272
especificaciones presion temperatuta 10 283.15 z1 0.21 Z2 0.015 Z3 0.775 estimaciones ψ 0.5 FASE α X1 0.02 X2 0.01 X3 0.97 FASE β Y1 0.4 Y2 0.02 Y3 0.58 BUTANOL NUMERO PRINCIPAL NUMERO SECUNDARIO CH3 1 1 CH2 1 2 OH 5 14 METANOL CH3 1 1 OH 5 14 AGUA H2O 8 17 r1 3.9243 r2 q1 3.668 q2 φ1 0.0792870369341457 φ2 ϴ1 0.0505289839100727 ϴ2 l1 -1.6428 l2 lnϒ1 C 0.588338438978351 lnϒ2 C Ln ϒ R 1 2.77360863182287 Ln ϒ R 2 0.302797356419442 Ln ϒ R 3 0.00572873705823453 Ln ϒ 1 3.36194707080122 ϒ 1 CALCULO DE γ CALCULO DE ϒ 1

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UNIFACITERACION 1especificaciones 1 BUTANOLpresion2 METANOLtemperatuta 10283.153 AGUAz10.21Z20.015Z30.775estimaciones 0.5FASE X10.02X20.01X30.97FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.02752293580.017522592-1.11855695510.05362674810.0682982170.00173126050.0098992412LN T1.68328126210.079287036920.019205028430.9015079347CH20.05504587160.0223165087-1.11855695510.05362674810.0682982170.00173126050.0098992412LN T1.071900803710.050528983920.014106237630.9353647785OH0.02752293580.02479612080.38530556880.01682633180.02142976220.01686738120.8820057075LN T-0.3869217018l1-1.6428l2-1.6356l3-2.32H2O0.88990825690.9353647785-0.04272759070.01600329970.02038156090.02605399860.9761967765LN T0.0057287371ln1 C0.588338439ln2 C0.2737946311ln3 C0.0020825281

Ln R 12.7736086318Ln R 20.3027973564Ln R 30.0057287371

Ln 13.3619470708 128.8453000788Ln 20.5765919875 21.7799619497Ln 30.0078112651 31.0078418527

CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETA

estimaciones 0.5FASE X10.4X20.02X30.58CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.38532110090.2453162883-0.0330677950.25356397180.46133606740.02783942110.006445278LN T0.24073283210.733054318320.017756154830.2491895269CH21.10091743120.4463301741-0.0330677950.25356397180.46133606740.02783942110.006445278LN T0.153296850610.632370181420.017653954930.3499758637OH0.38532110090.3471456910.24675963380.07956013860.14475227380.27123481370.5742634068LN T-0.37988432l1-1.6428l2-1.6356l3-2.32H2O0.53211009170.5592902799-0.12788521950.07566858640.13767195640.4398984620.6355900895LN T-0.2253214247ln1 C-0.0164797594ln2 C-0.00663688ln3 C0.0872358131

Ln R 1-1.4177142755Ln R 2-1.1327136918Ln R 3-0.2253214247

Ln 1-1.434194035 10.238307354Ln 2-1.1393505717 20.3200267888Ln 3-0.1380856116 30.8710241188

SEGUNDA ITERACIONespecificaciones 1 BUTANOLpresion2 METANOLtemperatuta 10283.153 AGUAz10.2023682418Z20.0131461412Z30.784485617estimaciones 0.5FASE X10.0047364836X20.0062922824X30.988971234FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.0101181340.0064417523-1.20671673230.02153150740.01766536920.00063231750.0100525497LN T1.828996070210.019765333920.012720350530.9675143156CH20.01303619350.0052850889-1.20671673230.02153150740.01766536920.00063231750.0100525497LN T1.164690893810.012279601120.009108294130.9786121049OH0.0101181340.00911568710.39182863310.00675588770.00554281910.00616056290.8956652415LN T-0.3671437732l1-1.6428l2-1.6356l3-2.32H2O0.90731305870.9536586177-0.03872661860.00642543460.00527170130.00949894950.9913150381LN T0.0367016932ln1 C0.7061732329ln2 C0.3228130926ln3 C0.0002147201

Ln R 13.217471639Ln R 20.4682900933Ln R 30.0367016932

Ln 13.9236448719 150.5844831395Ln 20.7911031859 22.2058285234Ln 30.0369164133 31.0376062871

CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETA

estimaciones 0.5FASE X10.327117538X20.0199683766X30.6529140854CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.31842744460.2027281626-0.16766952650.23973532630.43163637450.02238804360.0071370997LN T0.395823234710.667780177920.019747640630.3124721815CH20.90032349910.3650060692-0.16766952650.23973532630.43163637450.02238804360.0071370997LN T0.252057248510.55682369420.01897829830.4241980079OH0.31842744460.28687947540.27400325720.07522115880.13543347480.21812295640.6359035511LN T-0.406421278l1-1.6428l2-1.6356l3-2.32H2O0.59900374810.6296008648-0.11142648620.07154184060.1288089710.35005357760.7038129022LN T-0.1999071272ln1 C-0.0057829816ln2 C0.0081316108ln3 C0.0806141794

Ln R 1-0.992879637Ln R 2-1.0041602471Ln R 3-0.1999071272

Ln 1-0.9986626186 10.3683717654Ln 2-0.9960286363 20.3693433291Ln 3-0.1192929478 30.8875477575TERCERA ITERACIONespecificaciones 1 BUTANOLpresion2 METANOLtemperatuta 10283.153 AGUAz10.2015719644Z20.0124677858Z30.7859602498estimaciones 0.5FASE X10.0031439288X20.0049355717X30.9919204995FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.00741238570.0047191263-1.21819972620.01595581610.01186113840.00046273020.0100761808LN T1.848507593810.013205483820.010042962530.9767515536CH20.0086530150.0035080757-1.21819972620.01595581610.01186113840.00046273020.0100761808LN T1.177115684810.008176768220.007167159630.9846560721OH0.00741238570.0066780090.39289923040.00500641690.003721640.00450830230.897770725LN T-0.3646875775l1-1.6428l2-1.6356l3-2.32H2O0.91001880690.9565025756-0.0380968910.00476153630.00353960210.00694980950.9936453702LN T0.0408808019ln1 C0.7229458667ln2 C0.3297685968ln3 C0.0001086318

Ln R 13.2767137312Ln R 20.4902578125Ln R 30.0408808019

Ln 13.9996595979 154.5795678727Ln 20.8200264094 22.2705598008Ln 30.0409894337 31.0418410971

CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETA

estimaciones 0.5FASE X10.2663593333X20.0181862514X30.7154544152CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.26105099520.1661992064-0.29694297090.22366067930.39996765330.01793776670.0077125779LN T0.549219321210.601400640820.019892158930.3787072003CH20.73309908250.2972105191-0.29694297090.22366067930.39996765330.01793776670.0077125779LN T0.349738718710.484653016420.018475951730.4968710319OH0.26105099520.23518755630.29694307470.07017745670.12549685870.17476465370.6871776956LN T-0.4254716873l1-1.6428l2-1.6356l3-2.32H2O0.65638019750.6899081037-0.09750016170.06674484280.1193583880.27813054520.7605627102LN T-0.1782148542ln1 C0.0161784759ln2 C0.0244859711ln3 C0.0707802108

