Mo phong phan xuong Amoni Dam Phu My

7/21/2019 Mo phong phan xuong Amoni Dam Phu My

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n Cng Ngh II GVHD: PGS.TS Nguyn nh Lm

Mc LcChng 1. Gii Thiu Tng Quan................................................................................8

1.1 Phn mm HYSYS...............................................................................................8

1.2 Phn xng Ammnia........................................................................................1!1.2.1 Gii "hiu #hung..........................................................................................1!

1.2.2 Phn xng Ammnia..................................................................................1!

1.2.2.1 H$%& h' () *h+ ,u hu-nh................................................................1!

1.2.2.2 /0&ming.................................................................................................11

1.2.2. Chu$n h' C3......................................................................................... 11

1.2.2.4 56"an h'.................................................................................................12

1.2.2.7 Tng h9 ammnia...................................................................................121.2.2.:;)m ,?n 9h@m () "hu hi Ammnia.......................................12

1. Bng %ng 9hn mm H$>$> () mD 9hEng Phn Fng Ammnia...................12

Chng 2. Qu' T&nh 5D PhEng................................................................................14

2.1 CDng #I9.........................................................................................14

2.1.1.1 TiJn h)nh mD 9hEng.................................................................................17

2.1.2 /0&ming "hK #I9.......................................................................................182.1.2.1 TiJn h)nh mD 9hEng.................................................................................18

2.2 Qu' "&nh #hu$n hLa C3...................................................................................21

2.2.1 TiJn h)nh mD 9hEng.....................................................................................21

2.2.1.1 C'# %=ng () "hiJ" MN #hOnh........................................................................21

2.2.1.2 5D hnh nhi" ng................................................................................... 21

2.2.1. hR9 #'# "hiJ" MN ,i6n *J" %=ng () #)i " #'# "hDng >U............................22

2.2.1.4 VJ" Wu? () > >'nh....................................................................................22. Cm "hiJ" MN hI9 "h C32MXng %ung mDi 5ZA.............................................24

2..1 gu$6n "[#...................................................................................................24

2..2 TiJn h)nh mD 9hEng.....................................................................................24

2..2.1 C'# %=ng () "hiJ" MN #hOnh........................................................................24

2..2.2 H nhi" ng............................................................................................ 27

SVTH: Nguyn Vn Thanh L Vn H!" Ng Th# L!nh an L$": %&H'


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2..2. hR9 "hiJ" MN ,i6n *J" %=ng () #)i " #'# "hDng >U..................................2:

2.. VJ" Wu? () > >'nh.......................................................................................28

2.4 Cm 5/"han/ hLa...............................................................................................28

2.4.1 gu$6n "[#...................................................................................................28

2.4.2 TiJn h)nh mD 9hEng.....................................................................................2\

2.4.2.1 C'# %=ng () "hiJ" MN #hOnh........................................................................2\

2.4.2.2 5D hnh nhi" ng................................................................................... 2\

2.4.2. hR9 "hiJ" MN ,i6n *J" #'# %=ng () #'# "hiJ" MN #hOnh................................!

2.4. VJ" Wu? () > >'nh.......................................................................................!

2.7 Cm n]n *hO ngu$6n ,iu....................................................................................1

2.7.1 gu$6n "[#...................................................................................................12.7.2 TiJn h)nh mD 9hEng.....................................................................................1

2.7.2.1 C'# %=ng () "hiJ" MN #hOnh........................................................................1

2.7.2.2 H nhi" ng............................................................................................ 2

2.7.2. hR9 "hiJ" MN ,i6n *J" #'# %=ng #)i " #'# "hDng >U...............................2

2.: Cm "ng h9 Ammnia.....................................................................................2

2.:.1 gu$6n "[#...................................................................................................2

2.:.2 TiJn h)nh mD 9hEng.....................................................................................42.:.2.1 C'# %=ng () "hiJ" MN #hOnh........................................................................4

2.:.2.2 H nhi" ng............................................................................................ 4

2.:.2. hR9 "hiJ" MN ,i6n *J" #'# %=ng #)i " #'# "hDng >U...............................4

2.:. VJ" Wu? () > >'nh.......................................................................................:

2.^ Cm ,)m ,


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2.8.1 5# O#h......................................................................................................41

2.8.2 TiJn h)nh mD 9hEng.....................................................................................41

2.8.2.1 C'# %=ng () "hiJ" MN #hOnh........................................................................41

2.8.2.2 5D hnh nhi" ng................................................................................... 4

2.8.2. hR9 "hiJ" MN ,i6n *J" %=ng () #)i " #'# "hDng >U..................................4

2.8. VJ" Wu? () > >'nh.......................................................................................4^

Chng . VJ" Qu? _/>"u%$e.......................................................................................72

.2.7 Tn "hI" '9 >uI" Wua #'# "hiJ" MN...................................................................72

Chng 4. VJ" ;uRn...................................................................................................7



4/55


Danh mc Bng

b?ng 2.1e Th)nh 9hn %=ng f" Z2!!1..17

b?ng 2.2e Gi' "&N >ai >U #ja "h)nh 9hn CH4"h/ /,"a T1:

b?ng 2.e Gi' "&N >ai >U #ja "h)nh 9hn C3 "h/ /,"a T.1^

b?ng 2.4e S >'nh *J" Wu? %=ng fP/>> ga> " 2!!.1^

b?ng 2.7e Th)nh 9hn %=ng f9/>> ai&.18

b?ng 2.:e Gi' "&N >ai >U #ja "h)nh 9hn CH4"h/ /,"a T1\

b?ng 2.^e Gi' "&N >ai >U #ja "h)nh 9hn C3 "h/ /,"a T.1\

b?ng 2.8e S >'nh *J" Wu? %=ng fP/>> ga> " 2!!4.2!

b?ng 2.\e Gi' "&N >ai >U #ja "h)nh 9hn C3 "h/ /,"a T.22

b?ng 2.1!e Gi' "&N >ai >U #ja "h)nh 9hn C3 "h/ /,"a T22

b?ng 2.11e Th)nh 9hn %=ng f9/>> ga> " T!!2..2

b?ng 2.12e H)m ,ng C32"h/ >U ka #ja "h'9 hI9 "h.27

b?ng 2.1e VJ" Wu? %=ng fPu&i0i/% ga> " 1!Z2!11.28

b?ng 2.14e VJ" Wu? %=ng fC32" l&/a28

b?ng 2.17e Gi' "&N #hu$n hLa #ja C32() C3 "h/ /,"a T2\

b?ng 21:e Sai >U #ja %=ng fGa> " V4!1.!

