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    CEMENT INDUSTRY

    Kelompok 5Maya Monica D (1105821)

    Miftahul Jannah (1100545)

    Ratnasari (1105339)

    Siti Fatimah S (0900451)

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    TABLE OF CONTENT

    History of Cement

    Types of Cement

    Cement Making Process

    Impact of Cement Industry

    Definition of Cement

    Prevention

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    HISTORY OF CEMENT

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    Cement was first used by Egypt in pyramid

    building process.

    Cement which made by Egypt is gypsumcalcinations, then Roman make cement

    from lime stone calcinations and Greek

    make it from volcanic soil.

    History of Cement

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    DEFINITION OF CEMENT

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    Cement comes from word

    Caementum which means

    a substance which has thefunction as an adhesive

    between two or more

    ingredients become a part

    of a cohesive or adhesivematerial between the rocks

    of building construction

    Definition of Cement

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    TYPES OF CEMENT

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    Types of Cement

    No. SNI Nama

    SNI 15-0129-2004 Semen portland putih

    SNI 15-0302-2004 Semen portland pozolan / Portland Pozzolan

    Cement (PPC)

    SNI 15-2049-2004 Semen portland / Ordinary Portland Cement

    (OPC)SNI 15-3500-2004 Semen portland campur

    SNI 15-3758-2004 Semen masonry

    SNI 15-7064-2004 Semen portland komposit

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    Cement

    Making

    Process

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    1. Limestone

    2. Clay

    Materials of Cement Making

    Process

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    3. Iron sand

    4. Silica

    Material of Cement Making Process

    http://1.bp.blogspot.com/_o-QRLq3n6Fw/TRdYgKmOzZI/AAAAAAAAALA/WNfen8uPt6o/s1600/psr+besi.png
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    How Cement is Made

    Extracting Raw Materials Crushing and Transportation

    Raw Material Preparation I: Storage and Homogenisation

    Raw Material Preparation II: Drying and Raw Grinding

    Burning

    Cement Grinding

    Loading and Shipping

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    Extracting raw materials

    Crushing and transportation

    The most important rawmaterials for makingcement are limestone,silica, clay and iron sand.

    These are extracted fromquarries by blasting or byripping using heavymachinery. Wheelloaders and dumpertrucks transport the raw

    materials to the crushinginstallations. There therock is broken down toroughly the size used inroad metalling.

    1.

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    Raw material preparation I:

    Storage and homogenisation

    The crushed materialis transported into theraw material storage

    of the cement plant byconveyor-belts,cableways or railwaysand also inexceptional caseswith trucks. Oncethere it is stored inblending beds andhomogenised.

    2.

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    Raw material preparation II:

    Drying and raw grinding

    The desired raw mix ofcrushed raw materialand the additionalcomponents required for

    the type of cement, e.g.silica sand and iron ore,is prepared usingmetering devices. Rollergrinding mills and ballmills grind the mixture to

    a fine powder at thesame time as drying it,before it is conveyed tothe raw meal silos forfurther homogenisation.

    3.

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    Burning

    The burning of the rawmeal at approx. 1,450Cis carried out in Lepol orpreheater kilns that work

    by varying methods, themain difference being inthe preparation andpreheating of the kilnfeed. By chemicalconversion, a process

    known as sintering, anew product is formed:clinker.

    4.

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    The making of clinker is based on this

    reactions:

    + + +

    C3S C2S C3A C4AF

    Reaction on Cement Making

    Process

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    Those reactions have six steps, they are:

    1. Water Evaporation

    This process working at temperature 100 - 200 oC.

    2. Extrication of Absorban Water

    This process working at temperature 100400 oC.

    3. Decomposition of Clay

    The product from this process is Al2O3.2SiO2,working at

    temperature 400 - 750 oC. This is the reaction:

    Al4(OH)8.Si4O10 2( Al2O3.2SiO2 ) + 4 H2O

    Reaction on Cement Making

    Process

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    4. Decomposition of Metakaolinit

    The product from this process are Al2O3 and SiO2,

    working at temperature 600 - 900 oC. This is the reaction:

    Al2O3.2SiO2 Al2O3. + 2SiO2

    5. Decomposition of Carbonat

    The product are C3S and C3A, working at

    temperature 600 - 1000 oC. This is the reaction:

    CaCO3 CaO + CO2

    3CaO + 2SiO2 +Al2O3 2( CaO .SiO2) +

    CaO.Al2O3

    Reaction on Cement Making

    Process

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    6. Reaction of Solid Phase

    This reaction working at temperature 800 - 1300 oC,

    and the product is the main components in clinker,

    they are C3A, C2S dan C4AF, this is the reaction:

    CaO.Al2O3+ 2CaO 3CaO.Al2O3

    CaO.Al2O3 + 3CaO + Fe2O3 4CaO.Al2O3.Fe2O3

    CaO .SiO2 + CaO 2CaO .SiO2

    Reaction on Cement Making

    Process

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    Tricalcium silicate (C3S). Hydrates and hardens rapidly and is largelyresponsible for initial set and early strength. Portland cements with higher

    percentages of C3S will exhibit higher early strength.