Ln R 1-0.5654895494Ln R 2-0.8698145699Ln R 3-0.1782148542

Ln 1-0.5493110735 10.5773474233Ln 2-0.8453285988 20.4294162294Ln 3-0.1074346433 30.8981352197

CUARTA ITERACIONespecificaciones 1 BUTANOLpresion2 METANOLtemperatuta 10283.153 AGUAz10.2017698697Z20.0123071755Z30.7859229547estimaciones 0.5FASE X10.0035397395X20.004614351X30.9918459095FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.0074808170.0047626934-1.2165676430.01607686030.01333264050.00046700190.0100755414LN T1.845770027910.014854117120.009380563730.9757653192CH20.00974240220.0039497313-1.2165676430.01607686030.01333264050.00046700190.0100755414LN T1.175372423410.009201698620.006697426530.9841008749OH0.0074808170.00673966040.39289965720.00504439660.00418334960.00454992110.8977137561LN T-0.3652692966l1-1.6428l2-1.6356l3-2.32H2O0.90995037570.9564306489-0.03810863340.00479765830.0039787280.00701417990.9935823174LN T0.0402300497ln1 C0.7209064706ln2 C0.328903326ln3 C0.0001196682

Ln R 13.2681646621Ln R 20.4869385274Ln R 30.0402300497

Ln 13.9890711327 154.0047028535Ln 20.8158418535 22.261078368Ln 30.0403497179 31.041174828

estimaciones 0.5FASE X10.2216714451X20.016162581X30.7621659739CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.21819635420.1389156202-0.40456553770.20818606810.37068634660.01474247920.0081320567LN T0.68079016210.543071466920.019182301330.4377462318CH20.61010489470.2473466367-0.40456553770.20818606810.37068634660.01474247920.0081320567LN T0.433522037110.424984622720.017301143330.557714234OH0.21819635420.19657870790.31379796120.06532202630.11630933570.14363350330.7245525456LN T-0.4363384465l1-1.6428l2-1.6356l3-2.32H2O0.69923483850.7349517602-0.08721507540.06212690770.11062025750.22723786540.8019288916LN T-0.1605783855ln1 C0.0453831696ln2 C0.0409269109ln3 C0.0608353274

Ln R 1-0.1934355125Ln R 2-0.7491104883Ln R 3-0.1605783855

Ln 1-0.1480523429 10.862385974Ln 2-0.7081835774 20.4925380427Ln 3-0.099743058 30.9050699386

QUINTA ITERACIONespecificaciones 1 BUTANOLpresion2 METANOLtemperatuta 10283.153 AGUAz10.2021507313Z20.0122580013Z30.7855912674estimaciones 0.5FASE X10.0043014626X20.0045160026X30.9911825348FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.00808941760.0051501615-1.2124627230.01731357360.01613534570.00050510060.0100701807LN T1.838835866910.018008391720.009159161730.9728324466CH20.01183888780.0047996813-1.2124627230.01731357360.01613534570.00050510060.0100701807LN T1.17095680210.011168659220.006546960230.9822843807OH0.00808941760.00728796440.39269015460.00543243710.00506274740.004921110.8972361334LN T-0.366411099l1-1.6428l2-1.6356l3-2.32H2O0.90934177510.9557909609-0.03824550050.00516671840.00481511150.00758699410.9930536885LN T0.0386721832ln1 C0.7152995412ln2 C0.326555887ln3 C0.0001526445

Ln R 13.2468418347Ln R 20.4788625641Ln R 30.0386721832

Ln 13.9621413759 152.5697771587Ln 20.8054184512 22.2376326429Ln 30.0388248276 31.0395883606

estimaciones 0.5FASE X10.1883249241X20.0144941174X30.7971809585CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.18607251520.118463844-0.49331116150.1940117960.34414889020.012416310.0084408958LN T0.792280692610.492694106920.018369786330.4889361068CH20.51832547920.2101377404-0.49331116150.1940117960.34414889020.012416310.0084408958LN T0.504518365510.376134434120.016163212930.607702353OH0.18607251520.1676375150.32626119370.06087460010.10798274380.12097002720.7520695932LN T-0.4417897898l1-1.6428l2-1.6356l3-2.32H2O0.73135867750.7687164852-0.07957229640.057897020.1027009470.19056634290.8323845371LN T-0.1455671709ln1 C0.0781457344ln2 C0.0571083881ln3 C0.0519481908

Ln R 10.1255926601Ln R 2-0.643071301Ln R 3-0.1455671709

Ln 10.2037383944 11.225977389Ln 2-0.5859629129 20.5565696756Ln 3-0.0936189801 30.9106296642

SEXTA ITERACIONespecificaciones 1 BUTANOLpresion2 METANOLtemperatuta 10283.153 AGUAz10.2026029996Z20.0122452795Z30.7851517208estimaciones 0.5FASE X10.0052059992X20.0044905591X30.9903034417FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.00889592510.0056636279-1.20744017640.01894433280.01943054410.00055561740.0100630871LN T1.830362712510.02173287420.009081471830.9691856542CH20.01432843830.0058089864-1.20744017640.01894433280.01943054410.00055561740.0100630871LN T1.165561161310.013497826120.006500709630.9800014643OH0.00889592510.00801456770.3924043440.00594411630.00609667370.00541328710.8966041LN T-0.3677550253l1-1.6428l2-1.6356l3-2.32H2O0.90853526760.9549432571-0.03842813680.00565336970.0057984650.00834659140.9923541591LN T0.0367857721ln1 C0.7084042921ln2 C0.3236733086ln3 C0.0001988265

Ln R 13.2208378317Ln R 20.4690454834Ln R 30.0367857721

Ln 13.9292421238 150.8684111002Ln 20.792718792 22.2093951538Ln 30.0369845986 31.0376770391

CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETA

estimaciones 0.5FASE X10.1627260027X20.0131603926X30.8241136047CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.16136366540.1027328516-0.567269250.18116372760.3201954220.01066587220.0086752607LN T0.887490484510.449142226320.017596996130.5332607776CH20.44786973220.1815738128-0.567269250.18116372760.3201954220.01066587220.0086752607LN T0.565147242510.335779795820.015162369530.6490578348OH0.16136366540.14537667670.33574713750.05684329350.10046692350.10391580530.7729511047LN T-0.4439091176l1-1.6428l2-1.6356l3-2.32H2O0.75606752730.7946874632-0.07373253760.05406289810.09555275060.16317734280.855496025LN T-0.1323790704ln1 C0.1121025561ln2 C0.0727845087ln3 C0.0443536303

Ln R 10.400569755Ln R 2-0.5499808369Ln R 3-0.1323790704

Ln 10.5126723111 11.6697473225Ln 2-0.4771963282 20.6205206916Ln 3-0.0880254401 30.9157375799