b?ng 2.1^e VJ" Wu? > >'nh %=ng fP&%u#" Ammnia:

b?ng 2.18e VJ" Wu? > >'nh %=ng fGa> " T7!71..:b?ng 2.1\e ThDng >U %=ng ammnia Jn " Mnh "'#h 1!`7!!2..8

b?ng 2.2!e S >'nh *J" Wu? %=ng >?n 9h@m %n Jn 9hn xng l&/a.4!

b?ng 2.21e ThDng >U %=ng *hO 9u&g/ ga> " 1!`7!14..42

b?ng 2.22e ThDng >U %=ng (/n" ga> " 1!`7!!2..42

b?ng 2.2e ThDng >U %=ng *hO *hDng ngng " #m ,)m ,'nh =ng ammnia >au *hi # "hu hi..4^

b?ng 2.27e S >'nh %=ng >?n 9h@m >au onh "h'9 hI9 "h 1!T7!72 48b?ng 2.2:e S >'nh %=ng >?n 9h@m onh >au *hi &a *hEi "h'9 hI9 "h 1!T7!71..4\



5/55


Danh mc hnh

Hnh 1.1e Gia %in Zn(i&m/n" ba>i>...8

Hnh 1.2e Gia %in Simu,a"in Zn(i&m/n". .\

Hnh 1.e S #'# 9hn xng #hOnh #ja nh) m'$.1!

Hnh 2.1e ThiJ" MN /0&ming > #I9.14

Hnh 2.2e _ "hN *h? >'" >ai >U #ja CH4"h/ %/,"aT #ja %=ng >?n 9h@m1:

Hnh 2.e _ "hN *h? >'" >ai >U #ja C3 "h/ %/,"aT "&ng %=ng >?n [email protected]^

Hnh 2.4e ThiJ" MN /0&ming "hK #I918

Hnh 2.7e _ "hN *h? >'" >ai >U #ja CH4"h/ %/,"aT #ja %=ng >?n 9h@m 1\

Hnh 2.:e _ "hN *h? >'" >ai >U #ja C3 "h/ %/,"aT #ja %=ng >?n [email protected]!

Hnh 2.ê Cm #hu$n hLa C3..21

Hnh 2.8e _ "hN *h? >'" >ai >U #ja C3 "h/ %/,"aT #ja %=ng >?n [email protected]

Hnh 2.\e _ "hN *h? >'" >ai >U #ja C3 "h/ %/,"aT #ja %=ng >?n [email protected]

Hnh 2.1!e Cm "hiJ" MN hI9 "h C32MXng %ung mDi 5ZA..24

Hnh 2.11e _ "hN nng C32 "h/ >U ka27

Hnh 2.12e Th'9 hI9 "h C32.2:

Hnh 2.1e H "hUng Mnh "'#h2^

Hnh 2.14e Th'9 gi?i hI92^

Hnh 2.17e Cm m/"han/ hLa.!Hnh 2.1:e Cm n]n *hO ngu$6n ,iu..1

Hnh 2.1ê H "hUng m'$ n]n.2

Hnh 2.18e Cm "ng h9 ammnia2

Hnh 2.1\e ThiJ" MN "ng h9 ammnia S2!!.7

Hnh 2.2!e Cm ,)m ,d 9h "hu# #ja nng ammnia %=ng onh "h/ >U ka44

Hnh 2.2ê Gia %in #)i " "h'9 hI9 "h....44



6/55


Hnh 2.28e Th'9 hI9 "h 1!T7!72...47

Hnh 2.2\e _ "hN >d 9h "hu# #ja nng ammnia %=ng onh "h/ >U ka..47

Hnh 2.!e Gia %in #)i " "h'9 hI9 "h 1!T7!714:

Hnh 2.1e Th'9 gi?i hI9 1!T7!7..4:

Hnh 2.2e _ "hN Miu %ipn "inh *hiJ" #ja %ung mDi "h/ >U ka.4^

Hnh .1e Gia %in hng %qn #hcn mD hnh nhi" ng.71



7/55


LI M U----------

;)m "hJ n) "hiJ" *J # #'# "hiJ" MN 9h?i (Rn h)nh h "hUng &a >a #L #hiu Wu? #a nhI"r _L ,) m" M)i ")n *hL ,uDn " &a #h #'# nh) nghi6n #Ku #'# nh) *s"huR". _iu n)$ ,d "& gi9 #ja m'$ "Onh "U# #a *J" h9 (i #'# 9hn mm #hu$6n %ng nhP&vv H$>$> #)ng ,)m #h (i# mD 9hEng () "Ui u hLa "huRn ,i hn &I" nhiu.

5D hnh hLa () mD 9hEng ,) m" 9hng 9h'9 nghi6n #Ku *ha hc# # Kng %ng&I" &ng &qie " nghi6n #Ku "hiJ" *J #hJ "inh (i6n #ja ng)nh %u *hO #ja "&tng_HbV_) wng.

him ( #ja 'n n)$ ,) mD 9hEng 9hn xng Ammni #ja nh) m'$ 9/n HYSYS. `) h)n "h)nh _ 'n n)$ #hng /m xin g+i ,ti #?mn >u >[# nhI" Jn "h$ PGS.T> gu$pn _nh ;m ngti "h$ "&d# "iJ9 hng %n _'n #ja #hng /m. T&ng Wu' "&nh "hd# hin ")i "h$ q nhi" "nh gi9 #hng /m&I" nhiu ( m" ")i ,iu *iJn "hK# () *inh nghim gi9 #hng /m a &a #'# 9hng 'n() gi?i Wu$J" # #'# (In "h[# m[# "&ng Wu' "&nh ,)m _ 'n n)$

Fin #h# Wuy Th$ CD >K# *hE/ () "h)nh #Dng.



8/55


Chng 1. Gii Thi T!ng "an

1.1 #h$n m%m &'('(

HYSYS ,) >?n 9h@m #ja #Dng "$ H$9&"/#hCana%a "hu# #Dng "$ AZA T/#hn,gi/

Zngin//&ing S0"za&/H$9&"/#h ;"%. HYSYS q # mua ,+ %ng "&ng (i# "hiJ" *J "hiJ" MN %$#hu$n >?n xuI" #Dng ngh.

