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UNIT 2: STRUCTURE OF ATOM
Atom was earlier considered the most fundamental and indivisible unit of matter. Daltons
Atomic Theory considered atom as the most fundamental unit of matter and thus believed it
to be indivisible. But further on Sub atomic particles were discovered like electron, protons,
neutrons, etc.
Electrons were discovered in the Cathode Ray tube experiment. Adding to this J.J
Thompson found out the charge to mass ratio of an electron. R.A Millikan found out the
value of charge on an electron with his oil drop experiment, and using the ratio of J.J
Thompson was able to find out the mass too. A simple modification of the cathode ray tubes
lead to the discovery of canal rays, particles carrying positive charge, thus, protons were
discovered. Eventually, due to the aspect of stabilizing the atom neutrons were discovered by
Chadwick. Neutrons have a mass slightly higher than the protons and have no charge.
8/12/2019 dsfgdsf
2/12
Now, since so many particles came up, thus there was a need to
visualize how these particles were arranged in an atom, thus
experimentalists started making atomic models, many came up with
distinct ideas but had to face serious limitations and drawbacks. Lord
Rutherford came up with an idea of the model like the solar system,
and his model was also called the solar system model. To put
limitations to his model James Clark Maxwell had already developed a
theory known as the electromagnetic theory of Maxwell.
Thus such models, though not perfect still helped the early
scientists to work on their own model in a more comprehensive way,
and also lead to the development of the Bohr model of atom, the twodevelopments which played an important role in the formulation of
Bohrs model were:
1. Dual character of electromagnetic radiation, which means radiation
has both wave and particle nature.
2. Experiments on atomic spectra, and the quantization of energy
levels.
Sir James Clark Maxwell gave the theory on wave nature of
electromagnetic radiation; by this he was able to explain the
phenomenon of charged particles on macroscopic level. He explained
that if a charge particle is accelerated then it emits electromagnetic
radiation, which is in fact a form of energy. Maxwell also proved that
light itself is an electromagnetic wave. Many phenomenon likediffraction, interference etc. could be explained by Maxwells theory,
but certain phenomenon seem to deviate from Maxwells
electromagnetic theory. Some of those phenomenon are:
1. Nature of emission of radiation: Black Body radiation.
8/12/2019 dsfgdsf
3/12
2. Ejection of electrons when radiation strikes the metal: The
Photoelectric effect.
3. Variation of heat capacity of solids as a function of temperature.
4. Line Spectra of atoms, with special reference to hydrogen.
Thus, to overcome this problem a theory was put forward by Max
Plank, the main and basic idea of his theory was that atoms and
molecules could emit or absorb energy(light) only in discrete
amounts and not in a continuous manner, thus to the smallest
quantity of energy Plank gave the name Quantum.
UNIT 2: STRUCTURE OF ATOM
Atom was earlier considered the most fundamental and indivisible
unit of matter. Daltons Atomic Theory considered atom as the most
fundamental unit of matter and thus believed it to be indivisible. But
further on Sub atomic particles were discovered like electron,
protons, neutrons, etc.
8/12/2019 dsfgdsf
4/12
Electrons were discovered in the Cathode Ray tube experiment.
Adding to this J.J Thompson found out the charge to mass ratio of an
electron. R.A Millikan found out the value of charge on an electron
with his oil drop experiment, and using the ratio of J.J Thompson was
able to find out the mass too. A simple modification of the cathode ray
tubes lead to the discovery of canal rays, particles carrying positive
charge, thus, protons were discovered. Eventually, due to the aspect of
stabilizing the atom neutrons were discovered by Chadwick. Neutrons
have a mass slightly higher than the protons and have no charge.
Now, since so many particles came up, thus there was a need to
visualize how these particles were arranged in an atom, thusexperimentalists started making atomic models, many came up with
distinct ideas but had to face serious limitations and drawbacks. Lord
Rutherford came up with an idea of the model like the solar system,
and his model was also called the solar system model. To put
limitations to his model James Clark Maxwell had already developed a
theory known as the electromagnetic theory of Maxwell.
Thus such models, though not perfect still helped the early
scientists to work on their own model in a more comprehensive way,
and also lead to the development of the Bohr model of atom, the two
developments which played an important role in the formulation of
Bohrs model were:
1. Dual character of electromagnetic radiation, which means radiation
has both wave and particle nature.
2. Experiments on atomic spectra, and the quantization of energy
levels.