SEPTIMA ITERACIONespecificaciones 1 BUTANOLpresion2 METANOLtemperatuta 10283.153 AGUAz10.2031037711Z20.0122507703Z30.7846454586estimaciones 0.5FASE X10.0062075421X20.0045015406X30.9892909172FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.00982484660.0062550296-1.20183589420.02080559150.02303915940.00061383950.0100549183LN T1.820929382910.025830920920.009074530230.9650945489CH20.01708497840.0069265334-1.20183589420.02080559150.02303915940.00061383950.0100549183LN T1.159554088210.016068689920.006506127830.9774251823OH0.00982484660.0088514570.39207193350.00652811880.00722893990.00598053570.8958762731LN T-0.3692229613l1-1.6428l2-1.6356l3-2.32H2O0.90760634610.9539668862-0.03863900920.00620880670.00687534830.00922220360.9915486062LN T0.0346976622ln1 C0.7007237219ln2 C0.3204645552ln3 C0.0002576784

Ln R 13.1919153468Ln R 20.4581442178Ln R 30.0346976622

Ln 13.8926390687 149.0401361873Ln 20.778608773 22.1784394526Ln 30.0349553406 31.0355734596

CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETA

estimaciones 0.5FASE X10.1426001287X20.0120859593X30.8453139119CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.14191384230.0903500404-0.62954406740.16956486390.29862329910.00931105570.0088578297LN T0.969422592110.411392761820.016891204430.5717160338CH20.39247741850.1591168507-0.62954406740.16956486390.29862329910.00931105570.0088578297LN T0.617320990210.302127154820.014297219930.6835756253OH0.14191384230.12785383080.34315330970.05320394690.0936982920.09071605510.7892176975LN T-0.4439871614l1-1.6428l2-1.6356l3-2.32H2O0.77551735040.8151307835-0.06915928190.0506015640.08911519550.14209875440.8734997582LN T-0.1206183864ln1 C0.1457400122ln2 C0.087737359ln3 C0.0379901099

Ln R 10.638945062Ln R 2-0.4681267731Ln R 3-0.1206183864

Ln 10.7846850742 12.191716604Ln 2-0.3803894141 20.6835951558Ln 3-0.0826282766 30.9206933269

OCTAVA ITERACIONespecificaciones 1 BUTANOLpresion2 METANOLtemperatuta 10283.153 AGUAz10.2036428914Z20.012267157Z30.7840899515estimaciones 0.5FASE X10.0072857829X20.0045343141X30.988179903FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.01084412570.0069039579-1.19579884980.02282585090.02687827080.00067777070.0100459534LN T1.810794611510.03021290420.00910899830.960678098CH20.02005261350.0081296619-1.19579884980.02282585090.02687827080.00067777070.0100459534LN T1.153100342210.018827023420.006542107330.9746308693OH0.01084412570.00976975180.39170545760.00716201060.00843352840.00660340610.8950775143LN T-0.3707783004l1-1.6428l2-1.6356l3-2.32H2O0.9065870670.9528955424-0.03887068850.00681169280.00802101630.01018387570.9906645464LN T0.0324653803ln1 C0.6924837648ln2 C0.317023595ln3 C0.0003296187

Ln R 13.1608639983Ln R 20.4464541073Ln R 30.0324653803

Ln 13.8533477632 147.1506485089Ln 20.7634777023 22.1457254542Ln 30.032794999 31.033338682

CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETA

estimaciones 0.5FASE X10.1264756621X20.0112104123X30.8623139256CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.12631749950.0804205636-0.68241235710.15912376050.27923582740.00823901120.0090030266LN T1.040335500310.378596520520.016256760330.6051467192CH20.34809815260.1411247608-0.68241235710.15912376050.27923582740.00823901120.0090030266LN T0.66247779510.273838424920.013552194830.7126093802OH0.12631749950.11380268440.34905389580.04992786770.08761513310.08027130540.8021544992LN T-0.4428272415l1-1.6428l2-1.6356l3-2.32H2O0.79111369320.8315237876-0.06550697960.04748572890.08332958420.12549325930.8878181056LN T-0.1100675776ln1 C0.1781074815ln2 C0.1018057896ln3 C0.0327066479

Ln R 10.8464883044Ln R 2-0.396053945Ln R 3-0.1100675776

Ln 11.0245957858 12.7859691047Ln 2-0.2942481554 20.74509157Ln 3-0.0773609297 30.9255557328

NOVENA ITERACIONespecificaciones 1 BUTANOLpresion2 METANOLtemperatuta 10283.153 AGUAz10.2042120532Z20.0122904978Z30.7834974489estimaciones 0.5FASE X10.0084241064X20.0045809957X30.9869948979FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.01193128630.0075961033-1.18944265060.02495509580.03088079560.00074601180.0100363882LN T1.800155056610.034805872720.009169197530.9560249298CH20.0231856140.0093998322-1.18944265060.02495509580.03088079560.00074601180.0100363882LN T1.146325153910.02172855620.006597319730.9716741243OH0.01193128630.01074920280.39131351910.00783009850.00968939070.00726826830.8942252753LN T-0.3723918623l1-1.6428l2-1.6356l3-2.32H2O0.90549990630.9517528495-0.03911799420.00744710220.00921545020.01121061790.9897212952LN T0.0301329403ln1 C0.6838540319ln2 C0.3134210751ln3 C0.0004148723

Ln R 13.1282853168Ln R 20.4342009905Ln R 30.0301329403

Ln 13.8121393486 145.2471347929Ln 20.7476220656 22.11197191Ln 30.0305478125 31.0310191845

CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETA

estimaciones 0.5FASE X10.1133598043X20.0104893422X30.8761508534CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.11362307020.0723386023-0.72758820990.14974683690.26184415830.00737569790.0091204275LN T1.101976923810.350045320820.015691201730.6342634775CH20.31199946150.126489753-0.72758820990.14974683690.26184415830.00737569790.0091204275LN T0.701730588210.249897517620.012910757830.7371917246OH0.11362307020.10236594660.35383170460.04698569370.08215819220.07186018810.8126147222LN T-0.4409406009l1-1.6428l2-1.6356l3-2.32H2O0.80380812240.8448666484-0.06254395270.04468746640.07813956050.11216789610.8993953957LN T-0.1005849124ln1 C0.2086424588ln2 C0.1148929327ln3 C0.0283360219

Ln R 11.0277747482Ln R 2-0.332525881Ln R 3-0.1005849124

Ln 11.236417207 13.4432548695Ln 2-0.2176329483 20.8044206515Ln 3-0.0722488904 30.9302993244