D,namic/ M+* #hJ mD 9hEng ng >+ %ng "&ng (i# *im "&a () "h/ %{i#'# "hDng >U #ja "hiJ" MN "&ng "&ang "h'i gi? ,R9 nh ang (Rn h)nh "hd# "J.

A>9/n HYSYS #L # > nhi" ng (ng #h[# () $ j *h? n|ng "Onh "'n ,inh hca"()"Onh "hiJ" "hd# #ja #'# h nhi" ng #h 9h]9 "Onh "'n #'# mD hnh &I" gn (i "hd#

"J #Dng ngh. HYSYS '9 Kng #'# $6u #u #Dng ngh # M?n #h mD hnh hLa () mD9hEng #'# Wu' "&nh #Dng ngh " *hai "h'# "i #hJ MiJn "&ng #'# nh) m'$ #hJ MiJn *hO#h Jn #'# Wu' "&nh ,c# hLa %u () #Dng ngh hLa hc#.

HYSYS ,) #Dng # &I" m9/n T/#h~P/>> m%/,ing

`^.2~A>9/n HYSYS. Chcn i,/~/z gia %in 9hn mm hin &a nh hnh %ie

Hnh 1.1e Gia %in Zn(i&m/n" ba>i>



9/55


Bc 0 Chcn #Iu "+ () h nhi" ng.

T&ng gia %in Simu,a"in ba>i# 5anag/& #hcn TaM Cm9n/n">~A%% >auL

#hn #Iu "+ "Onh "'n mng muUn.

Chcn TaM ,ui% P*g>~A%% #hcn h nhi" ng '9 %ng "Onh "'n.

CL "h #hcn nhiu %anh >'#h #Iu "+ () nhiu h nhi" ng "&ng #}ng m"i,/ mD 9hEng.

Bc 1 ThiJ" ,R9 #'# "hDng >U #h #'# %=ng () "hiJ" MN #Dng ngh.

_ () mDi "&tng mD 9hEng #hcn Zn"/& Simu,a"in Zn(i&nm/n" gia %in#ja P Ca>/ 5ain hin &a nh hnh M6n %i.

Hnh 1.2e Gia %in Simu,a"in Zn(i&m/n"

Bc 2 Ch


10/55


1.0 #h3n 45ng 6mmnia

1.0.1 Gi i )hi chng

h) m'$ _+ %ng ngun *hO "hi6n nhi6n " Mn "&ng am CDn Sn *hO ngh)nh mE b?n xuI" hi n#() in #ung #I9 #h Wu' "&nh (Rn h)nh #ja nh) m'$ () >inh h


11/55


H)m ,ng S "&ng *hO >au *hi *h+ ,u hu-nh 9h?i nhE hn !.!799m`

T&ng #Dng #I9 () "hK #I9(i x# "'#Qi*/n5agi6QhDm.

CnHm H23 C n1Hm2 C3 2 H2 h/a"

CH4 H23 C3 H2 h/a"

C3 H23 C32 H2 h/a"

CnHm 32 C32 H23 h/a"

a. C Dn g #I9e

VhO # &/0&ming MXng hi n# ,ng nhi" 9h?n Kng 8##ung #I9 MiWu' "&nh U" ng)i. iu *in (Rn h)nh Mnh "htng nhi" %=ng *hO#Dng ngh >au *hi &a *hEi #Dng


12/55


*hDng #=n % L #n m6"an hLa C3 C32#=n ,au *hi "'#h MXng %ung %N#h 5ZA8#a Wua "hiJ" MN m6"an h' (i x# "'#Qi*/n

C3 H2 CH4 H23 h/a"

C32 4H2 CH4 2H23 h/a"

H)m ,ng C3 C32#=n ,au *hi Wua m6"an h' 1!99m

1.0.0. T!ng hEF ammnia

VhO #Dng ngh >au *hi Wua m/"an h' # a i "ng h9 ammnia '9 >uI"1^ Ma&g nhi" :! C "&ng "hiJ" MN "ng h9 "h/ *iu hng *Onh (i x# "'#>[" #L "hiJ" MN "&a i nhi" M6n "&ng gia %=ng *hO &a () () #ja 2 "ng x# "'# nng #a hiu >uI" 9h?n Kng

H2 2 2H h/a"

Hiu >uI" "ng h9 ammnia 9u&g/ () h "hUng "hu hi h$%& " %=ng9u&g/

1.0.0. L:m =Hnh +Ing /n FhJm 9: )h hKi 6mm-nia

=ng >?n 9hIm >au *hoa *hEi "hiJ" MN 9h?n Kng # ,)m ,d #hOnh x'#. S+ %ng #Dng # mD 9hEng #h Wu' "&nh > gi9 n gi?nhLa &I" nhiu #ng nh /m ,


13/55


S+ %ng 9hn mm h$>$> (i *h % ,iu ,n $ j # Mi" ,) (i #'# #Iu "+ *hO#h 9h]9 "a mD 9hEng $ j ,) 'nh gi' ,


14/5514


Chng 0. "8 T7nh M #hNng

0.1 Cng PHn 7*@7ming

T&ng #Dng aue

1 CnHm H23 Cn 1 Hm 2 C3 2 H2

2 CH4 H23 C3 H2

C3 H23 C32 H2

Ph?n Kng 1 %ipn "? 9h?n Kng &/0&ming h$%a#Mn #a "h)nh h$%a#Mn "hI9 hn

() #uUi #}ng ,) &/0&ming m/"an 2. Ph?n Kng M[" u nhi" 7!!C Ui (i #'# h$%&

#a#Mn MR# #a () :!!C Ui (i m/"an.

Ph?n Kng #ho >inh &a m" ,ng nhE nhi" ( (R$ #n m" ,ng nhi" ,n #h 9h?n

Kng 1 2.

Ph?n Kng &/0&ming x?$ &a "&ng 2 #Dng #I9 ,ng nhi" #n #h 9h?n Kng #

,I$ gi'n "iJ9 " Wu' "&nh U" #h'$. T&ng "hiJ" MN &/0&m/& "hK #I9 ,ng nhi" # #ung

#I9 " Wu' "&nh U" m" 9hn ,ng *hO (i *hDng *hO.

