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8/19/2019 17.WM-RC Landfill Leachate
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UniPD17.1
MSc “Environmental Engineering” - Waste Management Course
17. LandfillLandfill
leachateleachate
managementmanagement
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UniPD17.2
Leachate is a wastewater produced by the infiltration of water in the
landfill.
The water percolating through the waste removes organic compounds,
metals and salts.
The QUALT! of the leachate depends by the "uality and type of the
waste #$%&, ndustrial waste, bottom ashes', it depends by the
conditions of the degradation of waste in the landfill #anaerobiccondition, aerobic conditions, semi(aerobic condtions' and finally it
depends by the age of the landfill #new landfill or old landfill'.
The QUA)TT! of leachate depends by*
+ haracteristics of the site
+ limatic - meteorological conditions of the site
+ Physical characteristics of the waste
+ haracteristics of the barrier systems
What is leachate?What is leachate?
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UniPD17.3
ydrological balance of a landfill / &ater 0udget of a landfill
LcLi
L ∆Ubio
∆Uw%
1
232
P 4T / 4
Pe
∆Us
Pi
%urface
water
1roundwater
source
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UniPD17.4
% * infiltration from the surface water sources
23 * 2un off from surroundings to the landfill
2 * 2un off from the landfill to surroundings
P * Precipitation /rainfall
4T * 4vaporation - Transpiration
Pe * Precititation entered in the landfill body
Pi * Precipitation nfiltrated in the top cover
ydrological balance of a landfill / &ater 0udget of a landfill
%ymbols
4 * 4vaporation #only'
1 * infiltration from the groundwater sources
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UniPD17.5
L * Total produced leachate
Li * Uncontrolled infiltrated leachate
∆Us* $oisture variation of top cover
Lc * ollected leachate
∆Ubio * &ater consumpion or production by
biological activity
∆Uw * $oisture variation of waste
ydrological balance of a landfill / &ater 0udget of a landfill
%ymbols
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UniPD17.6
% * infiltration from the surface water sources
23 * 2un off from surroundings to the landfill
2 * 2un off from the landfill to surroundings
P * Precipitation / rainfall
4T * 4vaporation - Transpiration
Pe * Precititation entered in the landfill body
Pi * Precipitation nfiltrated in the top cover
ydrological balance of a landfill / &ater 0udget of a landfill
%ymbols
4 * 4vaporation #only'
1 * infiltration from the groundwater sources
Uncontrollable
ontrollable
Avoidable
ontrollable/Uncontrollable
Avoidable
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17.7
L * Total leachate produced
Li * Uncontrolled leachate escape
5Us* $oisture variation of top cover
Lr *Leachate recovered
5Ubio * &ater consumpion or production due to biological activity
5Uw * $oisture variation of waste
ydrological balance of a landfill / &ater 0udget of a landfill
%ymbols
Avoidable
Uncontrollable/
ontrollable
6
%hould be e"ual
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17.
ydrological balance of a landfill / &ater 0udget of a landfill
Lr Li
L ∆Ubio
∆Uw%
1
232
P 4T / 4
Pe
∆Us
Pi
%urface
water
source
1roundwater
source
!
!
!!
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UniPD17.!