DECIMA ITERACIONespecificaciones 1 BUTANOLpresion2 METANOLtemperatuta 10283.153 AGUAz10.2048032393Z20.0123183479Z30.7828784128estimaciones 0.5FASE X10.0096064786X20.0046366958X30.9857568256FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.01306713250.0083192445-1.18286991150.0271517460.03498439370.00081736660.0100263905LN T1.789186732510.039540923320.009245575530.9512135012CH20.02643984940.0107191532-1.18286991150.0271517460.03498439370.00081736660.0100263905LN T1.139340607910.024731021620.006664799130.9686041792OH0.01306713250.01177251580.39090332790.0085193360.01097696650.00796346590.8933344936LN T-0.3740371077l1-1.6428l2-1.6356l3-2.32H2O0.90436406020.9505589843-0.03937652170.00810262680.01044004640.01228447140.9887353852LN T0.0277395888ln1 C0.6749839051ln2 C0.3097192589ln3 C0.0005132293

Ln R 13.0947181092Ln R 20.4215874209Ln R 30.0277395888

Ln 13.7697020142 143.3671401195Ln 20.7313066798 22.0777938458Ln 30.0282528181 31.0286557143

CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETA

estimaciones 0.5FASE X10.1025572782X20.0098899452X30.8875527767CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.10316259020.0656788939-0.76639917490.14134119640.24626669150.00667046720.009216647LN T1.155742738610.325141679820.015189476430.6596688438CH20.2822677380.1144360195-0.76639917490.14134119640.24626669150.00667046720.009216647LN T0.735968253410.229516854420.012357841130.7581253045OH0.10316259020.0929418310.35775205560.04434827670.07727048910.06498924330.8211877144LN T-0.4386573349l1-1.6428l2-1.6356l3-2.32H2O0.81426860250.8558614499-0.06010887340.04217905430.07349093130.10131349510.9088839141LN T-0.0920619299ln1 C0.2370499914ln2 C0.1269582768ln3 C0.0247221499

Ln R 11.1865368245Ln R 2-0.2764768001Ln R 3-0.0920619299

Ln 11.4235868159 14.151986174Ln 2-0.1495185233 20.8611224871Ln 3-0.06733978 30.9348774947

ONCEAVA ITERACIONespecificaciones 1 BUTANOLpresion2 METANOLtemperatuta 10283.153 AGUAz10.2054086995Z20.012349069Z30.7822422315estimaciones 0.5FASE X10.0108173991X20.0046981379X30.984484463FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.01423443760.0090624142-1.17617503420.02937989460.03913140450.0008907590.0100161109LN T1.778049821710.044353110320.009331893130.9463149966CH20.0297726580.012070329-1.17617503420.02937989460.03913140450.0008907590.0100161109LN T1.132248707210.027794076920.006739936330.9654659868OH0.01423443760.0128241710.39048127490.00921845670.01227816370.00867851540.8924186043LN T-0.375690018l1-1.6428l2-1.6356l3-2.32H2O0.9031967550.9493320533-0.03964232870.00876755110.01167759770.01338927350.9877216864LN T0.0253207078ln1 C0.6660072759ln2 C0.3059739551ln3 C0.0006240159

Ln R 13.0606525861Ln R 20.4087975999Ln R 30.0253207078

Ln 13.726659862 141.5401264292Ln 20.714771555 22.0437197514Ln 30.0259447237 31.0262842177

CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETA

estimaciones 0.5FASE X10.0935660746X20.0093875867X30.8970463387CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.09445290030.0601338335-0.79989649630.13381645640.23233000470.00608746740.0092964053LN T1.202774505810.303377753120.014745586330.6818766607CH20.25752130620.1044034059-0.79989649630.13381645640.23233000470.00608746740.0092964053LN T0.765917727810.212075800220.011880296830.776043903OH0.09445290030.08509504740.3610048270.04198725770.07289760940.05930917460.8282940448LN T-0.4361914962l1-1.6428l2-1.6356l3-2.32H2O0.82297829240.8650160308-0.05808583270.03993352060.06933194370.09236129590.916749143LN T-0.0844060989ln1 C0.2632160074ln2 C0.1380045758ln3 C0.0217292905

Ln R 11.3258828536Ln R 2-0.2269791942Ln R 3-0.0844060989

Ln 11.589098861 14.8993319595Ln 2-0.0889746183 20.9148687942Ln 3-0.0626768084 30.9392469814

DOCEAVA ITERACIONespecificaciones 1 BUTANOLpresion2 METANOLtemperatuta 10283.153 AGUAz10.2060211548Z20.0123815065Z30.7815973388estimaciones 0.5FASE X10.0120423095X20.0047630129X30.9831946776FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.0154177270.0098157603-1.16944323310.03160870380.04327018840.00096521980.0100056854LN T1.766887233510.049183068720.009423893230.9413930381CH20.03314397120.0134371153-1.16944323310.03160870380.04327018840.00096521980.0100056854LN T1.125140455310.030880341920.00681953430.9623001241OH0.0154177270.01389022680.39005305980.00991778460.01357677970.00940397460.8914897036LN T-0.3773295628l1-1.6428l2-1.6356l3-2.32H2O0.90201346570.9480883214-0.0399118780.00943267260.0129126940.01451045440.9866935866LN T0.0229074585ln1 C0.6570418385ln2 C0.3022342033ln3 C0.0007461426

Ln R 13.0265256971Ln R 20.3959954669Ln R 30.0229074585

Ln 13.6835675356 139.7880865918Ln 20.6982296702 22.0101908547Ln 30.0236536011 31.0239355663

CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETA

estimaciones 0.5FASE X10.0860146548X20.0089634666X30.9050218787CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.08713589110.055475429-0.82892635510.12708632220.2198704420.00560060730.0093631612LN T1.244020937410.284320306620.014353380330.7013263131CH20.23673758190.0959773396-0.82892635510.12708632220.2198704420.00560060730.0093631612LN T0.792183144110.197079024620.011466861930.7914541135OH0.08713589110.07850296560.36372949170.03987556010.06898820330.05456577810.8342418871LN T-0.4336811045l1-1.6428l2-1.6356l3-2.32H2O0.83029530150.8727067929-0.05638940920.03792511330.06561375980.08489981020.9233321668LN T-0.0775340171ln1 C0.2871449723ln2 C0.1480648424ln3 C0.0192435668

Ln R 11.448435926Ln R 2-0.1832223708Ln R 3-0.0775340171

Ln 11.7355808983 15.6722218311Ln 2-0.0351575284 20.965453318Ln 3-0.0582904503 30.9433759038CATORCEAVA ITERACIONespecificaciones 1 BUTANOLpresion2 METANOLtemperatuta 10283.153 AGUAz10.2066339798Z20.0124148175Z30.7809512027estimaciones 0.5FASE X10.0132679596X20.004829635X30.9819024053FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.01660329790.0105705589-1.16274938630.03381221280.04735611210.00103988830.0099952342LN T1.755822956110.053978325120.009518583930.936503091CH20.036517320.0148047268-1.16274938630.03381221280.04735611210.00103988830.0099952342LN T1.11809480710.033956287620.006901301530.9591424109OH0.01660329790.01495833810.38962370930.01060917420.01485880990.01013145730.8905585265LN T-0.3789380126l1-1.6428l2-1.6356l3-2.32H2O0.90082789480.9468421916-0.0401820390.0100902440.01413201580.01563506140.9856629673LN T0.0205264507ln1 C0.6481881321ln2 C0.2985418692ln3 C