;ng nhi" " Wu' "&nh U" n)$ #ung #I9 #h 9h?n Kng &/0&ming ,ng h$%a#Mn

#=n ,au *hi &a *hEi "hiJ" MN "hK #I9 #L " , H2e2,) e1

0.1.1 ?*@7ming / cQF

Hnh 2.1e ThiJ" MN /0&ming > #I9



15/5517


0.1.1.1 TiRn h:nh m FhNng

a. C'# %=ng () "hiJ" MN #hOnh ThiJ" MNe

ThiJ" MN gia nhi" Z2!!1

ThiJ" MN &/0&m/& > #I9 H2!!1 =ng () f" Z2!!1 (i #'# "hDng >Ueb?ng 2.1e Th)nh 9hn %=ng f" Z2!!1

CIu "+;u ,ng m~h

141744

H2 124

2 724

C32 ^4A& :

CH4 2:241

C2H: 4787

CH8 7!

nC4H1! 4

iC4H1! 4

nC7H12 \

H23 1!821!

9 >uI" Ma&g 7.2

hi" C 7!

=ng &a f9/>> ga> " 2!!M. 5D hnh nhi" ng

Chcn h nhi" ng P/ngMin>n ( #'# #Iu "+ $ #hj $Ju ,) #'#h$%a#Mn nh C3 C3 2() n#.

#. hR9 "hiJ" MN ,i6n *J" %=ng () #)i " #'# "hDng >U#.1 ThiJ" MN gia nhi" Z2!!1

ChcnP !.4Ma&

hi" %=ng &a f" H2!!1 77C

#.2 ThiJ" MN &/0&m/& > #I9



16/551:


C)i " Wuan "&cng nhI" Ui (i "hiJ" MN n)$ L ,) 9h?n Kng hLa hc# x?$&a () T a99&a#h #ja "ng 9h?n Kng.

Ph?n Kng &/0&ming #'# h$%a#Mn MR# #a "h)nh #'# h$%a#Mn MR#"hI9e

C7H12 H23 C4H1! C3 2H2

C4H1! H23 CH8 C3 2H2

CH8 H23 C2H: C3 2H2

C2H: H23 CH4 C3 2H2

4 2 2CH H ( C( H + +C'# 9h?n Kng x?$ &a h)n ")n T a99&a#h

#ja #'# 9h?n Kng MXng ! Ph?n Kng &/0&ming m/"han/e

CH4 8.^8b?ng 2.2e Gi' "&N >ai >U #ja "h)nh 9hn CH4"h/ /,"a T

/,"a T ! 1 2 4 7 : ^ 8 \

CH4 Sim

8.41: 8.4^2 8.728 8.78 8.:\ 8.:\7 8.^71

8.8!

8 8.8:4

8.\2

! 8.\

!.!^ !.!! !.!24 !.!18 !.!11 !.!!7 !.!!2!.!!

8 !.!14!.!2

1 !.!

0 2 4 6 8 10 12

0.000

0.010

0.020

0.030

0.040

f(x) = 0.02 x^-0.38R = 0.09

4

e Logarithmic (e) Power (e) Power (e)

Sai s



17/551^


Hnh 2.2e _ "hN *h? >'" >ai >U #ja CH 4 "h/T #ja %=ng >?n 9h@m T 7.: C

2 2 2C( H ( C( H + +

Ph?n Kng #hu$n hLa C3e

C3P 7.2^

b?ng 2.e Gi' "&N >ai >U #ja "h)nh 9hn C3 "h/ /,"a T

T ! 1 2 4 7 : ^ 8 \C3Sim 7.1\1 7.2!! 7.2!8 7.21: 7.227 7.2 7.241 7.27! 7.278 7.2:: 7

!.!!7 !.!!4 !.!! !.!!2 !.!!1 !.!!! !.!!! !.!!1 !.!!2 !.!! !

0 2 4 8 !0 !2

0.000

0.002

0.004

0.006

DT - e CO

Sai s

Hnh 2.e _ "hN *h? >'" >ai >U #ja C3 "h/ T "&ng %=ng >?n 9h@m

T 4.:C%. VJ" Wu? () > >'nh

b?ng 2.4e S >'nh *J" Wu? %=ng fP/>> ga> " 2!!

T6n %=ngP/>> ga> " 2!!

P 5D9hEng

;u ,ng m~h 18888 188^:

H2 ^!74\ ^!71

2 724 724

C3 \:! \:1

C32 11:1: 11:!\



18/5518


A& : :

CH4 1:!:8 1:!:8

H23 ^74\7 ^77!^

Hu hJ" #'# >U ,iu mD 9hEng gn >'" (i "hd# "J ( (R$ "a #L "h #hI9 nhRn *J"Wu? mD 9hEng n)$

0.1.0 ?*@7ming )hS cQF

Hnh 2.4e ThiJ" MN /0&ming "hK #I9

0.1.0.1 TiRn h:nh m FhNng

a. C'# %=ng () "hiJ" MN #hOnh ThiJ" MNe

ThiJ" MN &/0&m/& "hK #I9 2!! ThiJ" MN gia nhi" H2!!8 ThiJ" MN gia nhi" H2!!\

=ng () f9/>> ga> " 2!! (i #'# "hDng >Ue M?ng 2.4 =ng () f9/>> ai& (i #'# "hDng >Ue

b?ng 2.7e Th)nh 9hn %=ng f9/>> ai&

CIu "+;u ,ng m~h

772^

32 1114^

2 4144:

C32 1:

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H23 41\

9 >uI" 2.\



19/551\


hi" 77!

=ng &a f9/>> ga> " 2!!4

M. 5D hnh nhi" ng

Chcn h nhi" ng P/ngMin>n ( #'# #Iu "+ $ #hj $Ju ,) #'#h$%a#Mn nh () n#.

#. hR9 "hiJ" MN ,i6n *J" %=ng () #)i " #'# "hDng >U#.1 ThiJ" MN &/0&m/& "hK #I9 Tng "d (i "hiJ" MN &/0&m/& > #I9 #)i " Wuan "&cng nhI" Ui (i "hiJ" MN

n)$ L ,) 9h?n Kng hLa hc# x?$ &a () T a99&a#h #ja "ng 9h?n Kng. Ph?n Kng &/0&ming m/"han/e

CH4P !.4!\

b?ng 2.:e Gi' "&N >ai >U #ja "h)nh 9hn CH4"h/ /,"a T

T ! 1 2 4 7

CH4 Sim !.\4 !.4!! !.4!^ !.41 !.42! !.42:

!.!^ !.!21 !.!!: !.!1! !.!2: !.!42

0 1 2 3 4 5 6

0.000

0.020

0.040

0.060

4

Sai s

Hnh 2.7e _ "hN *h? >'" >ai >U #ja CH4"h/T #ja %=ng >?n 9h@m

T 2.4

C

4 2 2CH ( C( H (+ +

Ph?n Kng #hu$n hLa CH4"h)nh C3T !

