


62/84

1.835

1.849

1.862

1.875

1.886

Log(K)

20.276

19.987

19.714

19.456

19.212

18.981

18.763

18.556

18.361

18.177

18.003

17.839

17.684

17.538

17.400

17.271

17.149

17.035

16.928

16.827

16.733

Log(K)

37.386

36.880

36.399

35.941

35.503

35.085

34.685

34.30233.936

33.584

0

0%

5%

10%

15%

20%

25%

30%

35%

40%

45%

50%

55%

60%

65%

70%

75%

80%

85%

90%

95%

100%

D

# Co!e$ra!i%

0 1 2 3

-15

-10

-5

0

5


63/84

33.247

32.923

32.612

32.314

32.027

31.75231.487

31.233

30.989

30.754

30.528

-50

-45

-40

-35

-30

-25

-20ogCuT*

0 1 2

1.000E-047

1.000E-043

1.000E-039

1.000E-035

1.000E-031

1.000E-027

1.000E-023

1.000E-019

1.000E-015

1.000E-011

1.000E-007

1.000E-003

1.000E+001

ogCuT*


64/84


65/84

[CuOH(+a)] [Cu(OH)3(-a)] [CuO2(-2a)] [CuT] [Cu(+2a)]/[CuT]

1.334E-002 1.489E-017 1.762801E-031 3.940E+004 1.000E+000

4.219E-003 4.708E-017 1.762801E-030 3.940E+003 1.000E+000

1.334E-003 1.489E-016 1.762801E-029 3.940E+002 1.000E+000

4.219E-004 4.708E-016 1.762801E-028 3.941E+001 1.000E+000

1.334E-004 1.489E-015 1.762801E-027 3.941E+000 1.000E+000

4.219E-005 4.708E-015 1.762801E-026 3.941E-001 9.999E-001

1.334E-005 1.489E-014 1.762801E-025 3.942E-002 9.997E-001

4.219E-006 4.708E-014 1.762801E-024 3.945E-003 9.989E-001

1.334E-006 1.489E-013 1.762801E-023 3.954E-004 9.966E-001

4.219E-007 4.708E-013 1.762801E-022 3.983E-005 9.894E-001

1.334E-007 1.489E-012 1.762801E-021 4.074E-006 9.672E-001

4.219E-008 4.708E-012 1.762801E-020 4.362E-007 9.033E-001

1.334E-008 1.489E-011 1.762801E-019 5.276E-008 7.468E-001

4.219E-009 4.708E-011 1.762801E-018 8.207E-009 4.801E-001

1.334E-009 1.489E-010 1.762801E-017 1.877E-009 2.099E-001

4.219E-010 4.708E-010 1.762801E-016 9.322E-010 4.227E-002

1.334E-010 1.489E-009 1.762801E-015 1.626E-009 2.423E-003

4.219E-011 4.708E-009 1.762801E-014 4.751E-009 8.294E-005

1.334E-011 1.489E-008 1.762801E-013 1.490E-008 2.644E-006

4.219E-012 4.708E-008 1.762801E-012 4.709E-008 8.368E-008

1.334E-012 1.489E-007 1.762801E-011 1.489E-007 2.646E-009

4.219E-013 4.708E-007 1.762801E-010 4.710E-007 8.366E-011

1.334E-013 1.489E-006 1.762801E-009 1.491E-006 2.643E-012

4.219E-014 4.708E-006 1.762801E-008 4.726E-006 8.338E-014

1.334E-014 1.489E-005 1.762801E-007 1.507E-005 2.616E-015

4.219E-015 4.708E-005 1.762801E-006 4.885E-005 8.067E-017

1.334E-015 1.489E-004 0.000017628 1.665E-004 2.366E-018

4.219E-016 4.708E-004 0.0001762801 6.471E-004 6.089E-020

1.334E-016 1.489E-003 0.0017628005 3.252E-003 1.212E-021

4.219E-017 4.708E-003 0.0176280053 2.234E-002 1.764E-023

1.334E-017 1.489E-002 0.1762800526 1.912E-001 2.061E-025

4.219E-018 4.708E-002 1.7628005258 1.810E+000 2.177E-027

1.334E-018 1.489E-001 17.6280052582 1.778E+001 2.217E-029

4.219E-019 4.708E-001 176.280052582 1.768E+002 2.229E-031

1.334E-019 1.489E+000 1762.80052582 1.764E+003 2.233E-033