Ln R 12.9927160251Ln R 20.3833227397Ln R 30.0205264507

Ln 13.6409041572 138.1262933105Ln 20.681864609 21.9775616759Ln 30.0205264507 31.0207385671

CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETAestimaciones 0.5FASE X10.0796224041X20.0086030337X30.9117745622CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.08094076870.0515312784-0.85417815470.12106978640.20873554130.00519046140.009419505LN T1.280278905910.267599189620.014006960230.7183938502CH20.21914423140.0888447037-0.85417815470.12106978640.20873554130.00519046140.009419505LN T0.815271944810.184127248720.011107978530.8047647728OH0.08094076870.07292162040.36603071190.03798776660.06549443320.05056979490.8392620178LN T-0.4312136693l1-1.6428l2-1.6356l3-2.32H2O0.8364904240.8792183622-0.05495532160.0361296580.06229088160.07862420130.9288884067LN T-0.0713689564ln1 C0.308915669ln2 C0.1571914403ln3 C0.0171713346

Ln R 11.5564277316Ln R 2-0.1444969672Ln R 3-0.0713689564

Ln 11.8653434006 16.4581532388Ln 20.0126944731 21.01277539Ln 3-0.0541976218 30.9472448917CATORCEAVA ITERACIONestimaciones 0.5FASE X10.0144761727X20.0048945574X30.9806292699FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.01777131210.0113141801-1.15619566590.03595443620.05133096290.00111351370.0099849323LN T1.745024424110.058669075820.00960974130.9317211833CH20.03984267720.0161528817-1.15619566590.03595443620.05133096290.00111351370.0099849323LN T1.111218383210.036976648520.006980521130.9560428305OH0.01777131210.01601063210.38920059190.01128133430.01610598890.01084877770.8896406391LN T-0.3804927983l1-1.6428l2-1.6356l3-2.32H2O0.89965988060.9456145152-0.04044826240.01072952650.01531819120.01674425420.984647057LN T0.0182129268ln1 C0.6395805778ln2 C0.2949528512ln3 C

Ln R 12.9597334361Ln R 20.3709694219Ln R 30.0182129268

Ln 13.5993140139 136.5731371713Ln 20.6659222732 21.9462847Ln 30.0182129268 31.0183797936CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETAestimaciones 0.5FASE X10.074202522X20.0082981064X30.9174993717CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.07568864990.0481874951-0.87609898050.11572289870.19883822430.00484422090.0094671459LN T1.312048064210.252976348920.013705125430.7333185257CH20.20422712470.0827970614-0.87609898050.11572289870.19883822430.00484422090.0094671459LN T0.83550230510.172955645920.010799302330.8162450518OH0.07568864990.06818985150.36797745690.0363100870.06238897650.04719643180.843506749LN T-0.4288556414l1-1.6428l2-1.6356l3-2.32H2O0.84174254280.8847387593-0.05374114320.03453403930.05933732320.07333362210.9335864409LN T-0.0658703952ln1 C0.3285405966ln2 C0.1654018806ln3 C0.0154457447

Ln R 11.6512459984Ln R 2-0.1103697811Ln R 3-0.0658703952

Ln 11.9797865949 17.2411975121Ln 20.0550320996 21.0565745297Ln 3-0.0504246505 30.9508255702QUINCEAVA ITERACIONestimaciones 0.5FASE X10.0156613237X20.0049603539X30.9793783224FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.01891897030.0120448414-1.14980479490.0380325080.05517960670.0011859170.0099748048LN T1.734526300810.063235517620.009702597930.9270618845CH20.04310456070.0174753033-1.14980479490.0380325080.05517960670.0011859170.0099748048LN T1.104533257610.039927969820.007060932330.9530110979OH0.01891897030.01704458690.38878451840.01193336570.01731356840.01155419010.8887382934LN T-0.3819887232l1-1.6428l2-1.6356l3-2.32H2O0.89851222240.9444082346-0.04070993870.01134966490.01646670390.01783531690.983648348LN T0.0159738669ln1 C0.6312431731ln2 C0.2914771912ln3 C

Ln R 12.9276840111Ln R 20.3589753739Ln R 30.0159738669

Ln 13.5589271842 135.1254937388Ln 20.650452565 21.916407932Ln 30.0159738669 31.0161021312CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETAestimaciones 0.5FASE X10.0695574659X20.0080349348X30.9224075993CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.07118568870.0453206661-0.89527864290.1109457980.19000042960.00454843770.0095078993LN T1.340074114410.240104909520.01343638430.7464587065CH20.19144256670.0776139897-0.89527864290.1109457980.19000042960.00454843770.0095078993LN T0.853349082310.163239174420.010528430130.8262323954OH0.07118568870.0641330180.36964364520.03481118790.05961596360.04431466620.8471378043LN T-0.4266279207l1-1.6428l2-1.6356l3-2.32H2O0.84624550390.8894717317-0.05270130590.03310845640.05669994760.068819270.9376052634LN T-0.0609442843ln1 C0.3462692134ln2 C0.172808131ln3 C0.0139951419

Ln R 11.7350401012Ln R 2-0.0801160101Ln R 3-0.0609442843

Ln 12.0813093146 18.0149561466Ln 20.0926921209 21.0971239018Ln 3-0.0469491423 30.9541359215DIESISEISAVA ITERACIONestimaciones 0.5FASE X10.0168154479X20.0050248421X30.9781597099FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.02003696340.0127566164-1.14361952030.0400316180.0588806160.00125650670.0099649339LN T1.724395997110.06764976420.00979316430.922557072CH20.04628104940.0187631045-1.14361952030.0400316180.0588806160.00125650670.0099649339LN T1.098082356710.042791272220.00713953330.9500691948OH0.02003696340.01805181570.38837900260.01256062150.01847482490.0122419340.8878588216LN T-0.3834182455l1-1.6428l2-1.6356l3-2.32H2O0.89739422930.9432331344-0.04096492150.01194623950.01757115940.01889932350.9826749558LN T0.0138225406ln1 C0.6232280217ln2 C0.2881364575ln3 C

Ln R 12.8967714823Ln R 20.3474155478Ln R 30.0138225406

Ln 13.519999504 133.7844117074Ln 20.6355520053 21.8880640752Ln 30.0138225406 31.0139185136CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETAestimaciones 0.5FASE X10.065554543X20.0078077837X30.9266376733CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.06730488690.0428499374-0.9121077360.10667767650.18210522550.00429431080.009542954LN T1.364845458610.228751896220.01319873930.7580493647CH20.18042534780.0731474265-0.9121077360.10667767650.18210522550.00429431080.009542954LN T0.869123287310.154758521620.010291535530.8349499429OH0.06730488690.06063670380.37107742480.033471990.0571387050.04183875060.8502611152LN T-0.4245455828l1-1.6428l2-1.6356l3-2.32H2O0.85012630570.8935507649-0.05180600210.03183476310.054343860.06494453220.9410621187LN T-0.0565309807ln1 C0.3622551815ln2 C0.179479336ln3 C0.0127701067