Ph?n Kng #hu$n hLa C3 "h)nh C32e C3 1~232C32C3 P \. !4

b?ng 2.^e Gi' "&N >ai >U #ja "h)nh 9hn C3 "h/ /,"a T



20/552!


T ! !.2 !.4 !.: !.8 1C3>im \.!:^ \.!77 \.!42 \.!! \.!18 \.!!7

/ !.!!4 !.!!2 !.!!1 !.!!! !.!!2 !.!!

-1.2 -1 -0.8 -0.6 -0.4 -0.2 0

0.000

0.001

0.002

0.003

0.004

Sai s

Hnh 2.:e _ "hN *h? >'" >ai >U #ja C3 "h/T #ja %=ng >?n 9h@m T !.:C

%. VJ" Wu? () > >'nh

b?ng 2.8e S >'nh *J" Wu? %=ng fP/>> ga> " 2!!4

T6n %=ngP/>> ga> " 2!!4

P 5D 9hEng

;u ,ng m~h 27:!^ 27:2\2

H2 \48!: \48!1

2 41\^! 41\^!

C3 217: 214

C32 112: 112

A& 7!7 7!7

CH4 1!48 1!47

H23 81:\: 81:\

Hu hJ" #'# >U ,iu mD 9hEng gn >'" (i "hd# "J ( (R$ "a #L "h #hI9 nhRn *J"Wu? mD 9hEng n)$



21/5521


0.0 "8 )7nh ch,An ha C

Hnh 2.^e Cm #hu$n hLa C3

C3 "&ng *hO #Dng ngh &a *hEi &/0&ming # #hu$n h' "h)nh C32() H2"&ng"hiJ" MN #hu$n h' C3 2!!4~2!!7

C3 H23 C32 H2

Cn MXng 9h?n Kng %N#h #hu$n "h/ #hiu #hu$n h' C3 #a hn nhi" "hI9 ()hi n# nhiu hn "u$ nhi6n " , 9h?n Kng "|ng *hi nhi" "|ng. hi" "Ui u #h9h?n Kng #hu$n h' 9h "hu# () h


22/5522


0.0.1. YhZ F c8c )hiR) V[ =in ;R) +ng 9: c:i P\) c8c )hng /]

a.2 2 2C( H ( C( H + +

ThiJ" MN 9h?n Kng 2!!4 Ph?n Kng x?$ &a "&ng "hiJ" MN 2!!4e

C)i " Wuan "&cng nhI" #h "hiJ" MN n)$ ,) T a99&a#h 9hn mm #L "h "Onh "'nhiu >uI" #hu$n hLa #ja 9h?n Kng >'" (i M)i #h.C3 P 2.412

b?ng 2.\e Gi' "&N >ai >U #ja "h)nh 9hn C3 "h/ /,"a T

T ! 2 4 : 8 1! 12 14C3 >im 2.241 2.2^2 2.!4 2.7 2.:^ 2.\\ 2.41 2.4:

!.!^1 !.!78 !.!47 !.!2 !.!18 !.!!7 !.!!8 !.!21

0 2 4 6 8 10 12 14 16

0.000

0.020

0.040

0.060

0.080

1)

Sai s

Hnh 2.8e _ "hN *h? >'" >ai >U #ja C3 "h/ T #ja %=ng >?n 9h@m /,"a T 1!.8C

M. ThiJ" MN 9h?n Kng 2!!7 Ph?n Kng x?$ &a "&ng "hiJ" MN 2!!7 C)i " Wuan "&cng nhI" #h "hiJ" MN n)$ ,) T a99&a#h 9hn mm #L

"h "Onh "'n hiu >uI" #hu$n hLa #ja 9h?n Kng >'" (i M)i q #hC3 P !.1^^b?ng 2.1!e Gi' "&N >ai >U #ja "h)nh 9hn C3 "h/ /,"a T

T ! 2 4 : 8 1!C3 >im !.17: !.1:2 !.1:8 !.1^7 !.182 !.18\

!.12! !.!84 !.!48 !.!11 !.!28 !.!:8



23/552


0 2 4 6 8 10 12

0.000

0.050

0.100

0.150

2)

Sai s

Hnh 2.\e _ "hN *h? >'" >ai >U #ja C3 "h/T #ja %=ng >?n 9h@m /,"a T :.:C

0.0.1.2 ^R) _ 9: / /8nh

b?ng 2.11e Th)nh 9hn %=ng f9/>> ga> " T!!2

T6n %=ngP/>> ga> " T!!2

P 5D 9hEng

;u ,ng m~h 27:!^ 27:2\4

H2 11^7!\ 11^4\22 41\^! 41\^!

C3 47 47

C32 782\ 782

A& 7!7 7!7

CH4 1!48 1!47

H23 78\\ 7\!!

Hu hJ" #'# >U ,iu mD 9hEng gn >'" (i "hd# "J ( (R$ "a #L "h >+%ng *J" Wu? mD 9hEng n)$



24/5524


0. Cm )hiR) V h Q F ) h C 0 n g + n g mi M D 6 .

Hnh 2.1!e Cm "hiJ" MN hI9 "h C32MXng %ung mDi 5ZA.

0..1 Yg,n )bc.

H "hUng "'#h C32# %da "&6n Wu' "&nh 5ZA h


25/5527


ThiJ" MN "'#h ,a>h.

=ng #Dng ngh #hOnh.

=ng *hO i &a " "hiJ" MN #hu$n hLa C3 nhi" "hI9

=ng *hO #Dng ngh >au *hi q # hI9 "h C32. =ng *hO C32 i &a " Mnh "'#h.

ThDng >U u () #ja Wu' "&nh.

=ng *hO #Dng ngh #hOnh i () #L "hDng >U " *J" Wua mD 9hEng #ja#m "hiJ" MN " Le M?ng 2.2.

=ng Amin/ "un h)n 4! *hUi ,ng 5ZA.