4.219E-020 4.708E+000 17628.0052582 1.763E+004 2.235E-035

1.334E-020 1.489E+001 176280.052582 1.763E+005 2.235E-037

4.219E-021 4.708E+001 1762800.52582 1.763E+006 2.235E-039

1.334E-021 1.489E+002 17628005.2582 1.763E+007 2.235E-041

4.219E-022 4.708E+002 176280052.582 1.763E+008 2.235E-043

1.334E-022 1.489E+003 1762800525.82 1.763E+009 2.235E-045


66/84

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

iagrama de Predomia!ia

[Cu(

[Cu

[Cu(

[Cu

"H

4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Diagrama de &'errum


67/84

"H

3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Diagrama de &'errum


68/84

"H


69/84

[CuOH(+a)]/[CuT] [Cu(OH)3(-a)]/[CuT] [CuO2(-2a)]/[CuT] log[CuT]

3.386E-007 3.778E-022 4.474E-036 4.5955478202

1.071E-006 1.195E-020 4.474E-034 3.5955481382

3.386E-006 3.778E-019 4.474E-032 2.5955491437

1.071E-005 1.195E-017 4.474E-030 1.5955523235

3.386E-005 3.778E-016 4.473E-028 0.5955623788

1.071E-004 1.195E-014 4.473E-026 -0.4044058251

3.385E-004 3.777E-013 4.472E-024 -1.4043052923

1.070E-003 1.194E-011 4.469E-022 -2.4039875328

3.375E-003 3.766E-010 4.458E-020 -3.4029842161

1.059E-002 1.182E-008 4.426E-018 -4.3998266148

3.275E-002 3.655E-007 4.327E-016 -5.3899897227

9.672E-002 1.079E-005 4.041E-014 -6.3602686007

2.529E-001 2.822E-004 3.341E-012 -7.2776734329

5.141E-001 5.737E-003 2.148E-010 -8.0858153093

7.108E-001 7.931E-002 9.390E-009 -8.7264791611

4.526E-001 5.051E-001 1.891E-007 -9.0305009811

8.205E-002 9.155E-001 1.084E-006 -8.7888094941

8.881E-003 9.910E-001 3.710E-006 -8.3232253749

8.954E-004 9.991E-001 1.183E-005 -7.8267424065

8.961E-005 9.999E-001 3.744E-005 -7.3270825094

8.961E-006 9.999E-001 1.184E-004 -6.827082414

8.958E-007 9.996E-001 3.743E-004 -6.3269747625

8.951E-008 9.988E-001 1.183E-003 -5.8266237963

8.928E-009 9.963E-001 3.730E-003 -5.3255147379

8.857E-010 9.883E-001 1.170E-002 -4.822026005

8.638E-011 9.639E-001 3.609E-002 -4.3111745516

8.013E-012 8.941E-001 1.059E-001 -3.7785417087

6.520E-013 7.276E-001 2.724E-001 -3.1890231996

4.103E-014 4.579E-001 5.421E-001 -2.4878909482

1.889E-015 2.108E-001 7.892E-001 -1.6509890537

6.980E-017 7.788E-002 9.221E-001 -0.7185826655

2.331E-018 2.601E-002 9.740E-001 0.2576505788

7.506E-020 8.375E-003 9.916E-001 1.2498558863

2.387E-021 2.664E-003 9.973E-001 2.2473615861

7.563E-023 8.439E-004 9.992E-001 3.2465698285

2.393E-024 2.670E-004 9.997E-001 4.246319152

7.569E-026 8.445E-005 9.999E-001 5.246239851

2.394E-027 2.671E-005 1.000E+000 6.2462147708

7.569E-029 8.446E-006 1.000E+000 7.2462068395

2.394E-030 2.671E-006 1.000E+000 8.2462043313

7.569E-032 8.446E-007 1.000E+000 9.2462035382


70/84

+2a)]/[CuT]

H(+a)]/[CuT]

OH)3(-a)]/[CuT]

2(-2a)]/[CuT]

0 1 2 3 4 5 6 7

-40

-35

-30

-25

-20

-15

-10

-5

0

5

10

15

Diagr

ogCuT*

0 1 2 3 4 5 6 7

5

10

15

Diagr

log[Cu(+2a)]