Ln R 11.8092163984Ln R 2-0.053262328Ln R 3-0.0565309807

Ln 12.17147158 18.7711820439Ln 20.126217008 21.1345283433Ln 3-0.043760874 30.9571828174DIESISIETEAVA ITERACIONestimaciones 0.5FASE X10.0179317136X20.0050874786X30.9769808078FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.02111852490.0134451971-1.13767286060.04194229770.06241702940.00132485070.00995538LN T1.714684240810.07188889820.009880647230.9182304548CH20.04935334010.0200086621-1.13767286060.04194229770.06241702940.00132485070.00995538LN T1.091897983510.045550611220.00721565330.9472337358OH0.02111852490.01902622230.38798652530.01316013070.01958443650.0129077980.8870075845LN T-0.3847757701l1-1.6428l2-1.6356l3-2.32H2O0.89631266770.9420963267-0.04121166020.01251642480.01862649630.01992973580.9817328134LN T0.0117686659ln1 C0.6155723748ln2 C0.2849460829ln3 C

Ln R 12.8671490818Ln R 20.3363462669Ln R 30.0117686659

Ln 13.4827214567 132.5481801153Ln 20.6212923498 21.8613319802Ln 30.0117686659 31.0118381891CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETAestimaciones 0.5FASE X10.0620882311X20.0076108512X30.9303009177CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.06394411220.0407102861-0.92691351310.10286261920.17504873130.00407482450.0095732606LN T1.386780257610.21871915120.012988336130.7682925129CH20.17088503960.0692796275-0.92691351310.10286261920.17504873130.00407482450.0095732606LN T0.883091201810.147332967920.010083806630.8425832255OH0.06394411220.05760889540.37231743660.03227494890.05492460630.03970033210.8529613873LN T-0.4226144536l1-1.6428l2-1.6356l3-2.32H2O0.85348708050.897083208-0.05103131340.03069627330.05223806030.06160082040.944050758LN T-0.052576438ln1 C0.3766526205ln2 C0.1854829793ln3 C0.011730762

Ln R 11.8749860701Ln R 2-0.0293963998Ln R 3-0.052576438

Ln 12.2516386906 19.503296046Ln 20.1560865795 21.1689274039Ln 3-0.040845676 30.959977266DIECIOCHOAVA ITERACIONestimaciones 0.5FASE X10.0190048133X20.0051478595X30.9758473272FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.02215841540.0141072477-1.13198901680.04375814230.06577736130.00139061210.0099461898LN T1.705426971210.075936300320.009964494630.9140992051CH20.05230682550.021206054-1.13198901680.04375814230.06577736130.00139061210.0099461898LN T1.086003024110.04819399120.007288809530.9445171996OH0.02215841540.01996308640.38760901210.01372988380.02063879950.01354850050.8861887497LN T-0.3860579347l1-1.6428l2-1.6356l3-2.32H2O0.89527277730.9410033186-0.04144895170.01305830930.01962928690.02092144920.9808265338LN T0.0098187217ln1 C0.6083012945ln2 C0.281916421ln3 C

Ln R 12.8389247696Ln R 20.3258068327Ln R 30.0098187217

Ln 13.4472260641 131.413133322Ln 20.6077232538 21.8362459699Ln 30.0098187217 31.0098670835CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETAestimaciones 0.5FASE X10.0590734578X20.0074394241X30.9334871181CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.06102099260.0388492698-0.9399715110.09945057550.16873807480.00388436250.0095995824LN T1.406237480510.209836705620.012801803230.7773614912CH20.16258749850.0659156668-0.9399715110.09945057550.16873807480.00388436250.0095995824LN T0.895481414410.14081201920.009901187330.8492867936OH0.06102099260.05497538180.37339473060.03120436050.05294452730.03784469270.8553066181LN T-0.4208339151l1-1.6428l2-1.6356l3-2.32H2O0.85641020010.9001556406-0.05035799420.02967805090.05035483360.05870141240.9466464405LN T-0.0490318405ln1 C0.3896100517ln2 C0.1908830655ln3 C0.010844924

Ln R 11.9333944694Ln R 2-0.0081586384Ln R 3-0.0490318405

Ln 12.3230045211 110.2062933091Ln 20.1827244271 21.2004835417Ln 3-0.0381869165 30.9625330108DIESINUEVEAVA ITERACIONestimaciones 0.5FASE X10.0200308217X20.0052056953X30.974763483FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.02315276790.0147403064-1.12658446490.04547533710.06895478980.00145354020.0099373979LN T1.696647363110.079780856720.010044340730.9101748026CH20.05513070190.0223509003-1.12658446490.04547533710.06895478980.00145354020.0099373979LN T1.080412235910.050712929320.007358669630.9419284011OH0.02315276790.02085892410.38724788950.01426868380.02163577340.01416159870.8854054101LN T-0.3872632265l1-1.6428l2-1.6356l3-2.32H2O0.89427842480.9399581746-0.04167590580.01357075480.02057749540.02187065370.9799595398LN T0.0079764469ln1 C0.6014295023ln2 C0.27905352ln3 C

Ln R 12.812167505Ln R 20.3158219328Ln R 30.0079764469

Ln 13.4135970073 130.3743045925Ln 20.5948754527 21.812805151Ln 30.0079764469 31.0080083435CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETAestimaciones 0.5FASE X10.0564410309X20.0072896445X30.9362693246CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.05846850960.0372242208-0.95151470650.09639692990.16309054390.00371838520.0096225378LN T1.423525990710.201958576820.012636199530.7854052237CH20.15534228690.0629783379-0.95151470650.09639692990.16309054390.00371838520.0096225378LN T0.906490607310.135069737220.009740249730.8551900131OH0.05846850960.05267578420.37433448810.03024622560.05117251550.03622760360.8573519043LN T-0.4191992845l1-1.6428l2-1.6356l3-2.32H2O0.85896268310.9028385045-0.04977041780.02876678170.04866949680.05617635530.9489101467LN T-0.0458533076ln1 C0.4012672481ln2 C0.1957392122ln3 C0.0100865565

Ln R 11.9853451886Ln R 20.0107645023Ln R 3-0.0458533076

Ln 12.3866124366 110.8765863395Ln 20.2065037146 21.2293723008Ln 3-0.035766751 30.9648653211VEINTEAVA ITERACIONestimaciones 0.5FASE X10.0210070392X20.0052607893X30.9737321716FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.02409892520.0153426814-1.12146905540.04709221170.07194637620.00151346050.0099290285LN T1.688357805710.083416161120.010119965330.9064638737CH20.05781753890.0234401886-1.12146905540.04709221170.07194637620.00151346050.0099290285LN T1.075133508310.053102003820.007425019530.9394729767OH0.02409892520.02171134160.38690414420.01477600650.0225744360.01474539210.8846597086LN T-0.3883916249l1-1.6428l2-1.6356l3-2.32H2O0.89333226750.9389636876-0.04189190820.01405326260.02147024490.02277468710.9791342034LN T0.0062433142ln1 C0.594963144ln2 C0.2763598613ln3 C