8/12/2019 dsfgdsf
5/12
Sir James Clark Maxwell gave the theory on wave nature of
electromagnetic radiation; by this he was able to explain the
phenomenon of charged particles on macroscopic level. He explained
that if a charge particle is accelerated then it emits electromagnetic
radiation, which is in fact a form of energy. Maxwell also proved that
light itself is an electromagnetic wave. Many phenomenon like
diffraction, interference etc. could be explained by Maxwells theory,
but certain phenomenon seem to deexperimentalists started making
atomic models, many came up with distinct ideas but had to face
serious limitations and drawbacks. Lord Rutherford came up with an
idea of the model like the solar system, and his model was also called
the solar system model. To put limitations to his model James Clark
Maxwell had already developed a theory known as the
electromagnetic theory of Maxwell.
Thus such models, though not perfect still helped the early
scientists to work on their own model in a more comprehensive way,
and also lead to the development of the Bohr model of atom, the two
developments which played an important role in the formulation of
Bohrs model were:
1. Dual character of electromagnetic radiation, which means radiation
has both wave and particle nature.
2. Experiments on atomic spectra, and the quantization of energy
levels.
Sir James Clark Maxwell gave the theory on wave nature of
electromagnetic radiation; by this he was able to explain the
phenomenon of charged particles on macroscopic level. He explained
that if a charge particle is accelerated then it emits electromagnetic
radiation, which is in fact a form of energy. Maxwell also proved that
light itself is an electromagnetic wave. Many phenomenon like
diffraction, interference etc. could be explained by Maxwells theory,
but certain phenomenon seem to deviate from Maxwellselectromagnetic theory. Some of those phenomenon are:
8/12/2019 dsfgdsf
6/12
1. Nature of emission of radiation: Black Body radiation.
2. Ejection of electrons when radiation strikes the metal: The
Photoelectric effect.
3. Variation of heat capacity of solids as a function of temperature.
4. Line Spectra of atoms, with special reference to hydrogen.
Thus, to overcome this problem a theory was put forward by Max
Plank, the main and basic idea of his theory was that atoms and
molecules could emit or absorb energy(light) only in discrete
amounts and not in a continuous manner, thus to the smallest
quantity of energy Plank gave the name Quantum.
UNIT 2: STRUCTURE OF ATOM
Atom was earlier considered the most fundamental and indivisible
unit of matter. Daltons Atomic Theory considered atom as the most
fundamental unit of matter and thus believed it to be indivisible. But
further on Sub atomic particles were discovered like electron,
protons, neutrons, etc.
8/12/2019 dsfgdsf
7/12
Electrons were discovered in the Cathode Ray tube experiment.
Adding to this J.J Thompson found out the charge to mass ratio of an
electron. R.A Millikan found out the value of charge on an electron
with his oil drop experiment, and using the ratio of J.J Thompson was
able to find out the mass too. A simple modification of the cathode ray
tubes lead to the discovery of canal rays, particles carrying positive
charge, thus, protons were discovered. Eventually, due to the aspect of
stabilizing the atom neutrons were discovered by Chadwick. Neutrons
have a mass slightly higher than the protons and have no charge.
Now, since so many particles came up, thus there was a need to
visualize how these particles were arranged in an atom, thusexperimentalists started making atomic models, many came up with
distinct ideas but had to face serious limitations and drawbacks. Lord
Rutherford came up with an idea of the model like the solar system,
and his model was also called the solar system model. To put
limitations to his model James Clark Maxwell had already developed a
theory known as the electromagnetic theory of Maxwell.
Thus such models, though not perfect still helped the early
scientists to work on their own model in a more comprehensive way,
and also lead to the development of the Bohr model of atom, the two
developments which played an important role in the formulation of
Bohrs model were:
1. Dual character of electromagnetic radiation, which means radiation
has both wave and particle nature.
2. Experiments on atomic spectra, and the quantization of energy
levels.
8/12/2019 dsfgdsf
8/12
Sir James Clark Maxwell gave the theory on wave nature of
electromagnetic radiation; by this he was able to explain the
phenomenon of charged particles on macroscopic level. He explained
that if a charge particle is accelerated then it emits electromagnetic
radiation, which is in fact a form of energy. Maxwell also proved that
light itself is an electromagnetic wave. Many phenomenon like
diffraction, interference etc. could be explained by Maxwells theory,
but certain phenomenon seem to deexperimentalists started making
atomic models, many came up with distinct ideas but had to face
serious limitations and drawbacks. Lord Rutherford came up with an
idea of the model like the solar system, and his model was also called
the solar system model. To put limitations to his model James Clark
Maxwell had already developed a theory known as the
electromagnetic theory of Maxwell.