71/84

-10

-5

0

ogCuT*

4 5 6 7

-10

-9

-8

-7

-6

-5

-4

Diagr

ogCuT*

log[CuOH(+a)]

log[Cu(OH)3(-a)]

log[CuO2(-2a)]

[Cu(+2a)]

[CuOH(+a)]

[Cu(OH)3(-a)]

[CuO2(-2a)]


72/84


73/84

log[Cu(+2a)] log[CuOH(+a)] log[Cu(OH)3(-a)] log[CuO2(-2a)]

4.5955476731 -1.874743614 -16.8271377229 -30.7537968286

3.5955476731 -2.374743614 -16.3271377229 -29.7537968286

2.5955476731 -2.874743614 -15.8271377229 -28.7537968286

1.5955476731 -3.374743614 -15.3271377229 -27.7537968286

0.5955476731 -3.874743614 -14.8271377229 -26.7537968286

-0.4044523269 -4.374743614 -14.3271377229 -25.7537968286

-1.4044523269 -4.874743614 -13.8271377229 -24.7537968286

-2.4044523269 -5.374743614 -13.3271377229 -23.7537968286

-3.4044523269 -5.874743614 -12.8271377229 -22.7537968286

-4.4044523269 -6.374743614 -12.3271377229 -21.7537968286

-5.4044523269 -6.874743614 -11.8271377229 -20.7537968286

-6.4044523269 -7.374743614 -11.3271377229 -19.7537968286

-7.4044523269 -7.874743614 -10.8271377229 -18.7537968286

-8.4044523269 -8.374743614 -10.3271377229 -17.7537968286

-9.4044523269 -8.874743614 -9.8271377229 -16.7537968286

-10.4044523269 -9.374743614 -9.3271377229 -15.7537968286

-11.4044523269 -9.874743614 -8.8271377229 -14.7537968286

-12.4044523269 -10.374743614 -8.3271377229 -13.7537968286

-13.4044523269 -10.874743614 -7.8271377229 -12.7537968286

-14.4044523269 -11.374743614 -7.3271377229 -11.7537968286

-15.4044523269 -11.874743614 -6.8271377229 -10.7537968286

-16.4044523269 -12.374743614 -6.3271377229 -9.7537968286

-17.4044523269 -12.874743614 -5.8271377229 -8.7537968286

-18.4044523269 -13.374743614 -5.3271377229 -7.7537968286

-19.4044523269 -13.874743614 -4.8271377229 -6.7537968286

-20.4044523269 -14.374743614 -4.3271377229 -5.7537968286

-21.4044523269 -14.874743614 -3.8271377229 -4.7537968286

-22.4044523269 -15.374743614 -3.3271377229 -3.7537968286

-23.4044523269 -15.874743614 -2.8271377229 -2.7537968286

-24.4044523269 -16.374743614 -2.3271377229 -1.7537968286

-25.4044523269 -16.874743614 -1.8271377229 -0.7537968286

-26.4044523269 -17.374743614 -1.3271377229 0.2462031714

-27.4044523269 -17.874743614 -0.8271377229 1.2462031714

-28.4044523269 -18.374743614 -0.3271377229 2.2462031714

-29.4044523269 -18.874743614 0.1728622771 3.2462031714

-30.4044523269 -19.374743614 0.6728622771 4.2462031714

-31.4044523269 -19.874743614 1.1728622771 5.2462031714

-32.4044523269 -20.374743614 1.6728622771 6.2462031714

-33.4044523269 -20.874743614 2.1728622771 7.2462031714

-34.4044523269 -21.374743614 2.6728622771 8.2462031714

-35.4044523269 -21.874743614 3.1728622771 9.2462031714


74/84

8 9 10 11 12 13 14 15 16 17 18 19 20

ama de Souiidad

log[C

log[C

log[C

log[C

log[C

EC#

"H

8 9 10 11 12 13 14 15 16 17 18 19 20

ama de Souiidad


75/84

log[C

EC#

"H

8 9 10 11 12 13

ama de Souiidad

log[C

EC#


76/84

"H


77/84

log([Cu(+2a)]/[CuT]) log([CuOH(+a)]/[CuT]) log([Cu(OH)3(-a)]/[CuT])