Ln R 12.7869133665Ln R 20.306403977Ln R 30.0062433142

Ln 13.3818765105 129.4259374182Ln 20.5827638383 21.7909815801Ln 30.0062433142 31.0062628443CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETAestimaciones 0.5FASE X10.0541342209X20.0071583334X30.9387074457CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.05623170120.0358001475-0.96174087210.09366203060.15803267870.0035731910.0096426321LN T1.438912128110.194959179320.01248896630.7925518547CH20.14899326860.0604043406-0.96174087210.09366203060.15803267870.0035731910.0096426321LN T0.916288383410.130000242620.009598090130.8604016673OH0.05623170120.0506605860.37515730120.02938810310.04958552170.03481300110.8591422676LN T-0.4177034336l1-1.6428l2-1.6356l3-2.32H2O0.86119949140.905189569-0.04925579220.02795063280.04716012810.05396871310.9508917063LN T-0.0430015433ln1 C0.411753637ln2 C0.2001062435ln3 C0.0094345305

Ln R 12.0316205053Ln R 20.0276464906Ln R 3-0.0430015433

Ln 12.4433741424 111.5118177984Ln 20.2277527341 21.2557747768Ln 3-0.0335670128 30.966990108321 ITERACIONestimaciones 0.5FASE X10.0219318311X20.0053130204X30.9727551485FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.02499527660.0159133472-1.11664706780.04860883350.07475234290.00157026460.0099210963LN T1.680561761810.086839749620.010191260830.9029689895CH20.06036283780.024472095-1.11664706780.04860883350.07475234290.00157026460.0099210963LN T1.070169046510.055358401720.007487740130.9371538582OH0.02499527660.02251888760.38657838180.01525187310.02345485730.01529882490.883952964LN T-0.3894442815l1-1.6428l2-1.6356l3-2.32H2O0.89243591610.9380215505-0.04209658360.01450585310.02230760180.02363188480.9783519842LN T0.0046189637ln1 C0.5889014117ln2 C0.2738350372ln3 C

Ln R 12.7631712804Ln R 20.2975552766Ln R 30.0046189637

Ln 13.3520726921 128.5618723012Ln 20.5713903138 21.7707272072Ln 30.0046189637 31.0046296475CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETAestimaciones 0.5FASE X10.0521061741X20.0070428549X30.940850971CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.05426516420.0345481434-0.97081852640.09121071140.1534993610.00344573760.0096602813LN T1.45262606510.188730278620.012357877830.7989118436CH20.14341148820.0581413944-0.97081852640.09121071140.1534993610.00344573760.0096602813LN T0.92502131510.125514122320.009472241830.865013636OH0.05426516420.04888888220.37588013860.02861895870.04816311380.03357124420.8607147816LN T-0.4163378844l1-1.6428l2-1.6356l3-2.32H2O0.86316602850.9072565568-0.04880356650.02721910980.0458072950.05203176520.9526321521LN T-0.0404414578ln1 C0.4211877162ln2 C0.2040341131ln3 C0.0088716356

Ln R 12.0728987861Ln R 20.0427259768Ln R 3-0.0404414578

Ln 12.4940865023 112.1106653993Ln 20.2467600898 21.2798720217Ln 3-0.0315698222 30.968923301722 ITERACIONestimaciones 0.5FASE X10.0228044712X20.0053623292X30.9718331996FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.02584110120.016451845-1.11211819080.05002664790.07737542660.00162390070.0099136083LN T1.67325545910.090052391720.010258207430.8996894008CH20.06276459960.025445809-1.11211819080.05002664790.07737542660.00162390070.0099136083LN T1.065516447910.057481493120.007546787630.9349717192OH0.02584110120.02328091280.38627088340.01569673730.02427789570.0158213920.8832857931LN T-0.3904232418l1-1.6428l2-1.6356l3-2.32H2O0.89159009140.9371325211-0.04228976040.01492895740.02309038270.02444143530.9776135648LN T0.0031015882ln1 C0.5832379897ln2 C0.2714763536ln3 C

Ln R 12.7409282216Ln R 20.2892700134Ln R 30.0031015882

Ln 13.3241662113 127.7758298123Ln 20.560746367 21.7519796323Ln 30.0031015882 31.0031064031CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETAestimaciones 0.5FASE X10.0503179309X20.0069410102X30.9427410588CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.05253113870.0334441689-0.97889177720.08901182490.14943293580.00333350630.0096758305LN T1.464867152410.183178406920.012241001430.8045805916CH20.13848971820.0561460272-0.97889177720.08901182490.14943293580.00333350630.0096758305LN T0.93281634710.121535546420.009360603630.8691038501OH0.05253113870.0473266540.37651708030.02792901950.04688720170.03247779310.8621001916LN T-0.4150935435l1-1.6428l2-1.6356l3-2.32H2O0.8649000540.9090791564-0.04840497870.02656291790.0445937920.05032688560.9541655127LN T-0.0381417813ln1 C0.4296771087ln2 C0.2075680361ln3 C0.0083837967

Ln R 12.1097693106Ln R 20.0562114051Ln R 3-0.0381417813

Ln 12.5394464193 112.6726536921Ln 20.2637794411 21.3018410321Ln 3-0.0297579846 30.970680424723 ITERACIONestimaciones 0.5FASE X10.0236249931X20.0054087057X30.9709663013FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.02663642090.0169581886-1.10787840750.05134816640.07982031290.00167436420.0099065648LN T1.666429391410.093057450420.010320852430.8966216971CH20.06502291670.0263613682-1.10787840750.05134816640.07982031290.00167436420.0099065648LN T1.061169659610.059472436920.007602177730.9329253854OH0.02663642090.02399743670.38598165880.01611138680.02504502160.01631304930.8826582245LN T-0.3913312093l1-1.6428l2-1.6356l3-2.32H2O0.89079477180.9362965766-0.04247143650.01532332510.02381998590.02520324330.976918977LN T0.0016882674ln1 C0.5779623144ln2 C0.2692793558ln3 C

Ln R 12.7201538216Ln R 20.2815359783Ln R 30.0016882674

Ln 13.2981161359 127.0616104752Ln 20.5508153341 21.7346667744Ln 30.0016882674 31.0016896933CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETAestimaciones 0.5FASE X10.0487368935X20.0068509551X30.9444121514CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH30.05099802620.0324681064-0.98608428290.08703780360.1457823890.00323439760.0096895678LN T1.475808425910.178222677620.012136654930.8096406674CH20.13413823890.0543818654-0.98608428290.08703780360.1457823890.00323439760.0096895678LN T0.939783667410.117999941520.009261379830.8727386786OH0.05099802620.04594543360.37707988580.02730963580.04574177870.03151219390.8633241615LN T-0.4139611869l1-1.6428l2-1.6356l3-2.32H2O0.86643316640.9106905802-0.04805270540.02597383030.04350439540.0488219210.9555201926LN T-0.0360746875ln1 C0.437319005ln2 C0.2107487443ln3 C0.0079594527

Ln R 12.1427449019Ln R 20.0682850352Ln R 3-0.0360746875

Ln 12.5800639069 113.1979815742Ln 20.2790337795 21.3218519946Ln 3-0.0281152347 30.972276320324 ITERACIONestimaciones 0.5FASE X10X20X30FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH300ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!1ERROR:#DIV/0!2ERROR:#DIV/0!3ERROR:#DIV/0!CH200ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!1ERROR:#DIV/0!2ERROR:#DIV/0!3ERROR:#DIV/0!OH00ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!l1-1.6428l2-1.6356l3-2.32H2O00ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!ln1 CERROR:#DIV/0!ln2 CERROR:#DIV/0!ln3 C

Ln R 1ERROR:#NUM!Ln R 2ERROR:#NUM!Ln R 3ERROR:#NUM!