ydrological balance of a landfill / &ater 0udget of a landfill
Lr
L ∆Ubio
∆Uw
2
P 4T / 4
Pe
∆Us
Pi
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UniPD17.1"
L 7 Pi 8 % 8 1 9 ∆Us 9 ∆Uw 9 ∆Ubio
Pi 7 P 8 23 ( 2 : 4T
Lr 7 L : Li
onsidering that some terms are e"ual to
;ero the e"uation becomes the following*
Lr 7 L 7 P ( 2 : 4T 9 ∆Us 9 ∆Uw 9 ∆Ubio
ydrological balance of a landfill / &ater 0udget of a landfill
4"uations
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UniPD17.11
#reci$itation % &ain'all * should be evaluated by
pluviometers as much close as possible to the site of thelandfill
Sur'ace runo'' * can be calculated using the followingformula
2 7 . P2 7 surface runoff #mm/d'
7 runoff coefficient
P 7 rainfall #mm/d'
7 a.bi
a : depends on the presence of the final cover, on the
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UniPD17.12
4mpirical values of =bi> for taly
4mpirical values for =a>
2U)?@@ ?4@@4)T 7 a.bi
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UniPD17.13
4vaporation - 4vaporation and Transpiration #4 / 4T'
4vaporation 7 no plants or grass on the top cover
4vaporation - Transpiration 7 plants and grass on the top
cover
Potential 4T #P4i'* $aimal 4T from surface covered with a
homogeneous,green crop with optimal water supply
1overning factors*
: $eteorological factors* &ind, Temperature, 2elativehumidity
: %oil and plant factors* Type/state of crop, %oil type
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UniPD17.14
Potential 4vapotranspiration
PE 16(
10T
I ) Cii
T
a
i= ⋅
P4i 7 potential evapotranspiration of the i(month #mm/month'
Ti 7 monthly average temperature #B'
1,51412
i01
i T )
5
T(I ∑= 7 annual thermal inde
a = 6,75 10-7 IT3 - 7,71 10-5 IT
2 + 1,7 10-2 IT + 0,423
i 7 depends on hours of sunlight and on latitude
Thorntwaite @ormula*
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UniPD17.15
i values depending on month #sunlight' and on latitude
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UniPD17.16
ow to manage the Potential 4vapotranspiration values
During the =wet> season where P : 2 C P4, 4T 7 P4 can be
assumed
During the =dry> season where P : 2 P4, it is more difficult
to evaluate the value of the 4T.
A suggestion can be the following*
4T 7 P4 . U / @
U * actual moisture content of the ground
@ * field capacity
4ven in this case an evaluation or an estimation of the U - @
values should be done.
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UniPD 17.17
4vaporation
Turc @ormula*
L
a P
a P E
++
+=
1
4 7 evaporation in EF days #mm/EF days' GGG
P 7 average precipitation in EF days #mm/EFdays' GGG
a 7 amount of water that can evaporate in EF days withoutprecipitation 7 EF : F.FE3tF.H
t 7 time since the last precipitation #in seconds'
L 7 heliothermic factor
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UniPD 17.1
eliothermic factor
g I T L )2(
16
1+=
T 7 average temperature #B'
I g 7 F#F.EI 8 F.JK n/)' solar radiation
F 7 theoretica maimum solar radiation #cal/cmK/d' #see page KF'
) 7 theoretical maimum hours of incoming solar radiation #seepage KE'
n 7 effective hours of incoming solar radiation
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UniPD 17.1!
F theoretical maimum solar radiation #cal/cmK/d'
values depending on month and on latitude
) th ti l i h f i i l di ti
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UniPD 17.2"
) theoretical maimum hours of incoming solar radiation
depending on month and on latitude
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UniPD 17.21
nfiltration
nfiltration through a low permeability layer* Darcy law
Q 7 3%3i MmN/sO
* Permeability of the layer #m/s'% * Area of the layer #mK'
* ydraulic gradient #m/m'
Q * @low rate of water
&ater can permeate #infiltrate' though a porous medium only
after reaching saturation #@4LD APAT!, @'
@ definition* The volume of water which is the maximum that
a soil can hold in its pores after excess water has been drained
away; the state of a soil in this condition, when the only water
that remains is water retained by the soil particles through
surface tension.
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UniPD 17.22
nfiltration
igh permeable soils or waste can be manage at the same
way to model the infiltration.
t can be considered that due to hydraulic short circuits
through the medium, the percolation of water can appear after
the saturation of HF of the @.