ThDng >U #n *h? >'" ,) >U ka #ja "h'9 hI9 "h. ThDng >U n)$ > # #hcn

MXng #'#h "ha$ i >U ka () 'nh gi' >ai >U #ja %=ng >?n 9h@m #Iu "+ #hcn "Onh >ai >U ,) C32 "&ng %=ng *hO q # ,)m >


26/552:


29 30 3! 32 33 34 3" 3 3#0

200

400

00

800

!000

!200

!400

!00

!800

2000

Nng CO2 theo S a

$%&g ' * theo +, 'a

s a

CO2 ppm

Hnh 2.11e _ "hN nng C32 "h/ >U ka

` h)m ,ng "i6u #hu@n #ja C32 "&ng %=ng *hO >n mD 9hEng #'# %=ng () "hiJ" MN 9h #=n mD hnh Amin/ %}ng mD 9hEng "hiJ" MN hI9"h MXng 5ZA () "hiJ" MN "'i >inh Amin/.

0..0. YhZF )hiR) V[ =in ;R) +ng 9: c:i P\) c8c )hng /]

a. Th'9 hI9 "h C32



27/552^


Hnh 2.12e Th'9 hI9 "h C32 T&ng "h'9 hI9 "h C32 1!T!!2 C32# "'#h &a *hEi %=ng *hO MXng hI9 "h

ng# %=ng "&ng hai #I9. T&ng 9hn %i #ja "h'9 hI9 "h %ung %N#h M'n "hun

"'i >inh # %}ng hI9 "h 9hn ,n C32. T&ng 9hn "&6n #ja "h'9 n)$ %ung%N#h "hun "'i >inh # %}ng "'#h C32#=n ,


28/5528


C32"h'" &a *hEi Mnh "'#h "hI9 '9 #hKa $ hi n# Mq h) " >'nh #ja %=ng *hO #Dng ngh >au *hi q # hI9 "h C3 2fPu&i0i/% ga> "1!Z2!11

b?ng 2.1e VJ" Wu? %=ng fPu&i0i/% ga> " 1!Z2!11

CU Td Me #&fYG #D (6I ( jkH2 m~h 11:444 11^1!1 !.7:

2 m~h 41888 4188\ !.!!



29/552\


C3 m~h 448 472 !.88

C32 m~h 8 81 2.4^

CH4 m~h 121 1!44 1:.1\

H23 m~h ^:! ^!8 ^.4

5ZA m~h ! ! !.!!

SU ,iu > >'nh #ja %=ng C32 >au *hi q # "'#h &a fC32" l&/a

b?ng 2.14e VJ" Wu? %=ng fC32" l&/a

CU Td Me #&fYG #D (6I (H2 m~h : 47 2 m~h 7 ^ C3 m~h ! ! C32 m~h 771 7!14 1.4CH4 m~h ! ! H23 m~h 7!2\ !^

5ZA m~h ! !

da () M?ng >U ,iu > >'nh #ja hai %=ng #hOnh #ja #m "hiJ" MN "a "hI$ 9hn ,n #'#>U ,iu mD 9hEng gn (i >U ,iu "hd# "J (R$ *J" Wu? mD 9hEng ,) #hI9 nhRn #.

0.2 Cm M*)han* ha

0.2.1 Yg,n )bc

CDng


30/55!


C'# %=ng #Dng ngh #hOnh.

=ng *hO #Dng ngh Jn " #m "hiJ" MN hI9 "h C32.

=ng *hO #Dng ngh >au *hi q 5/"an hLa.

ThDng >U u () #ja Wu' "&nh. =ng *hO #Dng ngh #L "hDng >U u () nh *J" Wu? mD 9hEng #ja #m "hiJ" MNhI9 "h C32e M?ng 2.1

ThiJ" MN 5/"an hLa ,) "hiJ" MN 9h?n Kng ,'" $ ,)>d ?nh hng #ja /,"a T nhi" Jn #hu$n hLa "hiJ" MN 9h?n Kng " L #L"h x'# Nnh "hDng >U ,)m (i6# #ja "hiJ" MN.

i $ ,) "hN "h hin >d ?nh hng #ja /,"a T Jn #hu$n hLa #Iu "+ #hcn "Onh ,) C3 () C32.

b?ng 2.17e Gi' "&N #hu$n hLa #ja C32() C3 "h/ /,"a T

/,"a T !C ! 1! 2! ! 4!

C32 Cn(/&>in 1!! 1!! 1!! 1!! 1!!

C3 Cn(/&>in 1!! 1!! 1!! 1!! 1!!

T M?ng >U ,iu #hcn /,"a T ,) !C.

0.2.0.0 M hnh nhi) PXng

Chcn h nhi" ng P/ngMin>n mD 9hEng #m "hiJ" MN n)$.



31/551


0.2.0. YhZF )hiR) V[ =in ;R) c8c +ng 9: c8c )hiR) V chWnh

Hnh 2.17e Cm m/"han/ hLa

VhO #Dng ngh " "h'9 hI9 "h C32 1!T!!2 # gia nhi" Jn nhi" !! 3C *hi#hng i Wua M "&a i nhi" *hO*hO 1!Z!11 () M #n MXng nhi" 1!Z2!11. b"&a i nhi" *hO*hO 1!Z!11 ,)m , " V4!1 b?ng 21:e Sai >U #ja %=ng fGa> " V4!1

CU Td Me #&fYG #D (6I ( jk

H2 m~h 114^:\ 11742 !.7^

2 m~h 41888 4188\ !.!!

C3 m~h ! ! !

C32 m~h ! ! !

A& m~h ! 7!7

CH4 m~h 1^44 17^:

H23 m~h :!! 71



32/552


T M?ng >U ,iu "a "hI$ *J" Wu? mD 9hEng &I" gn (i "hd# "J. `R$ *J" Wu? mD 9hEng ,)#hI9 nhRn #.

0. Cm nln ;hW ng,n =i

Hnh 2.1:e Cm n]n *hO ngu$6n ,iu

0..1 Yg,n )bc

_ n]n *hO ngu$6n ,iu >au *hi q "iJn h)nh m/"han/ hLa " '9 >uI" Man u ,) 24.7Ma&g Jn 12 Ma&g >+ %ng h "hUng n]n #I9e #I9 1 " 24.7 Ma&g Jn 42 Ma&g #I9 2 "

42 Ma&g Jn ::.1 Ma&g #I9 " ::.1 Ma&g ,6n 12 Ma&g.

mi #I9 n]n >au *hi &a *hEi m'$ n]n *hO > # ,)m ,au *hi q # 5/"han/ hLa e M?ng 2.4.2



33/55


=ng H2"hu hi.