-1.470594545275E-007 -6.4702914342 -21.4226855431

-0.000000465 -5.9702917522 -19.922685861

-1.470592303976E-006 -5.4702927577 -18.4226868666

-4.650404165441E-006 -4.9702959376 -16.9226900464-1.470569895973E-005 -4.4703059928 -15.4227001017

-4.650180097750E-005 -3.9703377889 -13.9227318978

-0.0001470346 -3.4704383217 -12.4228324306

-0.0004647941 -2.9707560813 -10.9231501901

-0.0014681107 -2.4717593979 -9.4241535067

-0.0046257121 -1.9749169993 -7.9273111081

-0.0144626042 -1.4847538913 -6.4371480002

-0.0441837262 -1.0144750134 -4.9668691222

-0.1267788939 -0.5970701811 -3.5494642899

-0.3186370176 -0.2889283047 -2.2413224136-0.6779731657 -0.1482644529 -1.1006585617

-1.3739513457 -0.3442426329 -0.2966367417

-2.6156428328 -1.0859341199 -0.0383282288

-4.0812269519 -2.0515182391 -0.0039123479

-5.5777099203 -3.0480012075 -0.0003953164

-7.0773698175 -4.0476611047 -5.52135126577917E-005

-8.5773699129 -5.0476612 -5.53088644354248E-005

-10.0774775644 -6.0477688516 -0.0001629604

-11.5778285306 -7.0481198177 -0.0005139266

-13.078937589 -8.0492288761 -0.001622985

-14.5824263218 -9.052717609 -0.0051117178

-16.0932777753 -10.0635690624 -0.0159631713

-17.6259106182 -11.0962019054 -0.0485960142

-19.2154291273 -12.1857204144 -0.1381145233

-20.9165613787 -13.3868526659 -0.3392467747

-22.7534632732 -14.7237545603 -0.6761486692

-24.6858696614 -16.1561609485 -1.1085550574

-26.6621029057 -17.6323941928 -1.5847883017

-28.6543082132 -19.1245995003 -2.0769936092

-30.651813913 -20.6221052002 -2.574499309

-32.6510221553 -22.1213134425 -3.0737075513

-34.6507714789 -23.621062766 -3.5734568749

-36.6506921779 -25.120983465 -4.0733775739

-38.6506670977 -26.6209583849 -4.5733524937

-40.6506591664 -28.1209504535 -5.0733445624

-42.6506566582 -29.6209479454 -5.5733420542

-44.6506558651 -31.1209471522 -6.0733412611


78/84

EC# Cu #1

'g/ #2

'g/ #3

EC# * #1

'ol/ #2

'ol/ #3

EC# * #1

log['ol/] #2

log['ol/] #3

E* g*,al las '!*as sul* ,aaa,E* l ,a*go " 46 a 123 u'pl o* l*o "'os ",*os " 10.5 u 11

T]

(+2a)]

OH(+a)]

(OH)3(-a)]

O2(-2a)]

1 #2 & #3


79/84

! l pH pa,a s aso ua " 60

l'!s p,'!s!ls.

Os,a'os * la g,:a a"u*a ul pH;75.


80/84


81/84

log([CuO2(-2a)]/[CuT])

-35.3493446488

-33.3493449668

-31.3493459723

-29.3493491522-27.3493592074

-25.3493910035

-23.3494915363

-21.3498092959

-19.3508126125

-17.3539702139

-15.3638071059

-13.393528228

-11.4761233957

-9.6679815193

-8.0273176675

-6.7232958475

-5.9649873345

-5.4305714537

-4.9270544221

-4.4267143193

-3.9267144146

-3.4268220662

-2.9271730323

-2.4282820907

-1.9317708236

-1.442622277

-0.97525512

-0.564773629

-0.2659058805

-0.1028077749

-0.0352141631

-0.0114474074

-0.0036527149

-0.0011584148

-0.0003666571

-0.0001159806

-3.6679641059815E-005

-1.1599455878888E-005

-3.6681035141089E-006

-0.00000116

-3.6681174560845E-007


82/84

2

2

2

3.15E-05

3.15E-05

3.15E-05

-4,.2.2

-4,.2.2

-4,.2.2

o* ",*as " ,s!"uos *o 'u& !"os.os l'!s p,'!s!ls p,o sa'os uo, p,au!* pa,a *o "aa, las u,as.


83/84

80 po"'os "!, u u'pl o* los

!s u* '*!'o log[CuT];-903 ua*"oo*lus!* po"'os "!, u s!=a*"o ,oas a,o*aa"as).


84/84

Documents

(2013-II) 2da Practica - Cu(OH)2 (Funda II)