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N. Defoer & H. Van Langenhove
Research Group of Environmental Organic Chemistry andTechnology, Ghent University
Introduction
� biological waste treatment is a growing sector in Europe
� 30% of urban waste/industrial residuals is biodegradable or 60 million tons/year
� Flanders (2000): 347 000 tons greenwaste 286 000 tons VFG (vegetable, fruit and garden waste)
Consequence of this growth: odour is becoming anincreasingly sensitive issue!
Aim of this presentation:
Giving an overview of the present knowledge on odouremissions and possible reduction techniques atcomposting facilities
Introduction
Odour generation
� anaerobic conditions
� high temperatures
� stripping
Important mechanisms in odour generation:
Odour generation1. anaerobic conditions
aerobic: organics + O2 → CO2 + H2O
anaerobic: instead of O2 other electronacceptors like NO3-, SO4
2- , oxidized matter and CO2
� results in formation of N2, H2S, organic sulphur compounds,reduced organic compounds and methane
→ efficient aeration, optimal moisture content and appropriateporosity will contribute to less odour production
Note: Anaerobic microsites are hard to avoid in practice!
Odour generation2. High temperatures
Development of typical process phases with own temperatures andproduction of specific odorants
� mesophilic startphase: biogenic odour components (terpenes)
� selfheating phase: volatile biogenic odours
� thermophilic phase: decrease of biogenic odours abiogenic odours by pyrolyse, auto-oxidation, Maillard reactions
� maturation phase: decline in temperature, decrease of microbiological activity
Odour generation
� Activity of thermophilic organisms optimal at 52 to 60°C
� Macgregor et al. (1981), Finstein et al. (1986): reduction in odour production when T < 60°C
� Miller (1993), Toffey et al. (1995), Hentz et al. (1996): increasing odour emission at increasing composting temperatures
3. Stripping
Aeration of biowaste
→ improves input of oxygen
→ promotes output of volatile odorous substances
Odour generation
Flanders: 2 types of waste are composted separately
Odour sources
VFG waste
(vegetable, fruit & garden waste)
composting in closedbuildings
greenwaste
(organic waste from gardens, parks & roadsides)
composting outside
Odour sources
Continuous odour sources
- storage of waste
- composting process
- leachate
Discontinuous odour sources
- dumping of waste
- shredders, mills, �
- turning and moistening of compost
- sieving
- digging up compost
Odour sources
Diffuse odour sources
� leachate, open hall doors, cracks, failure to properly clean facility areas, �
� Kuchta (1994): diffuse odour sources can be up to 10% of total odour emission at composting facilities
Odour sources
Bidlingmaier (1993)Composting stage Air flow
(m3/h)Odour emission
(ou/h × 104)Receiving area 45320 2131Pretreatment 14825 156Composting area -sucking -blowing
134506800
153803400
Storage 3400 34Final treatment 3300 39
� composting area (including turning) most important odour source� immediately prior to turning: 1000 ou.m-3
during turning: 5000 ou.m-3
� relative values more important than absolute values
Odour sources
TNO (1994)
� research at greenwaste composting facilities with different turning frequencies
� turning most important odour source followed by continuous emission of composting piles and storage of biological waste
� contribution of different sources (in percentage) dependent on method of composting
Factors influencing odour emission
History of waste
� storage, frequency and way of collecting
� material too long in collection containers � trash and putrefying odours
� De Bo & Van Langenhove (1999): one week storage of material that was collected every two weeks gave rise to an odour emission of 2 to 6 times higher
Conclusion: it is really important to handle the waste the same day as it is received!
Factors influencing odour emission
Feed composition
� high levels of specific feed like grass can be problematic
� grass fraction > 10%: odour problems are possible
� mechanism: high grass levels (nitrogen source)� no lack of nitrogen� higher rate of oxygen depletion� anaerobic conditions
Possible solution: addition of grass in phases during the composting process
Factors influencing odour emission
Seasonal influence
� cumulation of different effects:- higher waste supply (from June to September supply 2 or 3 times as high as in January and February)
- feed composition (more grass)- higher temperatures
� higher odour emission during spring/summer
Factors influencing odour emission
Moisture content
� one of the most common factors leading to anaerobic conditions
� moisture < 35-40%: reduction of decomposition
� upper limit varies with different materials (function of particle sizes and structural characteristics)
� for most compost mixtures: 55-60% is recommended
Odour reduction techniques
Turning frequency
� turning releases odorous compounds trapped within piles
� lack of turning allows anaerobic conditions � increases severity of odours when piles are eventually disturbed
� Defoer & Van Langenhove (2000): research on the influence of turning frequency on odour emission at 3 greenwaste composting plants with different turning frequencies ( plant A: every 6 weeks, plant B: every week, plant C: every 8 weeks)
Odour reduction techniques
Turning frequency
RESULTS
- odour emission high and nearly the same during first 10 days
- afterwards fast decline to the same continuous odour emission
- peak emissions after every turning were lowest for plant B with the highest turning frequency
Odour reduction techniques
Turning frequency
CONCLUSIONS
- a complete odour balance could not be made
- the plant with the highest turning frequency had the lowest odour emission
- other factors (height of compost piles, turning equipment, �) could have played a role
Odour reduction techniques
Aeration
inadequate oxygenation (aeration) leads to developmentof anaerobic conditions
� active aeration has pronounced effect on both rate of composting and odour production
Influence type of aeration
research of Bidlingmaier (1993) sucking aeration: 15380 ×104 ou.h-1
blowing aeration: 3400 ×104 ou.h-1
Odour reduction techniques
Odour masking
� overpowering of the odorous molecules with stronger, more pleasant molecules
� Defoer & Van Langenhove (2000): sniffing team measurements around a greenwaste composting plant with and without odour masking products
- large variation in the results (from -5 to +73% reduction with a mean value of 17%)
- �soap� odour is also annoying- no ecologically sound reduction technique
Odour reduction techniques
Air treatment
� air from closed buildings can be removed by ventilation
� used as process air for aerating compost piles (odour reduction)
� odour removal by chemical or biological treatment
� biological treatment is the most cost-efficient technique
� in Flanders used by all VFG composting facilities
Odour reduction techniques
Air treatment
Defoer & Van Langenhove (2000): monitoring campaign ofbiofilters at 5 Flemish aerobic VFG composting plants
- 3 of the 5 biofilters: VOC removal efficiency > 94%- 1 biofilter lower efficiency of 80% due to low influent concentrations- 1 biofilter VOC removal efficiency of only 64% (reason was not clear)
Odour reduction techniques
Air treatment
Note: results were expressed in VOC removal efficiency butDefoer et al. (2002) found a good correlation between odourand VOC concentration for the effluent of biofilters at VFGcomposting plants
� biofiltration is a reliable technique for odour removal at composting facilities
Final conclusion
� considerable research on odour production has been done
� importance of factors like turning frequency and aeration are difficult to describe quantitatively
� effects of odour masking products are ambiguous
� VFG composting: biofiltration is a reliable technique for odour removal
� greenwaste composting: not in closed buildings � biofiltration not possible
� other methods like adaptation of aeration and turning frequency must offer a solution