=ng *hO ngu$6n ,iu >au *hi # n]n.

0..0.0 & nhi) PXng


0..0. YhZF )hiR) V[ =in ;R) c8c +ng[ c:i P\) c8c )hng /]

mUi #I9 n]n Ma gm 1 m'$ n]n 1 "hiJ" MN ,)m ,


34/554


_$ ,) 9h?n Kng "huRn nghN#h () #ho m" 9hn h$%& () ni" # #hu$n h' "h)nhamDni[# *hi *hO "ng h9 i Wua ,9 x# "'#. T&ng 1!7!!1 *h?ng 27 ni" ()h$%& # #hu$n h' "h)nh amDni[#. Phn *hDng #hu$n h' # #=n , # "'i"un h)n Jn "h'9 "ng h9 >au m" Wu' "&nh "'#h amDni[# "h)nh 9h@m %i % ,) "&ng *h?ng " :!487C Ui (i ,9 x# "'# "hKnhI" () ^!447C Ui (i ,9 x# "'# "hK hai "&ng Mnh 1!7!!1.

Sau *hi *hO "ng h9 i Wua 1!7!!1 *hO i &a # ,)m ,


35/557


," #,% /x#hang/& () #uUi #}ng Wua M "&a i nhi" nLng h" h/a"/x#hang/& Jn "h'9 "ng h9 amDni[# nht m'$ n]n "un h)n ,) m" 9hn #ja m'$ n]n*hO "ng h9 1!V4!1.

0..0 TiRn h:nh m FhNng

0..0.1 C8c +ng 9: )hiR) V chWnh

ThiJ" MN #hOnh. Th'9 "ng h9 ammnia 1!7!!1. C'# "hiJ" MN "&a i nhi". C'# "hiJ" MN "'#h.

=ng #Dng ngh #hOnh. =ng *hO ngu$6n ,iu " h "hUng n]n. =ng *hO "ng h9 &a *hEi "hiJ" MN 9h?n Kng. =ng ammnia >?n 9h@m.

=ng *hO i Wua #m "hu hi ammnia. ThDng >U u () #ja Wu' "&nh.

=ng *hO ngu$6n ,iu i &a *hEi #m n]n *hO #L "hDng >U " Wu' "&nh mD 9hEng" L.

0..0.0 & nhi) PXng


0..0. YhZF )hiR) V[ =in ;R) c8c +ng[ c:i P\) c8c )hng /]

a. Th'9 "ng h9 ammnia 1!7!!1.



36/55:


Hnh 2.1\e ThiJ" MN "ng h9 ammnia S2!!

ThiJ" MN "ng h9 ammnia 1!7!!1 ,) "hiJ" MN *iu S2!! %=ng hng *Onh (i %=ng*hO Wua #'# "ng x# "'# "h/ hng hng *Onh. 1!7!!1 #hKa !2 "ng x# "'# () !1"hiJ" MN "&a %i nhi" M6n "&ng.

Hu hJ" ,ung *hO "ng h9 "un h)n a () "hiJ" MN "ng h9 Wua 2 tng () #hOnh

" ,)m ngui (E #hNu '9 % L nhi" "hiJ" *J #ja (E #hNu'9 gi?m %'ng *.

T


37/55^


u "i6n # iu #honh MXng %=ng #,% >h" %=ng n)$ ,)m ngui %=ng *hO "ng h9 a() Wua Ung "&ung "m.

VhO &ti *hEi "ng x# "'# %u "i6n # ,)m ngui MXng #'#h i ng)i Ung "hiJ" MN "&ai nhi" M6n "&ng " *hi Jn "ng "hK 2.

Sau *hi Wua "ng "hK 2 %=ng *hO &ti *hEi "hiJ" MN #hu$n h' i Wua ni hi nhi" "ha1!Z7!!1 "?n xuI" hi nu#.

0.. ^R) _ 9: / /8nh

SU ,iu > >'nh %=ng Ammnia >?n 9h@m fP&%u#" Ammniab?ng 2.1^e VJ" Wu? > >'nh %=ng fP&%u#" Ammnia

CU Td Me #&fYG #D (6I (jkH2 m~h 7:8 247

2 m~h 12^ 11^

A& m~h ^ 27CH4 m~h 47! 1!

H m~h ^\!7 ^1^\ !.\\

SU ,iu > >'nh %=ng *hO Wua #m "hu hi Ammnia fGa> " T7!71.

b?ng 2.18e VJ" Wu? > >'nh %=ng fGa> " T7!71

CU Td Me #&fYG #D (6I (jk

H2 m~h 1174 117\ 0.042 m~h 44\8 487 2."8A& m~h ^! 7:8 CH4 m~h 18 17:1 !!.40

H m~h \8 871 !"."!



38/558


0. Cm =:m =Hnh 6mmnia

Hnh 2.2!e Cm ,)m ,


39/55\


"&nh >Di () Ma$ hi. T Jn *hu (d# "hu hi ammnia

=ng ammnia Jn M #hKa

0..0.0 M hnh nhi) PXng

Chcn h nhi" ng Su& P ( h n)$ #L >d "ng "'# #ja H() H23



40/554!



a. bnh "'#h 1!`7!! () m'$ n]n 1! V4!71

Hnh 2.22e bnh "'#h () m'$ n]n

Phn uI" 1.8 Ma&g ,6n 1:.: Ma&g ngti "a %}ng h "hUng m'$ n]n

(i hai #I9 n]ne " 1.8 Ma&g ,6n ^ Ma&g #I9 n]n 1 "O >U n]n .\ () " ^ Ma&g ,6n1:.: Ma&g #I9 n]n 2 "o >U n]n 2.4.

TiJn h)nh mD 9hEng "a "hiJ" ,R9 > %=ng nh hnh %i () nhR9 #'# "hDng >U '9>uI" ,)m (i# #ja m'$ n]n.

Ta MU "&O #'# in"/,/& 1!Z4!41 () 1!Z7!71 #'# Mnh "'#h ,Eng ngng " 1!`7!!^ () 1!`7!!8 M? ( m'$ n]n.