W
W FC +
−=
453555.06.0
@ * @ield apacity # of dry matter'
& * &eight of E mN of waste at the average depth of thelandfill #g'
As example: MS with a density of !."# t$m%, with a moisture
content of %#&, has a '( of "!&
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UniPD 17.23
Assignment
1iven the data below and the information available in the previous slides,
calculate the leachate production of a landfill for untreated municipal
solid waste.
The following informations are available*
E' )o top cover during operation of the landfill
K' Temporary top cover realised by sandy material until the EHB year after
closure with a slope of H(EFN' @inal top cover realised by clayey material since EHB year after closure
with a slope of H
' EF meters of depth of the landfill
H' Population served* E.FFF.FFF people
J' The landfill is composed by NF sectors, each sector is completed in onesemester.
Any other re"uired data should be reasonable assumed
(he use o' E)cel is recommen*e* 'or calculations
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UniPD 17.24
Quality
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UniPD 17.25
Leachate omposition
average values acetogenic phase
average values methanogenic phase
4hrig, ERIR ruse, ERR 4hrig, ERIR ruse, ERR
p ( J,E S, I,F S,J
0?DH mg/l ENFFF JNFF EIF KNF
?D mg/l KKFFF RHFF NFFF KHFF
0?DH /?D ( F,HI F,FJ
%ulphate mg/l HFF KFF IF KF
a mg/l EKFF JHF JF KFF
$g mg/l SF KIH EIF EHF
@e mg/l SIF ENH EH KH$n mg/l KH EE F,S K
n mg/l H K,K F,J F,J
%r mg/l S E
A? Vg/l EJS KFF EFF ESKH
Average concentrations of biochemical influenced leachate components
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UniPD 17.26
Average concentrations of non biochemical influenced leachate components
4hrig, ERIR ruse, ERR
T) Mmg / lO EKHF RKF
)() Mmg / lO SF SF
ges. P / total ) Mmg / lO J J,I
hlorid Mmg / lO KEFF KEHF
)a Mmg / lO ENHF EEHF Mmg / lO EEFF IIF
As MVg / lO EJF KH,H
Pb MVg / lO RF EJF
d MVg / lO J NS,H
r MVg / lO NFF EHH
o MVg / lO HH
u MVg / lO IF RF)i MVg / lO KFF ERF
g MVg / lO E,H
T) 7 total Weldal nitrogen
Leachate omposition
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UniPD 17.27
Leachate management options
+ A. n situ * recirculation+ 0. ?n site* leachate treatment plant
+ . ?ff site* co(treatment at eternal
facilities #industrial or domestic'
+ ,
C
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UniPD 17.2
*everse +smosis
Leachate treatment options
Biological Treatment
Adsorption
+xidation
+one - /
'locculation$)recipitation - 0eutralisation
1iological Treatment
Adsorption
2vaporation
3esiccation
Leachate
cleaned
Leachate
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UniPD 17.2!
%election criteria for treatment
!oung $edium ?ld
?D #mg/l' C EF.FFF HFF(EF.FFF HFF?D/T? K,S K,F(K,S K,F
0?DH/?D C F, F,E(F, F,E
0iological treatment
hemical precipitation
?;one
2everse osmosis
Activated carbonon echange
good good4fair fair fair4poor poor
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UniPD 17.3"
e issues in leachate treatment
+ )X? in acid phase leachate is easy to degrade #X@As6'but )X? in methanogenic phase leachate is hard todegrade* t is difficult to obtain low effluent concentrationsby biological methods alone
+ Ammonia can be treated by three approaches*( 0iologically by nitrification* )8 → )?K( → )?N(
( 0iologically by nitrification(denitrification* )8 → )?K( → )?N(aerobic/anaerobic )?N( → )K⇑
( Air stripping* ncrease p #p C pa 7 R.N' and air inWection )8 → )N ⇑
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UniPD 17.31
Aerobic treatment* nfluent and effluent concentrations
!g"l
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UniPD 17.32
Activated %ludge Tan<
)itrification, Denitrification
0iological leachate treatment
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UniPD
Leachate treatment plant