Ln 1ERROR:#DIV/0! 1ERROR:#DIV/0!Ln 2ERROR:#NUM! 2ERROR:#NUM!Ln 3ERROR:#NUM! 3ERROR:#NUM!CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETAestimaciones 0.5FASE X10X20X30CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH300ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!1ERROR:#DIV/0!2ERROR:#DIV/0!3ERROR:#DIV/0!CH200ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!1ERROR:#DIV/0!2ERROR:#DIV/0!3ERROR:#DIV/0!OH00ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!l1-1.6428l2-1.6356l3-2.32H2O00ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!ln1 CERROR:#DIV/0!ln2 CERROR:#DIV/0!ln3 CERROR:#DIV/0!

Ln R 1ERROR:#NUM!Ln R 2ERROR:#NUM!Ln R 3ERROR:#NUM!

Ln 1ERROR:#DIV/0! 1ERROR:#DIV/0!Ln 2ERROR:#NUM! 2ERROR:#NUM!Ln 3ERROR:#DIV/0! 3ERROR:#DIV/0!25 ITERACIONestimaciones 0.5FASE X10X20X30FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH300ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!1ERROR:#DIV/0!2ERROR:#DIV/0!3ERROR:#DIV/0!CH200ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!1ERROR:#DIV/0!2ERROR:#DIV/0!3ERROR:#DIV/0!OH00ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!l1-1.6428l2-1.6356l3-2.32H2O00ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!ln1 CERROR:#DIV/0!ln2 CERROR:#DIV/0!ln3 C

Ln R 1ERROR:#NUM!Ln R 2ERROR:#NUM!Ln R 3ERROR:#NUM!

Ln 1ERROR:#DIV/0! 1ERROR:#DIV/0!Ln 2ERROR:#NUM! 2ERROR:#NUM!Ln 3ERROR:#NUM! 3ERROR:#NUM!CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETAestimaciones 0.5FASE X10X20X30CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH300ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!1ERROR:#DIV/0!2ERROR:#DIV/0!3ERROR:#DIV/0!CH200ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!1ERROR:#DIV/0!2ERROR:#DIV/0!3ERROR:#DIV/0!OH00ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!l1-1.6428l2-1.6356l3-2.32H2O00ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!ln1 CERROR:#DIV/0!ln2 CERROR:#DIV/0!ln3 CERROR:#DIV/0!

Ln R 1ERROR:#NUM!Ln R 2ERROR:#NUM!Ln R 3ERROR:#NUM!

Ln 1ERROR:#DIV/0! 1ERROR:#DIV/0!Ln 2ERROR:#NUM! 2ERROR:#NUM!Ln 3ERROR:#DIV/0! 3ERROR:#DIV/0!26 ITERACIONestimaciones 0.5FASE X10X20X30FASE Y10.4 Y20.02Y30.58CALCULO DE COEFICIENTE DE ACTIVIDAD DE LA FASE ALFACALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH300ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!1ERROR:#DIV/0!2ERROR:#DIV/0!3ERROR:#DIV/0!CH200ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!1ERROR:#DIV/0!2ERROR:#DIV/0!3ERROR:#DIV/0!OH00ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!l1-1.6428l2-1.6356l3-2.32H2O00ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!ln1 CERROR:#DIV/0!ln2 CERROR:#DIV/0!ln3 C

Ln R 1ERROR:#NUM!Ln R 2ERROR:#NUM!Ln R 3ERROR:#NUM!

Ln 1ERROR:#DIV/0! 1ERROR:#DIV/0!Ln 2ERROR:#NUM! 2ERROR:#NUM!Ln 3ERROR:#NUM! 3ERROR:#NUM!CALCULO DEL COEFICIENTE DE ACTIVIDAD EN LA FASE BETAestimaciones 0.5FASE X10X20X30CALCULO DE BUTANOLlnsumatoriasumatoriasumatoriaBUTANOLNUMERO PRINCIPALNUMERO SECUNDARIORQVa110111CH30.20.2311886587-0.2542518580.29811697390.56951591720.0847493607LN T*0.2559854261CH3110.90110.8481a15644.6150.1026395571CH20.60.4416575791-0.2542518580.29811697390.56951591720.0847493607LN T*0.1630095874CH2120.67440.543a181300180.0101406207OH0.20.3271537623-0.92579979470.09353942360.1786955970.8256988149LN T*0.9934391511OH51411.21a51328.2510.3137675202METANOLMETANOLa81342.4810.2984201023CH30.50.4140625-0.51431394030.6925156720.0956983676LN T*0.6157327158CH3110.90110.8481a550551OH0.50.5859375-0.46451998530.21728892510.9323731536LN T*0.377829488OH51411.21a85-122.4851.5407660232AGUAAGUAa5828.73580.9035122106H2O1101LN T*0H2O8170.921.41

CALCULO DE 1r13.9243r21.9011r30.92fracciones mezclalnsumatoriasumatoriasumatoriasumatoriaq13.668q22.048q31.4CH300ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!1ERROR:#DIV/0!2ERROR:#DIV/0!3ERROR:#DIV/0!CH200ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!1ERROR:#DIV/0!2ERROR:#DIV/0!3ERROR:#DIV/0!OH00ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!l1-1.6428l2-1.6356l3-2.32H2O00ERROR:#NUM!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!ERROR:#DIV/0!LN TERROR:#NUM!ln1 CERROR:#DIV/0!ln2 CERROR:#DIV/0!ln3 CERROR:#DIV/0!

Ln R 1ERROR:#NUM!Ln R 2ERROR:#NUM!Ln R 3ERROR:#NUM!

Ln 1ERROR:#DIV/0! 1ERROR:#DIV/0!Ln 2ERROR:#NUM! 2ERROR:#NUM!Ln


Zusammenfassung der erzielten Forschungsergebnisse … · NRTL-, UNIQUAC-Gleichung oder die Gruppenbeitragsmethoden ASOG, UNIFAC und Modified UNIFAC (Dortmund). Die Anwendung dieser

Zusammenfassung der erzielten Forschungsergebnisse … · NRTL-, UNIQUAC-Gleichung oder die Gruppenbeitragsmethoden ASOG, UNIFAC und Modified UNIFAC (Dortmund). Die Anwendung dieser

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