ThiJ" MN "'#h 1! 7!! " '#h ammnia Ma$ hi '9 >uI" !.!7 Ma&g " C. =ng h i # % n Jn

m'$ n]n 1!V4!71. TuI" ^Ma&g () # ,)m ,


41/5541


Hnh 2.2e Cm m'$ n]n

Sau L ammnia # ngng " "&ng "h iJ " MN ,) m ,< nh 1!Z7!1!A~b MXngn# ,)m m'" () # gm , # %n Jn #m "hu hi ammnia

0.. ^R) _ 9: / /8nh

=ng >?n 9h@m %n Jn 9hn xng l&/a

b?ng 2.2!e S >'nh *J" Wu? %=ng >?n 9h@m %n Jn 9hn xng l&/a

ThDng >U P 5D 9hEng Sai >U,z m~h :82\7 ^!42.:7 .12

Hm~h :81:4 ^!2:^ .!\H m, \\.81 \\.^8 !.!

T C 24 24 !.4!P ba&g 27 24.: 1.:!



42/5542


0. Cm )h hKi 6mmnia

Hnh 2.24e Cm "hu hi ammnia

0..1 Mc PWch

5# O#h #ja #m "hiJ" MN n)$ ,) "hu hi Ammnia# "&ng %=ng *hO i &a " (=ng"ng h9 Ammnia# () nhiu %=ng *hO x?. L "hu hi %=ng Ammnia# a ( #m"hiJ" MN ,)m ,?n 9h@m Ammnia# *h? n|ng "hu hi Ammnia#"&ng %=ng ,Eng ,6n "i \\.

=ng *hO >au *hi # &+a "'#h ammnia # "hu hi 9hn H2 "& ( "hiJ" MN 9h?nKng H2!!1. =ng *hO #L #hKa CH4# %n ( ,= U" nh m" %=ng nhi6n ,iu.

}ng %=ng %ung mDi ,) n# >U #ja %=ng M?ng >au.



43/554


b?ng 2.21e ThDng >U %=ng *hO 9u&g/ ga> " 1!`7!14

T& " 1! 7!!2. ThDng >U #ja %=ng M?ng >au.

b?ng 2.22e ThDng >U %=ng (/n" ga> " 1! 7!!2

T&au.

b?ng 2.2e ThDng >U %=ng *hO *hDng ngng " #m ,)m ,


44/5544


C'# %=ng 9h "& "hd# hin Wu' "&nh "&a i nhi".

=ng &ae

=ng Ammnia# q # "hu hi.

=ng *hO x?.

=ng H$%& "hu hi.

0..0.0 M hnh nhi) PXng

Chcn h nhi" ng Su& P ( h n)$ #L >d "ng "'# #ja H() H23.


a. Th'9 hI9 "h 1!T7!71

Y6u #ue %=ng *hO >au *hi &+a %=ng T 1!PV7!!1 *hDng #=n "h)nh

9hn H

Hnh 2.27e Th'9 hI9 "h 1!T7!71

bin ,uRn >U ka ,O "hu$J" #ja "h'9e Ta %}ng 9hng 9h'9 "h+ () >ai >U ka ,O

"hu$J" ,) >U ka nhE nhI" m) (@n ?m M? #hI" ,ng "'#h. da () >U ,iu mD9hEng "a #L "hN >d 9h "hu# #ja h)m ,ng H#ja %=ng onh "h/ >U ka nh

>aue



45/5547


0 ! 2 3 4 " #0

0

0

0

0

0.0!

0.0!

0.0!

(o Fh )hXc cpa nKng PX ammnia +ng Pqnh )h* /] Pra

&%&g ' amo&ia

tray number

mol frac

Hnh 2.2:e _ "hN >d 9h "hu# #ja nng ammnia %=ng onh "h/ >U ka

T "hN "a #hcn n 4. `R$ >U ka ,O "hu$J" #ja "h'9 "h ,) 4 ka.

ThiJ" ,R9 #'# "hDng >U #ja "h'9 hI9 "h 1!T7!71 nh >aue



46/554:


Hnh 2.2^e Gia %in #)i " "h'9 hI9 "h

M. Th'9 hI9 "h 1!T7!72

Hnh 2.28e Th'9 hI9 "h 1!T7!72 T&nh "d "hd# hin #ng nh (i "h'9 hI9 "h 1!T7!71 nhng $ (i $6u #u

,ng ammnia "&ng %=ng >?n 9h@m onh ,) 2!!99m.

2 3 4 " 0

0

0

0

0

0.0!

0.0!

0.0!

0.0!

(o Fh )hXc cpa nKng PX ammnia +ng Pqnh )h* /] Pra

&%&g ' amo&ia

tray number

mole frac

Hnh 2.2\e _ "hN >d 9h "hu# #ja nng ammnia %=ng onh "h/ >U ka



47/554^


T "hN () $6u #u "'#h "a #ng #L n4.

ThiJ" ,R9 #'# "hDng >U #ja "h'9 hI9 "h 1!T7!71 nh >aue

Hnh 2.!e Gia %in #)i " "h'9 hI9 "h 1!T7!71

#. Th'9 gi?i hI9 1!T7!7

Hnh 2.1e Th'9 gi?i hI9 1!T7!7

ung %N#h gi)u &a *hEi 1!T7!72 a Jn 1!Z7!71 Mi Mm 1!P7!72. S?n9h@m" 1!Z7!71 # "&n (i %ung %N#h gi)u " 1!T7!71 () # gia nhi" ,6n JnSVTH: Nguyn Vn Thanh L Vn H!" Ng Th# L!nh an L$": %&H'


48/5548


1:C " *hi Jn "hiJ" MN #hng #I" 1!T7!D

Qu' "&nh gi?i hI9 # "hd# hi6n nht (i# gia nhi" MXng %=ng hi #a '9 " 9x 9h"& ammnia > Ma$ hi () # "'#h &a.

_ "Onh >U ka ,O "hu$J" #ja "h'9 #hng #I" "a #ng %}ng 9hng 9h'9 "h+ () >ai iu

*in $ ,) "inh *hiJ" #ja %ung mDi >au *hi gi?i hI9. _ ?m M? Wu' "&nh #ja "h'9hI9 "h $6u #u %ung mDi 9h?i "inh *hiJ" \\\ m H23

Ta #L "hN >aue

2 2." 3 3." 4 4." " "." ."0.9"

0.9

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TvI LIwU T&6M ^&x

1. S "a$ (Rn h)nh nh) m'$ _

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