Thus such models, though not perfect still helped the early
scientists to work on their own model in a more comprehensive way,
and also lead to the development of the Bohr model of atom, the two
developments which played an important role in the formulation of
Bohrs model were:
1. Dual character of electromagnetic radiation, which means radiation
has both wave and particle nature.
2. Experiments on atomic spectra, and the quantization of energy
levels.
Sir James Clark Maxwell gave the theory on wave nature of
electromagnetic radiation; by this he was able to explain the
phenomenon of charged particles on macroscopic level. He explained
that if a charge particle is accelerated then it emits electromagnetic
radiation, which is in fact a form of energy. Maxwell also proved that
light itself is an electromagnetic wave. Many phenomenon like
diffraction, interference etc. could be explained by Maxwells theory,
but certain phenomenon seem to deviate from Maxwellselectromagnetic theory. Some of those phenomenon are:
8/12/2019 dsfgdsf
9/12
1. Nature of emission of radiation: Black Body radiation.
2. Ejection of electrons when radiation strikes the metal: The
Photoelectric effect.
3. Variation of heat capacity of solids as a function of temperature.
4. Line Spectra of atoms, with special reference to hydrogen.
Thus, to overcome this problem a theory was put forward by Max
Plank, the main and basic idea of his theory was that atoms and
molecules could emit or absorb energy(light) only in discrete
amounts and not in a continuous manner, thus to the smallest
quantity of energy Plank gave the name Quantum.
UNIT 2: STRUCTURE OF ATOM
Atom was earlier considered the most fundamental and indivisible
unit of matter. Daltons Atomic Theory considered atom as the most
fundamental unit of matter and thus believed it to be indivisible. But
further on Sub atomic particles were discovered like electron,
protons, neutrons, etc.
8/12/2019 dsfgdsf
10/12
Electrons were discovered in the Cathode Ray tube experiment.
Adding to this J.J Thompson found out the charge to mass ratio of an
electron. R.A Millikan found out the value of charge on an electron
with his oil drop experiment, and using the ratio of J.J Thompson was
able to find out the mass too. A simple modification of the cathode ray
tubes lead to the discovery of canal rays, particles carrying positive
charge, thus, protons were discovered. Eventually, due to the aspect of
stabilizing the atom neutrons were discovered by Chadwick. Neutrons
have a mass slightly higher than the protons and have no charge.
Now, since so many particles came up, thus there was a need to
visualize how these particles were arranged in an atom, thusexperimentalists started making atomic models, many came up with
distinct ideas but had to face serious limitations and drawbacks. Lord
Rutherford came up with an idea of the model like the solar system,
and his model was also called the solar system model. To put
limitations to his model James Clark Maxwell had already developed a
theory known as the electromagnetic theory of Maxwell.
Thus such models, though not perfect still helped the early
scientists to work on their own model in a more comprehensive way,
and also lead to the development of the Bohr model of atom, the two
developments which played an important role in the formulation of
Bohrs model were:
1. Dual character of electromagnetic radiation, which means radiation
has both wave and particle nature.
2. Experiments on atomic spectra, and the quantization of energy
levels.
8/12/2019 dsfgdsf
11/12
Sir James Clark Maxwell gave the theory on wave nature of
electromagnetic radiation; by this he was able to explain the
phenomenon of charged particles on macroscopic level. He explained
that if a charge particle is accelerated then it emits electromagnetic
radiation, which is in fact a form of energy. Maxwell also proved that
light itself is an electromagnetic wave. Many phenomenon like
diffraction, interference etc. could be explained by Maxwells theory,
but certain phenomenon seem to deviate from Maxwells
electromagnetic theory. Some of those phenomenon are:
1. Nature of emission of radiation:Black Body radiation.2. Ejection of electrons when radiation
strikes the metal: The Photoelectric
effect.3. Variation of heat capacity of solids asa function of temperature.4. Line Spectra of atoms, with special
reference to hydrogen.Thus, to overcome this problem a
theory was put forward by Max Plank,the main and basic idea of his theory
was that atoms and molecules could
emit or absorb energy(light) only in
discrete amounts and not in a
continuous manner, thus to the smallest
8/12/2019 dsfgdsf
12/12
quantity of energy Plank gave the name
Quantum.