    Tricalcium aluminate (C3A). Hydrates and hardens the quickest. Liberates a

    large amount of heat almost immediately and contributes somewhat to early

    strength. Gypsum is added to Portland cement to retard C3A hydration.

    Without gypsum, C3A hydration would cause Portland cement to set almost

    immediately after adding water.

    Dicalcium silicate (C2S). Hydrates and hardens slowly and is largely

    responsible for strength increases beyond one week.

    Tetracalcium aluminoferrite (C4AF). Hydrates rapidly but contributes very little

    to strength. Its use allows lower kiln temperatures in Portland cement

    manufacturing. Most Portland cement color effects are due to C4AF.

    About C3S, C3A, C2S and C4AF

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    Cement grinding

    After burning, the clinkeris cooled down andstored in clinker silos.

    From there the clinker isconveyed to ball mills orroller presses, in which itis ground down to veryfine cement, with theaddition of gypsum and

    anhydrite, as well asother additives,depending on the use towhich the cement is tobe put.

    5.

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    Loading and shipping

    The finished cement isstored in separate silos,depending on type andstrength class. From thereit is mainly loaded in bulk

    form from terminals ontorail or road vehicles as wellas onto ships. Only a smallproportion of the cementreaches the customer in theform of bags that have

    been filled by rotarypackers and stacked byautomatic palletisingsystems.

    6.

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    Reactions of Hydration

    2C3S + 6H = C3S2H3 + 3Ca(OH)2

    (100 + 24 = 75 + 49 ) 2 C2S + 4H = C3S2H3 + Ca(OH)2

    (100 + 21 = 99 + 22 )

    C3A + 6H = C3AH6 [C3A + CaSO4 . 2H2O = 3Cao. Al2O3.

    3CaSO4. 31H2O]

    Calcium Sulfoaluminate

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    Cement Manufacturing

    Details:

    1. Quarries (Limestone, Clay)

    2. Drill

    3. Dumper

    4. Crushing

    5. Prehomogenisation6. Grinding

    7. Preheating

    8. Filter

    9. Rotary Kiln

    10. Cooler

    11. Clinker Storage12. Additions

    13. Cement Grinding

    14. Cement Silos, Dispatching

    15. Grinding

    16. Homogenisation

    17. Filter

    18. Kiln

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    IMPACT OF CEMENT

    INDUSTRY

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    1. Declining Quality of Land

    The decline of soil

    fertility can be caused

    by clay mining

    process.

    Clay is used as a

    raw material for

    cement industry.

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    2. Declining Quality of Water

    Declining quality of

    water due to

    wastewater fromcement industry are

    dumped into the river

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    3. Cause Air Pollution

    Dust and smoke

    that generated

    during combustion

    process and during

    procurement of raw

    materials can

    cause respiratorysystem disorders

    4 I i th A t f

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    4. Increasing the Amount of

    Greenhouse Gases

    Gases that produced

    from combustion of

    petroleum fuels and coal

    are CO2, CO andanother gases.

    Increasing the amount

    of Carbon dioxide in theair can cause increasing

    of earth temperature.

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    5. Noise Pollution

    Noise pollution is a disruption in the

    environment caused by the sound or

    noise from industrial activities that cancause unrest for society.

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    6. decreasing diversity of flora, change in

    vegetation pattern and endemic species .

    7. Decreasing diversity of flora, change invegetation pattern and endemic species

    decreasing diversity of fauna (birds,

    endangered animals). Changes in aquaticecosystems and ground ecosystems as a

    place to live animals.

    Continued

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    PREVENTION

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    PREVENTION

    Implementing blended cementproduction

    that can decrease CO2emission.

    Replacing some of materials in cementmanufacture with more ecofriendly

    materials.

    Wate disposal industries that doesntdamage the environment.

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    http://people.ce.gatech.edu/~kk92/scmkek.

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